Article
Chemistry, Organic
Jessica M. L. Elwood, Martyr C. Henry, J. Daniel Lopez-Fernandez, Jenna M. Mowat, Mhairi Boyle, Benjamin Buist, Keith Livingstone, Craig Jamieson
Summary: We have reported the use of N-2,4-dinitrophenyltetrazoles as latent active esters (LAEs) in the synthesis of amide bonds. This method allows the generation of an HOBt-type active ester without the need for exogenous coupling agents. The methodology is applicable to a wide range of substrates, providing quantitative yields. The versatility and functional group tolerance were demonstrated in the one-step synthesis of various pharmaceutical agents and the N-acylation of resin-bound peptides.
Article
Chemistry, Organic
Nihal S. Tabasi, Sertac Genc, Derya Gulcemal
Summary: An acceptorless dehydrogenative coupling of primary alcohols to carboxylic acids/carboxylates, esters, and Guerbet alcohols was developed under aerobic conditions using an N-heterocyclic carbene iridium(i) catalyst. The selectivity of the products can be easily adjusted by modifying reaction conditions such as catalyst and base amounts, choice of base, and reaction temperature.
ORGANIC & BIOMOLECULAR CHEMISTRY
(2022)
Article
Chemistry, Applied
Hongyu Xia, Ganghu Wang, Dongbo Zhao, Chunyin Zhu
Summary: A visible-light-induced oxidative coupling reaction of arylboronic acids for the synthesis of biaryls has been developed. The reaction utilizes polydentate hydrazones as a bifunctional catalyst and proceeds smoothly at room temperature. It is compatible with a wide range of functional groups. The study of UV-Vis spectrum shows that hydrazone and its complex with CuI exhibit major absorptions upon visible-light, indicating the dual role of hydrazone as both ligand and photocatalyst in this reaction.
ADVANCED SYNTHESIS & CATALYSIS
(2022)
Article
Chemistry, Physical
Cheng Chen, Zhi-Qin Wang, Yan-Yan Gong, Ji-Chao Wang, Ye Yuan, Hua Cheng, Wei Sang, Somboon Chaemchuen, Francis Verpoort
Summary: The robust heterogeneous catalyst Co@NC, developed with cobalt embedded in nitrogen-doped porous carbon, efficiently produces numerous aromatic and aliphatic carboxylic acids. The catalyst can be reused up to 15 recycle rounds without activity decay, and can be easily recycled via magnetic separation. The key role of cobalt and nitrogen elements dispersed in the carbon matrix, as well as the hierarchical porosity, in catalytic activity and recyclability was elucidated through further experiments.
Article
Chemistry, Organic
Zijuan Yan, Feipeng Liu, Xuchao Wang, Qing Qiang, Yongjie Li, Yao Zhang, Zi-Qiang Rong
Summary: The facile synthetic method presented involves the construction of amides from alcohols and amines catalyzed by Ni/NHC, with advantages such as base metal catalysis, commercially available catalyst, good yields (up to 95%), and substrate generality. The nature of the reaction was revealed through NMR spectroscopy and isolation of intermediates.
ORGANIC CHEMISTRY FRONTIERS
(2022)
Correction
Chemistry, Multidisciplinary
Zhicong Lin, Boxiang Liu, Yu Wang, Siju Li, Shifa Zhu
Summary: In this study, vinyl-substituted alcohols were synthesized using acetylene as a C2 building block. The method exhibited high selectivity and yield, providing a new pathway for organic synthesis.
Article
Chemistry, Multidisciplinary
Yan Li, Rui Li, Bin Hong Liu, Zhou Peng Li
Summary: The combination of VO2+ in the anolyte with Pd/C at the anode is introduced for the first time in a formic acid fuel cell to enhance HCOOH electrooxidation. The VO2+/Pd catalyst combination establishes a stepwise reaction pathway involving HCOOH dehydrogenation and V3+ electrooxidation to regain VO2+. The fuel cell with the VO2+/Pd combination exhibits a peak power density of 341.3 mW cm(-2) and a stable power density higher than 30 mW cm(-2).
