4.6 Article

Top-down estimate of methane emissions in California using a mesoscale inverse modeling technique: The South Coast Air Basin

期刊

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
卷 120, 期 13, 页码 6698-6711

出版社

AMER GEOPHYSICAL UNION
DOI: 10.1002/2014JD023002

关键词

methane; emission inventory; inverse modeling; Los Angeles

资金

  1. National Research Council Research Associateship Award
  2. NOAA's Atmospheric Chemistry, Carbon Cycle, and Climate Program
  3. California Energy Commission Public Interest Environmental Research Program [DE-AC02-05CH11231]
  4. Laboratory Directed Research and Development program at Sandia National Laboratories
  5. United States Department of Energy's National Nuclear Security Administration [DEAC04-94AL85000]

向作者/读者索取更多资源

Methane (CH4) is the primary component of natural gas and has a larger global warming potential than CO2. Recent top-down studies based on observations showed CH4 emissions in California's South Coast Air Basin (SoCAB) were greater than those expected from population-apportioned bottom-up state inventories. In this study, we quantify CH4 emissions with an advanced mesoscale inverse modeling system at a resolution of 8kmx8km, using aircraft measurements in the SoCAB during the 2010 Nexus of Air Quality and Climate Change campaign to constrain the inversion. To simulate atmospheric transport, we use the FLEXible PARTicle-Weather Research and Forecasting (FLEXPART-WRF) Lagrangian particle dispersion model driven by three configurations of the Weather Research and Forecasting (WRF) mesoscale model. We determine surface fluxes of CH4 using a Bayesian least squares method in a four-dimensional inversion. Simulated CH4 concentrations with the posterior emission inventory achieve much better correlations with the measurements (R-2=0.7) than using the prior inventory (U.S. Environmental Protection Agency's National Emission Inventory 2005, R-2=0.5). The emission estimates for CH4 in the posterior, 46.39.2 Mg CH4/h, are consistent with published observation-based estimates. Changes in the spatial distribution of CH4 emissions in the SoCAB between the prior and posterior inventories are discussed. Missing or underestimated emissions from dairies, the oil/gas system, and landfills in the SoCAB seem to explain the differences between the prior and posterior inventories. We estimate that dairies contributed 5.91.7 Mg CH4/h and the two sectors of oil and gas industries (production and downstream) and landfills together contributed 39.68.1 Mg CH4/h in the SoCAB.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Engineering, Environmental

Influence of Wildfire on Urban Ozone: An Observationally Constrained Box Modeling Study at a Site in the Colorado Front Range

Pamela S. Rickly, Matthew M. Coggon, Kenneth C. Aikin, Raul J. Alvarez II, Sunil Baidar, Jessica B. Gilman, Georgios I. Gkatzelis, Colin Harkins, Jian He, Aaron Lamplugh, Andrew O. Langford, Brian C. McDonald, Jeff Peischl, Michael A. Robinson, Andrew W. Rollins, Rebecca H. Schwantes, Christoph J. Senff, Carsten Warneke, Steven S. Brown

Summary: Increasing trends in biomass burning emissions significantly impact air quality in North America. The transport of smoke from local and long-range fires has been found to increase the mixing ratios of ozone (O3) in urban areas. This is primarily due to the transport of pyrogenic volatile organic compounds (PVOCs) and the influence of O3 produced within the smoke. Detailed chemical measurements have shown that both local and long-range smoke periods lead to increases in carbon monoxide, background O3, OH reactivity, and total VOCs, while the NOx mixing ratios remain constant. Box-model calculations indicate that local O3 production is in the NOx-sensitive regime, with PVOCs substantially increasing O3 production in the transition and NOx-saturated regimes.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Environmental Sciences

Methane emissions decline from reduced oil, natural gas, and refinery production during COVID-19d

A. K. Thorpe, E. A. Kort, D. H. Cusworth, A. K. Ayasse, B. D. Bue, V Yadav, D. R. Thompson, C. Frankenberg, J. Herner, M. Falk, R. O. Green, C. E. Miller, R. M. Duren

