Article
Chemistry, Multidisciplinary
Lei Xu, Xiaoxuan Wang, Honglan Shi, Bin Hua, Joel Gerald Burken, Xingmao Ma, Hu Yang, John J. Yang
Summary: This study investigated the effects of different nanoparticles on lettuce grown in soil and found that the co-interactions of nanoparticles can affect their accumulation and distribution in plants. Additionally, the size of nanoparticles varied between roots and shoots, possibly as a result of the dissolution of nanoparticles in the rhizosphere or the formation of transformed nanoparticles.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2022)
Article
Chemistry, Multidisciplinary
Naseer Ahmad, Sufian Rasheed, Muhammad Ikram Nabeel, Waqas Ahmad, Abrar Mohyuddin, Syed Ghulam Musharraf, Muhammad Najam-ul-Haq, Zafar Khan Ghouri, Dilshad Hussain
Summary: In this study, a fluorine-free, durable superhydrophobic cotton fabric with CeO2 nanoparticles and stearic acid was developed to mimic the lotus effect. The modified fabric exhibited high superhydrophobicity, self-cleaning, antiwater absorption, UV-blocking, and antibacterial properties. The proposed strategy is simple, green, economical, and has potential for commercial applications in functional fabric preparation.
Article
Biochemistry & Molecular Biology
Artem M. Ermakov, Vera A. Afanasyeva, Alexander V. Lazukin, Yuri M. Shlyapnikov, Elizaveta S. Zhdanova, Anastasia A. Kolotova, Artem S. Blagodatski, Olga N. Ermakova, Nikita N. Chukavin, Vladimir K. Ivanov, Anton L. Popov
Summary: This study investigates the combined use of cold argon plasma (CAP) and metal oxide nanoparticles for antibacterial treatment. The results demonstrate that the combination of CAP and redox-active metal oxide or metal fluoride nanoparticles effectively inhibits bacterial growth, damages DNA, and disrupts the cell wall. The combination of CAP and CeF3 nanoparticles shows the strongest antimicrobial effect on plasmid DNA, while the CAP and WO3 combination is most effective against bacterial genomic DNA. CeF3 nanoparticles exhibit strong antimicrobial and DNA-damaging properties for the first time.
Article
Environmental Sciences
Yuan-Qiang Lu
Summary: Acute cerium dioxide poisoning or damage is very rare, and this is the first report worldwide of acute oral poisoning due to cerium dioxide nanoparticles, with the patient recovering well after treatment.
ENVIRONMENTAL TOXICOLOGY AND PHARMACOLOGY
(2021)
Article
Biochemistry & Molecular Biology
Adrian Boey, Shu Qing Leong, Sayali Bhave, Han Kiat Ho
Summary: Exposure to metallic nanoparticles can lead to unintended accumulation in body tissues, with cerium oxide nanoparticles showing potential beneficial effects by reducing oxidative stress levels and TGF-beta-mediated signaling in liver cells. These findings suggest a therapeutic pathway for hepatic fibrosis.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2021)
Article
Nanoscience & Nanotechnology
Yuemei Li, Yongmei Li, Haoming Wang, Riyue Liu
Summary: Yb/Er/CeO2-x upconversion nanoparticles have shown promising antioxidative activities in the treatment of Parkinson's disease, with increased enzyme-like catalytic activities and reductions in ROS production in the brain, indicating their potential as a therapeutic option for PD.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Zhihao Liang, Xiaoqin Pan, Wei Li, Erfeng Kou, Yunyan Kang, Bingfu Lei, Shiwei Song
Summary: ZnO quantum dots have varying effects on lettuce growth and nutritional quality, with high concentrations leading to ROS production and reduced biomass, while moderate to low concentrations promote nutrient absorption and enhance nutritional quality.
