4.8 Article

Multi-Light-Responsive Quantum Dot Sensitized Hybrid Micromotors with Dual-Mode Propulsion

期刊

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 10, 页码 3128-3132

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201811050

关键词

light; micromotor; nanomotor; propulsion; quantum dot

资金

  1. Spanish Ministry of Economy and Competitiveness [BES-2015-072346, RYC-2015-17558]
  2. EU
  3. Community of Madrid [S2013/MIT-3029]
  4. [CTQ2017-86441-C2-1-R]

向作者/读者索取更多资源

CdS quantum dots/C-60 tubular micromotors with chemical/multi-light-controlled propulsion and on-the-fly acceleration capabilities are described. In situ growth of CdS quantum dots on the outer fullerene layer imparts this layer with light-responsive properties in connection to inner Pt, Pd or MnO2 layers. This is the first time that visible light is used to drive bubble-propelled tubular micromotors. The micromotors exhibit a broad absorption range from 320 to 670 nm and can be wirelessly controlled by modulating light intensity and peroxide concentration. The built-in accelerating optical system allows for the control of the velocity over the entire UV/Vis light spectra by modulating the catalyst surface chemistry. The light-responsive properties have been also exploited to accelerate the chemical dealloying and propulsion of micromotors containing a Cu/Pd layer. Such dual operated hybrid micromotors hold considerable promise for designing smart micromachines for on-demand operations, motion-based sensing, and enhanced cargo transportation.

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