Summary: In the summer of 2020, the AVIRIS-NG airborne imaging spectrometer conducted surveys in California's Southern San Joaquin Valley and the South Bay to identify and analyze anthropogenic methane emissions. The results showed a decrease in CH4 emissions from the energy and oil & natural gas sectors, with variations observed across different facilities and sectors. This study not only assessed the impact of COVID-19 on CH4 emissions but also highlighted the potential of remote sensing technology in quantifying emissions at a sector and facility level.

ENVIRONMENTAL RESEARCH COMMUNICATIONS (2023)

Article Multidisciplinary Sciences

Excess methane emissions from shallow water platforms elevate the carbon intensity of US Gulf of Mexico oil and gas production

Alan M. Gorchov Negron, Eric A. Kort, Yuanlei Chen, Adam R. Brandt, Mackenzie L. Smith, Genevieve Plant, Alana K. Ayasse, Stefan Schwietzke, Daniel Zavala-Araiza, Catherine Hausman, Angel F. Adames-Corraliza

Summary: The Gulf of Mexico is the largest offshore fossil fuel production basin in the United States. This study estimates the climate impact of current field operations by collecting airborne observations and combining them with previous surveys and inventories. The findings show high methane emissions exceeding inventories, resulting in an elevated carbon intensity (CI) of the basin. Shallow waters exhibit an extraordinarily high CI primarily driven by methane emissions, indicating the outsized climate impact of current production in these areas.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2023)

Article Multidisciplinary Sciences

Single-blind validation of space-based point-source detection and quantification of onshore methane emissions

Evan D. Sherwin, Jeffrey S. Rutherford, Yuanlei Chen, Sam Aminfard, Eric A. Kort, Robert B. Jackson, Adam R. Brandt

Summary: Satellites are considered a useful tool for identifying large greenhouse gas point sources, but independent verification is needed for acceptance. The first single-blind controlled methane release testing of satellite-based detection and quantification was conducted, with five teams analyzing data from one to five satellites. The teams correctly identified 71% of all emissions, ranging from 0.20 to 7.2 metric tons per hour.

SCIENTIFIC REPORTS (2023)

Article Meteorology & Atmospheric Sciences

Using Space-Based CO2 and NO2 Observations to Estimate Urban CO2 Emissions

Emily G. Yang, Eric A. Kort, Lesley E. Ott, Tomohiro Oda, John C. Lin

Summary: Since a majority of CO2 emissions from fossil fuels come from cities, it is important to use novel techniques to utilize satellite observations of CO2 and proxy species to control urban CO2. This study aims to establish the relationship between satellite observations of CO2 and the proxy species of NO2 and estimate CO2 emissions based on NO2 data. The method was tested in Buenos Aires, Melbourne, and Mexico City and proved to be viable throughout the year. This method provides a valuable observational constraint on urban CO2 emissions, with comparable monthly urban CO2 emissions estimates to inventory estimates.

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES (2023)

Article Meteorology & Atmospheric Sciences

Sensitivity of Modeled Soil NOx Emissions to Soil Moisture

Daniel E. Huber, Allison L. Steiner, Eric A. Kort

Summary: As fossil fuel combustion decreases, the contribution of NOx emissions from managed and unmanaged soils (S-NOx) is increasing. While the Berkeley Dalhousie Soil NOx Parameterization (BDSNP) is commonly used to represent S-NOx, it relies on static relationships between soil moisture and S-NOx, which do not capture the dynamic nature of emissions. In this study, the BDSNP is updated to incorporate a dynamic S-NOx response to soil moisture, resulting in improved representation of S-NOx and reduced sensitivity to input soil moisture data.