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Peiling Pan, Majid Mohammadnia
Summary: A new magnetic nanocatalyst, Fe3O4-AQCA-Pd, supported on 2-aminoquinoline-7-carboxylic acid functionalized Fe3O4 nanoparticles, was prepared and characterized. The nanocatalyst was used in coupling reactions of pyridyl esters with phenylboronic acid to obtain ketone derivatives with high yields. It showed easy removal, excellent recyclability, and provided a clean synthesis in reduced times.
JOURNAL OF COORDINATION CHEMISTRY
(2023)
Article
Chemistry, Organic
Xianjun Xu, Huangdi Feng, Erik V. Van der Eycken
Summary: An efficient synthesis route for unsymmetric 1,4-diamino-2-butynes has been developed using a microwave-assisted Cu(I)-catalyzed cross-A(3)-coupling/decarboxylative coupling process. The multicomponent reaction yields target products in moderate to good yields with high chemoselectivity.
JOURNAL OF ORGANIC CHEMISTRY
(2021)
Article
Agricultural Engineering
Aakriti Sood, Rahul Upadhyay, Sushil K. Maurya
Summary: The sustainable and eco-compatible synthesis of important chemicals using renewable feedstocks is a significant area of research. This study demonstrates the synthesis of azelaic acid using non-edible Triadica sebifera seed oil and other vegetable oils, with yields of 48-72%. The use of a recyclable catalytic system and a greener oxidant reduces the harmful impact on the environment. The method can also be applied to the synthesis of other important chemicals.
INDUSTRIAL CROPS AND PRODUCTS
(2022)
Article
Chemistry, Physical
Haoyi Wang, Chaobo Yang, Can Shao, Sultan Alturkistani, Gaetano Magnotti, Jorge Gascon, Kazuhiro Takanabe, S. Mani Sarathy
Summary: A La2O3/CeO2 catalyst was synthesized and its doping with CeO2 improved both its performance and stability. The kinetics of the catalyst in the OCM process were investigated through experimental and modeling approaches.
Article
Chemistry, Multidisciplinary
Shafiur Rehman Khan, Sandhya Saini, K. Naresh, Alka Kumari, Vineet Aniya, Praveen K. Khatri, Anjan Ray, Suman L. Jain
Summary: A novel visible light-driven catalyst-free oxidation method is described in this paper, which uses CO2 as a substrate to obtain corresponding acids and CO in both batch and flow photoreactors.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Aiping Wang, Ya Xie, Jingjing Wang, Da Shi, Han Yu
Summary: An efficient and economical amidation strategy using a polyoxometalate-based iron catalyst has been developed, resulting in good yields of corresponding amide products for aliphatic, aromatic, and heterocyclic substrates without the need for additional base or organic ligands. Most significantly, the study presents the first example of heterogeneous iron (III)-catalyzed formation of diamides.
CHEMICAL COMMUNICATIONS
(2022)
Article
Energy & Fuels
Fatemeh Jangi, Nader Rahemi, Somaiyeh Allahyari
Summary: In this research, phosphotungstic acid (PTA) was impregnated on natural zeolites for oxidative desulfurization of dibenzothiophene (DBT). PTA-Ferr showed the highest DBT removal efficiency among the samples, with more than twice the removal rate compared to other samples.
PETROLEUM SCIENCE AND TECHNOLOGY
(2023)
Article
Chemistry, Organic
Yuanjing Huang, Jing Zhang
Summary: In this study, a practical and efficient KOtBu-facilitated amination of carboxylic acids with N,N-dimethylamine was described. This method is applicable for the transformation of various aliphatic and aromatic carboxylic acids and can be used for the late-stage dimethylamidation of complex drug molecules.
SYNTHESIS-STUTTGART
(2022)
Review
Environmental Sciences
Ragini Singh, Akhela Umapathi, Gaurang Patel, Chayan Patra, Uzma Malik, Suresh K. Bhargava, Hemant Kumar Daima
Summary: Nanozymes are nanomaterials that have enzyme-like properties and unique physical and chemical characteristics. They have shown great potential in environmental monitoring and remediation of pollutants, including heavy metals and organic compounds. However, their inherent toxicity needs to be evaluated and monitored to ensure their safe use.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Chemistry, Physical
Luqman H. Hashim, Ahmed Halilu, Yahaya Balarabe Umar, Mohd Rafie Bin Johan, Mohamed Kheireddine Aroua, Paramita Koley, Suresh K. Bhargava
Summary: This study focuses on the design and synthesis of highly active bifunctional catalysts for the conversion of furfural to furfuryl acetate. The catalysts with lower lattice strain exhibited higher catalytic activity.
