期刊
CHEMSUSCHEM
卷 12, 期 13, 页码 3089-3093出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201802144
关键词
alkylation; amines; carboxylic acids; cobalt; reduction
资金
- Indo-French Centre for the Promotion of Advanced Research [5805-1] Funding Source: Medline
Direct reductive alkylation of amines with carboxylic acid is carried out by using an inexpensive, air-stable cobalt/triphos catalytic system with molecular hydrogen as the reductant. This efficient synthetic method proceeds through reduction and condensation, followed by reduction of the in situ-generated imine into the amine in a green catalytic process.
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