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES (2023)

Article Meteorology & Atmospheric Sciences

Observing System Choice Can Minimize Interference of the Biosphere in Studies of Urban CO2 Emissions

Raj. M. M. Lal, Eric. A. A. Kort

Summary: Cities around the world have introduced initiatives to reduce CO2 emissions. Atmospheric observations can provide evaluation and assessment of these initiatives by quantifying emissions, considering local sources and sinks. The relative importance of the urban biosphere, which can act as both a source (respiration) and sink (photosynthesis) of CO2, has previously been suggested to strongly impact urban CO2 measurements, confounding the ability to use observations to study fossil emissions.

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES (2023)

Article Engineering, Environmental

Fuel-Type Independent Parameterization of Volatile Organic Compound Emissions from Western US Wildfires

Kanako Sekimoto, Matthew M. Coggon, Georgios I. Gkatzelis, Chelsea E. Stockwell, Jeff Peischl, Amber J. Soja, Carsten Warneke

Summary: This study finds that emissions of volatile organic compounds (VOCs) from biomass burning, which have impacts on air quality and climate, can be characterized by high- and low-temperature pyrolysis VOC profiles. The variability in VOC speciation is mainly influenced by combustion conditions rather than fuel type. The findings are based on measurements of VOCs obtained during the FIREX-AQ project in 2019 using a proton-transfer reaction time-of-flight mass spectrometer.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Engineering, Environmental

Fuel-Type Independent Parameterization of Volatile Organic Compound Emissions from Western US Wildfires

Kanako Sekimoto, Matthew M. Coggon, Georgios I. Gkatzelis, Chelsea E. Stockwell, Jeff Peischl, Amber J. Soja, Carsten Warneke

Summary: Laboratory studies have shown that biomass burning emissions of volatile organic compounds (VOCs) are mainly affected by combustion conditions rather than fuel type. In this study, ambient smoke emissions from wildfires in the western US were analyzed using positive matrix factorization (PMF) and measured with a mass spectrometer. The results showed that the variability in VOC emissions can be described by high- and low-temperature pyrolysis VOC profiles, which is consistent with previous laboratory findings.

ENVIRONMENTAL SCIENCE & TECHNOLOGY (2023)

Article Environmental Sciences

Quantifying anomalies of air pollutants in 9 US cities during 2020 due to COVID-19 lockdowns and wildfires based on decadal trends

Jeff Peischl, Kenneth C. Aikin, Brian C. McDonald, Colin Harkins, Ann M. Middlebrook, Andrew O. Langford, Owen R. Cooper, Kai -Lan Chang, Steven S. Brown

Summary: The COVID-19 pandemic led to lockdowns in the United States, resulting in decreased on-road emissions and lower concentrations of pollutants such as nitrogen dioxide (NO2), carbon monoxide (CO), ozone (O3), and particulate matter (PM2.5). The concentrations of these pollutants generally decreased in 9 U.S. cities during late March and early April, and decadal trends showed decreases in the summer months. The analysis also revealed anomalous increases in pollutants in western U.S. cities during late summer, attributed to wildfire emissions.

ELEMENTA-SCIENCE OF THE ANTHROPOCENE (2023)

Article Environmental Sciences

Heterogeneity and chemical reactivity of the remote troposphere defined by aircraft measurements - corrected

Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, Steven C. Wofsy

Summary: The NASA ATom mission collected in situ measurements of key reactive species in air parcels over the Pacific and Atlantic oceans. The study found that a large portion of the total reactivity is concentrated in a fraction of all air parcels, supporting previous model-only studies. The results also showed that current global chemistry models can capture much of the heterogeneity in tropospheric chemistry.

