4.5 Article

Highly Efficient and Stable Inorganic Perovskite Quantum Dots by Embedding into a Polymer Matrix

期刊

CHEMNANOMAT
卷 5, 期 3, 页码 346-351

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cnma.201800357

关键词

stability; hot-injection method; water resistance; light-emitting diodes; cellular imaging

资金

  1. National Natural Science Foundation of China [11674127, 11674126, 21403084, 11774122]
  2. Jilin Province Science Fund for Excellent Young Scholars [20170520129JH]
  3. National Key Research and Development Program [2016YFC0207101]

向作者/读者索取更多资源

All-inorganic perovskite quantum dots (QDs) with high photoluminescence quantum yield, narrow spectral bandwidth, and broad spectral tunability have broad applications. However, perovskite QDs suffer from poor stability and the fast anion-exchange reaction between different halide ions. Herein, we embedded green-light-emitting CsPbBr3 QDs and red-light-emitting CsPb(Br/I)(3) QDs into carboxyl-containing polymethyl methacrylate (PMMA) by the hot-injection method. As a result, the as-prepared perovskite@PMMA composites not only retain high luminescence but also exhibit good water resistance. Moreover, this treatment prevents anion exchange between different halide QD particles in the solid state. The applications in light-emitting diodes and cellular labeling agents are also carried out to demonstrate their good stability.

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