Review
Biochemistry & Molecular Biology
Somu Yadav, Shivangi Chamoli, Piyush Kumar, Pawan Kumar Maurya
Summary: Cerium oxide nanoparticles have wide applications in biomedical fields, but their safety and biocompatibility pose challenges. Polysaccharides can be used as coatings for cerium oxide nanoparticles, affecting their properties. This review explores the impact of biopolymer coatings on size, stability, aggregation, and biocompatibility of cerium oxide nanoparticles, as well as their applications in bone tissue regeneration, liver inflammation, wound healing, and antibacterial and anticancer activities. Biocompatible cerium oxide nanoparticles will enhance their biomedical applications.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Biochemistry & Molecular Biology
Valentina A. Petrova, Natallia V. Dubashynskaya, Iosif V. Gofman, Alexey S. Golovkin, Alexander I. Mishanin, Arthur D. Aquino, Daria V. Mukhametdinova, Alexandra L. Nikolaeva, Elena M. Ivan'kova, Alexander E. Baranchikov, Alexander V. Yakimansky, Vladimir K. Ivanov, Yury A. Skorik
Summary: Polymeric nanocomposite materials have the potential to enhance tissue-engineered scaffolds by influencing the structure and properties of polymeric materials and regulating cell behavior. In this study, cerium oxide nanoparticles were incorporated into a chitosan film to promote the proliferation of mesenchymal stem cells. The resulting CS-CeONP films exhibited good biocompatibility and regenerative potential in both in vitro and in vivo experiments.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Polymer Science
Vasily V. Spiridonov, Andrey V. Sybachin, Vladislava A. Pigareva, Mikhail I. Afanasov, Sharifjon A. Musoev, Alexander V. Knotko, Sergey B. Zezin
Summary: An elegant method for synthesizing nanocomposites consisting of cerium-containing nanoparticles stabilized by carboxymethyl cellulose (CMC) macromolecules at room temperature was introduced in this study. The nanocomposites were characterized using microscopy, XRD, and IR spectroscopy analysis. The crystal structure of the inorganic nanoparticles, corresponding to CeO2, was determined and a mechanism for nanoparticle formation was proposed. The study demonstrated that the size and shape of the nanoparticles in the resulting nanocomposites were independent of the ratio of the initial reagents. Spherical particles with a mean diameter of 2-3 nm were obtained in different reaction mixtures with a cerium mass fraction ranging from 6.4% to 14.1%. The study also proposed a dual stabilization scheme for CeO2 nanoparticles involving carboxylate and hydroxyl groups of CMC. These findings suggest that the easily reproducible technique has promise for the large-scale development of nanoceria-containing materials.
Article
Biotechnology & Applied Microbiology
Shizue Yoshihara, Kasumi Yamamoto, Yoshino Nakajima, Kana Ibuchi, Toshiyuki Nomura, Kensuke Kurahashi, Hayato Tokumoto
Summary: This study found that engineered ZnO nanoparticles (NPs) exist in particle and ion states in aqueous solutions, and the phytotoxicity of ionizable metal oxide NP dispersions negatively affects root elongation. Exposure to ZnO NPs leads to accumulation of zinc in roots, inhibition of chlorophyll synthesis, and abnormal cell wall metabolism, which ultimately result in root elongation stagnation and plant death.
PLANT CELL TISSUE AND ORGAN CULTURE
(2023)
Article
Chemistry, Multidisciplinary
Vivek Pandey, Irfan Anjum Badruddin, Sarfaraz Kamangar, Addisu Bekele Alemayehu
Summary: Diesel fuel blends with biodiesels can mitigate the rising price and demand of conventional fuels, as well as reduce engine emissions. The addition of CeO2 nanoparticles in Calophyllum Inophyllum methyl ester biodiesel (CIMEBD) improves engine performance and emissions. Ceria NP-doped biodiesel shows better engine performance and lower emissions compared to diesel-biodiesel (BD) blend, with optimum ceria NP size in the range of 20-40 nm.
Article
Engineering, Biomedical
Waliya Zubairi, Saimoon Tehseen, Muhammad Nasir, Aqif Anwar Chaudhry, Ihtesham Ur Rehman, Muhammad Yar
Summary: This study reports the synthesis and neovascularization activity of cerium oxide and cerium peroxide nanoparticles loaded into chitosan and collagen hydrogel. The results suggest that cerium peroxide loaded material shows better pro-angiogenic behavior as compared to cerium oxide loaded materials, indicating its potential for treating chronic ulcers and burns.