ATMOSPHERIC CHEMISTRY AND PHYSICS (2023)

Article Environmental Sciences

Arctic tropospheric ozone: assessment of current knowledge and modelperformance

Cynthia H. Whaley, Kathy S. Law, Jens Liengaard Hjorth, Henrik Skov, Stephen R. Arnold, Joakim Langner, Jakob Boyd Pernov, Garance Bergeron, Ilann Bourgeois, Jesper H. Christensen, Rong-You Chien, Makoto Deushi, Xinyi Dong, Peter Effertz, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Greg Huey, Ulas Im, Rigel Kivi, Louis Marelle, Tatsuo Onishi, Naga Oshima, Irina Petropavlovskikh, Jeff Peischl, David A. Plummer, Luca Pozzoli, Jean-Christophe Raut, Tom Ryerson, Ragnhild Skeie, Sverre Solberg, Manu A. Thomas, Chelsea Thompson, Kostas Tsigaridis, Svetlana Tsyro, Steven T. Turnock, Knut von Salzen, David W. Tarasick

Summary: This study summarizes recent research on the observations and modeling of tropospheric ozone in the Arctic, revealing significant differences in the seasonal cycles of surface ozone at different locations. The 12 state-of-the-art models used in this study lack the necessary surface halogen chemistry to accurately simulate coastal Arctic surface ozone depletion. The multi-model median underestimates Arctic surface ozone by 5% to 15% depending on the location, and there is a wide variability among the models.

ATMOSPHERIC CHEMISTRY AND PHYSICS (2023)

Article Environmental Sciences

Mercury in the free troposphere and bidirectional atmosphere-vegetation exchanges - insights from Maido mountain observatory in the Southern Hemisphere tropics

Alkuin M. Koenig, Olivier Magand, Bert Verreyken, Jerome Brioude, Crist Amelynck, Niels Schoon, Aurelie Colomb, Beatriz Ferreira Araujo, Michel Ramonet, Mahesh K. Sha, Jean-Pierre Cammas, Jeroen E. Sonke, Aurelien Dommergue

Summary: This article investigates atmospheric mercury concentrations and redox reactions in the lower free troposphere, and finds a lack of continuous monitoring stations in the Southern Hemisphere. By analyzing data from the Maido mountain observatory for 9 months, it identifies significant diurnal and seasonal variations in atmospheric elemental mercury.

ATMOSPHERIC CHEMISTRY AND PHYSICS (2023)

Article Environmental Sciences

Nitrogen oxides in the free troposphere: implications for tropospheric oxidants and the interpretation of satellite NO2 measurements

Viral Shah, Daniel J. Jacob, Ruijun Dang, Lok N. Lamsal, Sarah A. Strode, Stephen D. Steenrod, K. Folkert Boersma, Sebastian D. Eastham, Thibaud M. Fritz, Chelsea Thompson, Jeff Peischl, Ilann Bourgeois, Ilana B. Pollack, Benjamin A. Nault, Ronald C. Cohen, Pedro Campuzano-Jost, Jose L. Jimenez, Simone T. Andersen, Lucy J. Carpenter, Tomas Sherwen, Mat J. Evans

Summary: Satellite-based retrievals of tropospheric NO2 columns are widely used to infer NOx emissions. These retrievals rely on model information for the vertical distribution of NO2. Free tropospheric background above 2 km is important for these retrievals and has a significant impact on tropospheric OH and ozone concentrations.

ATMOSPHERIC CHEMISTRY AND PHYSICS (2023)

Article Environmental Sciences

Probing the limits of sampling gaseous elemental mercury passively in the remote atmosphere

Christopher Hoang, Olivier Magand, Jerome Brioude, Andrea Dimuro, Christophe Brunet, Claudine Ah-Peng, Yann Bertrand, Aurelien Dommergue, Ying Duan Lei, Frank Wania

Summary: Reliably recording low GEM concentrations in remote regions is challenging. In this study, passive air samplers were deployed in extreme environments for up to three years. The size of the sequestered mercury and contamination of field blank samples influenced the reliable recording of GEM concentrations. Longer deployment periods and storage in sealed glass jars were found to be effective in reducing contamination. However, sampling in Antarctica was compromised due to extreme temperatures and material failure.

ENVIRONMENTAL SCIENCE-ATMOSPHERES (2023)

暂无数据