☆ 4.6 Article

Visible light-induced direct conversion of aldehydes into nitriles in aqueous medium using Co@g-C3N4 as photocatalyst

CATALYSIS COMMUNICATIONS (2019)

期刊

CATALYSIS COMMUNICATIONS

卷 119, 期 -, 页码 76-81

出版社

ELSEVIER SCIENCE BV

DOI: 10.1016/j.catcom.2018.10.031

关键词

Visible-light; Aldehydes; Nitrites; Aqueous medium; g-C3N4, photocatalysis

类别

Chemistry, Physical

资金

SERB, Department of Science & Technology, New Delhi, India [SR/FT/CS-99/2010]

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Protocol

Reagent

摘要

Unprecedented Co@g-C3N4 catalyzed visible light driven efficient conversion of a variety of aldehydes into corresponding nitrites is reported. Operational simplicity, excellent yield of pure products (87-94%), ambient reaction condition, using aqueous methanol as solvent, visible-light photocatalysis are the salient features of envisaged methodology for direct conversion of aldehydes into nitrites. Furthermore, reusability of Co@g-C3N4 was checked up to five runs and it was noticed that there was no substantial change in morphology as well as the catalytic efficiency of catalyst.

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