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS
(2022)
Article
Medicine, Research & Experimental
Fereshteh Asgharzadeh, Alireza Hashemzadeh, Farzad Rahmani, Atieh Yaghoubi, Seyedeh Elnaz Nazari, Amir Avan, Seyed Mahdi Hasanian Mehr, Saman Soleimanpour, Majid Khazaei
Summary: The experimental study demonstrated that cerium oxide nanoparticles significantly reduced clinical symptoms of colitis, enhanced disease activity index, and effectively reduced tissue damage, suggesting a promising therapeutic effect in treating ulcerative colitis.
Article
Environmental Sciences
Vandita Anand, Anjana Pandey
Summary: This paper reports the green synthesis and characterization of CeO2 and SiO2 nanoparticles from leaf extracts of Nyctanthes arbor-tristis. The effects of these nanoparticles on blackgram plants were evaluated, and it was found that CeO2 and SiO2 nanoparticles enhanced plant growth by improving antioxidant enzymes and reducing superoxide radical and H2O2 levels. These findings suggest that the size and shape of CeO2 and SiO2 nanoparticles play a role in protecting against oxidative damage.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Multidisciplinary
Yixuan Wang, Ran Zhao, Xiao He, Zhe Zhang, Jingxin Meng, Shutao Wang
Summary: To survive in low oxygen water, water spiders collect and replenish air into their diving bell. Inspired by this strategy, researchers have developed a nanofiber coating that displays excellent and sustainable scalephobic capability underwater. This coating inhibits scale nucleation and reduces scale adhesion, resulting in a 98% reduction in scale deposition even after a month-long test. This air-replenishing strategy may lead to advanced long-term scalephobic materials.
ADVANCED MATERIALS
(2023)
Article
Environmental Sciences
Changjian Xie, Xiaowei Li, Zhiling Guo, Yuling Dong, Shujing Zhang, Ao Li, Shan Ma, Jianing Xu, Qiuxiang Pang, Willie J. G. M. Peijnenburg, Iseult Lynch, Peng Zhang
Summary: The toxicity of graphene oxide (GO) in aquatic systems was evaluated using the freshwater planarian Dugesia japonica. GO not only impaired the growth of normal worms, but also inhibited the regeneration processes of regenerating worms. High concentration of GO killed all the worms. Mechanistic analysis suggests that GO disturbed the antioxidative system and energy metabolism, causing oxidative damage and retardance of neuron regeneration.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
(2023)
Article
Engineering, Environmental
Kaini Yang, Xiangyu Wang, Iseult Lynch, Zhiling Guo, Peng Zhang, Lisi Wu, Jun Ma
Summary: An ultra-high NZVI-loaded PAN film with a unique 3D honeycomb structure was successfully designed and demonstrated excellent Cr(VI) removal activity and tolerance to coexisting ions. The film maintained a removal efficiency of over 80% even after long-term use.
JOURNAL OF HAZARDOUS MATERIALS
(2023)
Article
Environmental Sciences
Changjian Xie, Xiaowei Li, Lisha Hei, Yiqing Chen, Yuling Dong, Shujing Zhang, Shan Ma, Jianing Xu, Qiuxiang Pang, Iseult Lynch, Zhiling Guo, Peng Zhang
Summary: In this study, the toxic effects of cerium oxide nanoparticles (n-CeO2) on stem cells, tissue regeneration, and neuro-regeneration were investigated using freshwater planarian Dugesia japonica as a model. The study found that n-CeO2 not only disrupted the homeostasis of normal planarians, but also inhibited the regeneration processes of regenerated planarians. Ce3+ exhibited higher toxicity than n-CeO2.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Review
Chemistry, Multidisciplinary
Quanlong Wang, Peng Zhang, Weichen Zhao, Yuanbo Li, Yaqi Jiang, Yukui Rui, Zhiling Guo, Iseult Lynch
Summary: The development of nanotechnology and the widespread use of metal-based nanoparticles in consumer products have led to the release of nanoparticles into soil, particularly in agricultural systems. This review examines the interaction between metal-based nanoparticles and the plant rhizosphere microenvironment, using examples of commonly used nanoparticles such as Ag NPs and ZnO NPs. Factors such as soil pH, organic matter, microorganisms, and rhizosphere exudates can influence the behavior of nanoparticles in the environment. Moreover, nanoparticles can alter the soil chemistry and microbial properties in the rhizosphere, subsequently affecting their behavior and biological effects.
