期刊
CHEMPHYSCHEM
卷 20, 期 5, 页码 648-650出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201801207
关键词
hematite electrode; high-valence iron species; hydrocarbon oxidation; hydrogen peroxide oxidation; water oxidation
资金
- Japan Society for the Promotion of Science (JSPS) [17H04798]
- JST CREST from the Japan Science and Technology Agency (JST) [JPMJCR18R3]
The high-valence iron species (Fe(IV)=O) in the cytochrome P450 enzyme superfamily is generated via the activation of O-2, and serves as the active center of selective hydrocarbon oxidation reactions. Furthermore, P450 can employ an alternate route to produce Fe(IV)=O, even from H2O2 without O-2 activation. Meanwhile, Fe(IV)=O has recently been revealed to be the reactive intermediate during H2O oxidation to O-2 on hematite electrodes. Herein, we demonstrated the generation of Fe(IV)=O on hematite electrodes during the electrochemical oxidative decomposition of H2O2 using in situ UV-visible absorption spectra. The generation of Fe(IV)=O on hematite electrodes from H2O2 exhibited 100 mV lower overpotential than that from H2O. This is because H2O2 serves not only as the oxygen source of Fe(IV)=O, but also as the additional oxidant. Finally, we confirmed that the Fe(IV)=O generated on hematite electrodes can serve as the catalytic site for styrene epoxidation reactions.
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