期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 10, 页码 2161-2214出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201801331
关键词
amino acids; azomethine ylides pathway; decarboxylation; photoredox catalysis; radical pathway
资金
- Russian Science Foundation [18-73-00301]
- DST-RSF Major Research Project [INT/RUS/RSF/P-08]
This review aims to report recent advances on decarboxylative reactions of amino acids catalyzed by transition metals or non-metals and the growing opportunities they present in the construction of complex chemical scaffolds for applications encompassing natural product synthesis, synthetic methodology development, and functional materials. Different decarboxylative reactions have been highlighted such as radical, photoredox and metal and metal-free coupling reactions. etc. The review is divided into two main sections: one deals with reactions via radical pathways and the other via azomethine ylide pathways. The reactions have been discussed in more detail with particular emphasis on their useful applications and mechanistic illustrations.
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