CATALYSIS SCIENCE & TECHNOLOGY
(2023)
Article
Electrochemistry
Lizhi Qian, Jinliang Li, Gongxu Lan, Yuan Wang, Sufeng Cao, Lu Bai, Runguo Zheng, Zhiyuan Wang, Suresh K. Bhargava, Hongyu Sun, Hamidreza Arandiyan, Yanguo Liu
Summary: Transition metal oxide (TMO)-based anodes attract attention for lithium storage due to their high capacity, easy synthesis, and improved battery safety. The electrochemical performance of TMO anodes can be significantly improved through configurational entropy optimization. For example, a high-entropy oxide (FeCoNiCrCu)(3)O-4 with low potential and high capacity is synthesized. In both half-cell and full-cell configurations, the (FeCoNiCrCu)(3)O-4 electrode shows excellent performance with high specific capacity and low discharge voltage.
Article
Chemistry, Inorganic & Nuclear
Robert Gericke, Martin A. Bennett, Steven H. Priver, Suresh K. Bhargava
Summary: A series of mono and double bridged heterobimetallic d(8)-d(10) complexes with a [MM'](3+) core (M = Ni, Pt; M' = Cu, Ag, Au) were synthesized. The compounds have short metal-metal separations and metallophilic bonding interactions. Analysis using DFT showed the bonding trends between the metals.
INORGANIC CHEMISTRY
(2023)
Review
Chemistry, Physical
Hamidreza Arandiyan, Putla Sudarsanam, Suresh K. Bhargava, Adam F. Lee, Karen Wilson
Summary: Biomass is a renewable energy source that is being increasingly utilized due to concerns about climate change caused by fossil fuel consumption. Waste biomass-derived fuels and chemicals offer a solution to reduce reliance on fossil fuels and achieve "Net Zero 2050 CO2 emissions" with environmental, health, and economic benefits. This review focuses on the use of perovskite oxide catalysts for biomass valorization, discussing their structure-reactivity relationships in various reactions. The study highlights the prospects and challenges for the broader application of perovskite oxide catalysts in biomass valorization.
Article
Geochemistry & Geophysics
Md Khairul Islam, Michael Somerville, Mark I. Pownceby, James Tardio, Nawshad Haque, Suresh Bhargava
Summary: Printed circuit boards (PCBs) from antiquated electronic goods were processed through pyrometallurgical route to separate alloy and slag phases. The addition of B2O3 flux, along with CaO and SiO2, decreased the melting temperature and improved the recovery of valuable metals at 1350°C smelting temperature. A fluxing strategy for smelting e-waste PCBs containing high Al2O3 was proposed based on the experimental findings of this research.
Review
Immunology
K. Swetha, Niranjan G. Kotla, Lakshmi Tunki, Arya Jayaraj, Suresh K. Bhargava, Haitao Hu, Srinivasa Reddy Bonam, Rajendra Kurapati
Summary: Lipid nanoparticles (LNPs) are an advanced technology for efficient in vivo delivery of exogenous mRNA, especially for COVID-19 vaccines. LNPs consist of four different lipids: ionizable lipids, helper or neutral lipids, cholesterol, and lipids attached to polyethylene glycol (PEG). This review presents recent advances and insights in LNPs design, composition, and properties, with a focus on COVID-19 vaccine development. The role of ionizable lipids in mRNA vaccines and the use of LNPs as effective delivery vehicles for vaccination, genome editing, and protein replacement therapy are discussed.
Review
Engineering, Biomedical
N. P. Navya, Sunil Mehla, Amrin Begum, Harit K. Chaturvedi, Ruchika Ojha, Christian Hartinger, Magdalena Plebanski, Suresh K. Bhargava
Summary: Nanomaterials that mimic natural enzymes in the human body are known as nanozymes and have diagnostic, imaging, and therapeutic capabilities. Smart nanozymes exploit the tumor microenvironment to provide effective cancer therapy. This review focuses on the design and synthesis of nanozymes for cancer therapy, including understanding the tumor microenvironment and surface chemistry for site-specific therapy.
