期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 6, 页码 1759-1763出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201813464
关键词
ammonia; electrochemistry; hydrogen-storage material; hydrogenation; sustainable chemistry
资金
- National Science Foundation of China [21572099, 21332005]
- Natural Science Foundation of Jiangsu Province [BK20151379]
- Open Project of State Key Laboratory Cul-tivation Base for TCM Quality and Efficacy, Nanjing University of Chinese Medicine [TCMQ E 201702]
As a carbon-free and sustainable fuel, ammonia serves as high-energy-density hydrogen-storage material. It is important to develop new reactions able to utilize ammonia as a hydrogen source directly. Herein, we report an electrochemical hydrogenation of alkenes, alkynes, and ketones using ammonia as the hydrogen source and carbon electrodes. A variety of heterocycles and functional groups, including for example sulfide, benzyl, benzyl carbamate, and allyl carbamate were well tolerated. Fast stepwise electron transfer and proton transfer processes were proposed to account for the transformation.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据