期刊
CHEMCATCHEM
卷 11, 期 1, 页码 575-582出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201801344
关键词
Electrocatalysis; aqueous phase hydrogenation; phenol; benzaldehyde; Pt/C; particle size effects
资金
- U.S. DOE [DE-AC02-06CH11357]
- Canadian Light Source
Hydrogenation of phenol and of the benzaldehyde carbonyl group catalyzed by Pt are structure sensitive in aqueous phase. The intrinsic reaction rates are directly proportional to the average size of the Pt particles. This trend is indifferent of the genesis of the reduction equivalents, i.e., dissociation of H-2 or proton reduction under cathodic potential. It is concluded that the structure sensitivity is caused by the ensemble size sensitivity of the adsorption of the aromatic molecules, which is favored on (100) and (111) surfaces of larger particles. For electrocatalytic reduction, this structure sensitivity implies that hydrogen evolution increases in rate relative to hydrogen addition to reacting substrates as the size of Pt particles decreases.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据