ADVANCED HEALTHCARE MATERIALS
(2023)
Article
Engineering, Chemical
P. Sudhakar, Alka Kumari, Sazal Kundu, Vivek Ravi Sankar, Prathap Kumar Thella, Kalpit Shah, Suresh K. Bhargava
Summary: In this study, antisolvent crystallization of L-aspartic acid (L-ASP) was optimized using response surface methodology (RSM) and a focused beam reflectance measurement (FBRM) tool. Important process parameters such as storage temperature, stirrer velocity, storage time, and solvent ratio were identified to significantly improve the yield and quality of the product, while chord length distribution (CLD) data was obtained through FBRM. The results showed that 2-propanol was a more effective antisolvent than methanol for L-ASP crystallization. Temperature was found to have a critical effect on crystal formation, with crystals forming between 298.15 and 303.15 K. ANOVA results confirmed the significant impact of all studied variables on the yield and CLD. The optimum crystallization conditions were determined as 18 h, stirrer velocity of 200 rpm, distilled water-formic acid/IPA ratio of 1:3 (v/v), and storage temperature of 298.15 K. A quadratic response surface model satisfactorily described the crystallization of L-ASP with an R2 of 0.99 and a deviation of 1.2%.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2023)
Article
Chemistry, Multidisciplinary
Gongxu Lan, Huilin Fan, Yuan Wang, Hamidreza Arandiyan, Suresh K. Bhargava, Zongping Shao, Hongyu Sun, Yanguo Liu
Summary: The surface atomic arrangement and defective structures of electrocatalysts play a crucial role in determining their catalytic activity and selectivity. In this study, alpha-Fe2O3 nanosheets with surface oxygen vacancies were synthesized and their oxygen vacancy concentration was varied to study their oxygen reduction reaction (ORR) performance. The results showed that increasing the oxygen vacancy concentration improved the ORR activity up to a certain point, but further increase deteriorated the crystalline quality and affected the performance.
NEW JOURNAL OF CHEMISTRY
(2023)
Review
Chemistry, Physical
Pengcheng Mao, Hamidreza Arandiyan, Sajjad S. Mofarah, Pramod Koshy, Cristina Pozo-Gonzalo, Runguo Zheng, Zhiyuan Wang, Yuan Wang, Suresh K. Bhargava, Hongyu Sun, Zongping Shao, Yanguo Liu
Summary: Rechargeable sodium-air batteries have gained extensive attention and developed rapidly in recent years for electrochemical energy storage applications due to their low costs, abundance of precursor resources, and high energy density. However, challenges such as poor charge-discharge reversibility at the cathode and the formation of sodium dendrites at the anode still need to be addressed. Therefore, designing efficient and stable air cathode materials is crucial for the development and practical application of sodium-air batteries.
Review
Chemistry, Multidisciplinary
Uzma Malik, Roxanne Hubesch, Paramita Koley, Maciej Mazur, Sunil Mehla, Sai Kishore Butti, Milan Brandt, P. R. Selvakannan, Suresh Bhargava
Summary: Combining additive manufacturing with photocatalytic and plasmonic functionalities has promising applications in next-generation SERS. Laser powder bed fusion is a mature technique for manufacturing metallic structures, allowing the printing of complex internal structures. This feature article elaborates on the grafting of plasmonic and semiconductor nanoparticles on LPBF manufactured metallic substrates, showcasing the potential for tailoring substrate properties.
CHEMICAL COMMUNICATIONS
(2023)
Article
Materials Science, Multidisciplinary
Sunil Mehla, Sivacarendran Balendhran, Suresh K. Bhargava
Summary: This study investigates the impact of variations in the morphology of sunflower mimic metasurfaces on their plasmonic activity using experimental studies and finite difference time domain (FDTD) simulations. The study found that light polarization and morphological features such as dendrite shape, aspect ratio, and packing density play an important role in the distribution of enhanced electric field and plasmonic hot spots.
JOURNAL OF MATERIALS CHEMISTRY C
(2023)
Article
Thermodynamics
Ramesh Tangirala, Anoosha Borra, Bankupalli Satyavathi, Prathap Kumar Thella, K. Padmaja, Madapusi P. Srinivasan, Rajarathinam Parthasarathy, Suresh Bhargava
Summary: Crystallization experiments can provide insights into growth kinetic parameters through seeded or unseeded processes, aiding in the design of optimal crystallizers and control of crystal size distribution.
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
(2022)
Article
Chemistry, Physical
Bolun Yu, Denan Li, Qianqian Zhu, Shufan Yao, Lifeng Zhang, Yanshuo Li, Zhenxin Zhang
Summary: This study successfully improved the catalytic activity of a zeolitic octahedral metal oxide by incorporating a single zinc species into its micropore. The zinc incorporation achieved a high ethane conversion rate and ethylene selectivity. Mechanism study showed that the isolated zinc site played a crucial role in activating oxygen and ethane, as well as stabilizing intermediates and transition states.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Ruoqi Liu, Hao Fei, Jian Wang, Ting Guo, Fangyang Liu, Zhuangzhi Wu, Dezhi Wang
Summary: This work successfully synthesized a high-performing S-enriched MoS2 catalyst for electrocatalytic nitrogen reduction reaction (NRR), demonstrating high activity and selectivity. The synergistic effect of the 1T phase and bridging S22- species was shown to play a positive role in NRR performances, and DFT calculations revealed the mechanism behind the improved performance.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Pan Xia, Lele Zhao, Xi Chen, Zhihong Ye, Zhihong Zheng, Qiang He, Ignasi Sires
Summary: This study presents a modified gas-diffusion electrode (GDE) for highly efficient and stable H2O2 electrosynthesis by using trace polymethylhydrosiloxane (PMHS). DFT calculations provide an in-depth understanding of the roles of PMHS functional groups.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Kwangchol Ri, Songsik Pak, Dunyu Sun, Qiang Zhong, Shaogui Yang, Songil Sin, Leliang Wu, Yue Sun, Hui Cao, Chunxiao Han, Chenmin Xu, Yazi Liu, Huan He, Shiyin Li, Cheng Sun
Summary: Different B-doped rGO catalysts were synthesized and their 2e- oxygen reduction reaction (ORR) performance was investigated. It was found that the 2e- ORR selectivity of B-doped rGO was influenced by the B content and oxygen mass transfer conditions. The synthesized catalyst exhibited high 2e- ORR selectivity and was capable of degrading organic pollutants continuously.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Li Lv, Lin Lei, Qi-Wen Chen, Cheng-Li Yin, Huiqing Fan, Jian-Ping Zhou
Summary: Monoclinic phase La2Ti2O7 and orthorhombic phase Bi4Ti3O12 are widely used in photocatalysis due to their layered crystal structure. The electronic structures of these phases play a crucial role in their photocatalytic activity. Heat treatment in a nitrogen atmosphere introduces more oxygen vacancies into the S-scheme heterojunction, leading to enhanced NO removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Choe Earn Choong, Minhee Kim, Jun Sup Lim, Young June Hong, Geon Joon Lee, Keun Hwa Chae, In Wook Nah, Yeomin Yoon, Eun Ha Choi, Min Jang
Summary: In this study, the synergistic effect between argon-plasma-system (AP) and catalysts in promoting the production of reactive species for water remediation was investigated. By altering the oxygen vacancies concentration of CeO2/Bi2O3 catalyst, the production of hydrated electrons was stimulated for PFOA removal. The results showed that the built-in electric field in the Bi/Ce0.43 interface enhanced electron migration and eaq- generation, leading to improved PFOA removal efficiency.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yushan Wu, Di Xu, Yanfei Xu, Xin Tian, Mingyue Ding
Summary: Efficient synthesis of primary amines from carbonyl compounds was achieved via reductive amination using Ru@NC-Al2O3 as a catalyst, exhibiting high activity and selectivity under mild conditions.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Yilan Jiang, Peifang Wang, Tingyue Chen, Keyi Gao, Yiran Xiong, Yin Lu, Dionysios D. Dionysiou, Dawei Wang
Summary: By controlling the content of Co and Ni in Co1-xNixFe2O4, the production of O-1(2) from H2O2 can be regulated. NiFe2O4, with the lowest lattice distortion degree, can efficiently produce O-1(2) as the dominant reactive oxygen species. The system also exhibits significant resistance to water matrix interference.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Shuai Feng, Donglian Li, Hao Dong, Song Xie, Yaping Miao, Xuming Zhang, Biao Gao, Paul K. Chu, Xiang Peng
Summary: In this study, MoO2/Mo2N heterostructures were prepared by regulating the coordination of Mo atoms. The electrocatalyst exhibits high current density and excellent stability for hydrogen evolution reaction.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Jia-Cheng E. Yang, Min -Ping Zhu, Daqin Guan, Baoling Yuan, Darren Delai Sun, Chenghua Sun, Ming-Lai Fu
Summary: This study successfully modulated the electron configuration and spin state of millimetric metal catalysts by adjusting the support curvature radius. The electronic structure-oriented spin catalysis was found to affect the degradation of pollutants, providing new insights for the design and production of highly active, reusable, and stable catalysts.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Tao Zhong, Su Tang, Wenbin Huang, Wei Liu, Huinan Zhao, Lingling Hu, Shuanghong Tian, Chun He
Summary: In this study, a highly efficient photocatalyst for the elimination of CH3SH was developed by engineering different crystal facets and coupling them with PHI. Cu (111)/PHI exhibited the highest elimination efficiency and showed good stability and reusability. The enhanced surface electron pump effect and effective adsorption mechanisms were revealed through comprehensive characterizations and DFT calculations.
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY
(2024)
Article
Chemistry, Physical
Feifei Yang, Tianyu Zhang, Jiankang Zhao, Wei Zhou, Nicole J. Libretto, Jeffrey T. Miller
Summary: A Ni3Sn intermetallic nano particle was found to have geometrically isolated Ni sites that could selectively cleave C-O bonds in biomass derivatives. This nano particle showed high activity and selectivity towards 2-methylfuran, unlike Ni nanoparticles that produced other unwanted products derived from the aromatic rings.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Lulu Qiao, Di Liu, Anquan Zhu, Jinxian Feng, Pengfei Zhou, Chunfa Liu, Kar Wei Ng, Hui Pan
Summary: This study reveals that surface evolution plays a crucial role in enhancing the electrocatalytic performance of transition metal oxides for electrochemical nitrate reduction reaction (e-NO3RR). Incorporating nickel into Co3O4 can promote surface reconstruction and improve the adsorption of intermediates and reduce energy barriers, leading to enhanced catalytic performance. The reconstructed cobalt-nickel hydroxides (CoyNi1_y(OH)2) on the catalyst's surface serve as the active phase.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Xinyu Song, Yang Shi, Zelin Wu, Bingkun Huang, Xinhao Wang, Heng Zhang, Peng Zhou, Wen Liu, Zhicheng Pan, Zhaokun Xiong, Bo Lai
Summary: This study explores the discriminative activities and mechanisms for activation of O-O bond in peroxy compounds via single-atom catalysts (SACs) with higher coordination numbers (M-N5). The atomic catalyst (Fe-SAC) with Fe-N5 as the active center was constructed, effectively activating peroxymonosulfate (PMS), peroxydisulfate (PDS), and hydrogen peroxide (H2O2). The study demonstrates the degradation efficiencies of acyclovir are related to the O-O bond length in different peroxy compounds, and reveals the discriminative mechanisms for activation of O-O bond in different Fenton-like systems.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)
Article
Chemistry, Physical
Yangzhuo He, Hong Qin, Ziwei Wang, Han Wang, Yuan Zhu, Chengyun Zhou, Ying Zeng, Yicheng Li, Piao Xu, Guangming Zeng
Summary: A dual-metal-organic framework (MOF) assisted strategy was proposed to construct a magnetic Fe-Mn oxycarbide anchored on N-doped carbon for peroxymonosulfate (PMS) activation. The FeMn@NC-800 catalyst exhibited superior activity with almost 100% degradation of sulfamethazine (SMZ) in 30 minutes. The study provided insights for the rational design of high-performance heterogeneous catalysts and proposed a novel nonradical-based catalytic oxidation for environmental cleaning.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2024)