ENVIRONMENTAL SCIENCE-NANO
(2023)
Article
Chemistry, Multidisciplinary
Zhiling Guo, Peng Zhang, Changjian Xie, Evangelos Voyiatzis, Klaus Faserl, Andrew J. Chetwynd, Fazel Abdolahpur Monikh, Georgia Melagraki, Zhiyong Zhang, Willie J. G. M. Peijnenburg, Antreas Afantitis, Chunying Chen, Iseult Lynch
Summary: As antimicrobials, graphene materials (GMs) have potential advantages over traditional antibiotics. The antibacterial mechanism of GMs, whether it originates from parallel or perpendicular interactions or a combination of both, remains unclear. This study demonstrates that GMs with high surface oxygen content (SOC) predominantly attach in parallel to bacterial cell surfaces in suspension. The interaction mode shifts to perpendicular when the SOC reaches a threshold of around 0.3. These findings help to understand the different physical mechanisms leading to the antibacterial activity of GMs.
Article
Nanoscience & Nanotechnology
Mingshu Li, Li Gao, Jason C. White, Christy L. Haynes, Tana L. O'Keefe, Yukui Rui, Sami Ullah, Zhiling Guo, Iseult Lynch, Peng Zhang
Summary: Increasing the capacity of biological nitrogen fixation (BNF) is an effective strategy to enhance food security and reduce the carbon and nitrogen footprint of agriculture. Nanotechnology offers several pathways to successfully enhance BNF.
NATURE NANOTECHNOLOGY
(2023)
Article
Chemistry, Multidisciplinary
Mingshu Li, Peng Zhang, Zhiling Guo, Weidong Cao, Li Gao, Yuanbo Li, Chang Fu Tian, Qing Chen, Yunze Shen, Fazheng Ren, Yukui Rui, Jason C. White, Iseult Lynch
Summary: A single application of low-dose molybdenum disulfide nanoparticles (MoS2 NPs) can enhance soybean biological nitrogen fixation (BNF) and yield by 30%, compared to conventional molybdate fertilizer. MoS2 NPs can sustainably release molybdenum and enhance plant tolerance to abiotic stresses.
Article
Engineering, Environmental
Wu Cai, Peng Zhang, Xueci Xing, Lai Lyu, Han Zhang, Chun Hu
Summary: This study presents a synergetic strategy between microbes and dual-electric centers catalysts for treating water containing Ciprofloxacin. The catalyst cleaves Ciprofloxacin into small molecules and reduces the accumulation of antibiotic resistance genes, while promoting the expression of extracellular electron transfer-related genes.
Article
Chemistry, Multidisciplinary
Swaroop Chakraborty, Dhruv Menon, Venkata Sai Akhil Varri, Manish Sahoo, Raghavan Ranganathan, Peng Zhang, Superb K. Misra
Summary: Due to their excellent properties, ferrite nanoparticles are widely used for various applications. This study investigates the effects of doping ferrite nanoparticles with transition metal elements on their stability and toxicity. Monodispersed and phase pure ferrite variants were synthesized, and the results show that Co and Mn doping enhances dissolution, while Cu and Zn doping has the opposite effect. DFT calculations and cell viability tests further support the experimental data. Comparisons with other metal-oxide nanoparticles are also provided.
ENVIRONMENTAL SCIENCE-NANO
(2023)
Article
Chemistry, Multidisciplinary
Zhiling Guo, Peng Zhang, Changjian Xie, Evangelos Voyiatzis, Klaus Faserl, Andrew J. Chetwynd, Fazel Abdolahpur Monikh, Georgia Melagraki, Zhiyong Zhang, Willie J. G. M. Peijnenburg, Antreas Afantitis, Chunying Chen, Iseult Lynch
Summary: As antimicrobials, graphene materials (GMs) have potential advantages over traditional antibiotics due to their physical mechanisms of action, which reduce the chance of microbial resistance. This study shows that GMs with high surface oxygen content (SOC) primarily attach in parallel to the bacterial cell surface, while the interaction mode shifts to perpendicular when the SOC reaches a certain threshold. The rigidity of GMs is closely related to these distinct interaction modes. By understanding the interaction mode of GMs with bacteria, the antibacterial activity of GMs can be better understood.
Article
Engineering, Environmental
Fazel Abdolahpur Monikh, Willie Peijnenburg, Agnes G. Oomen, Eugenia Valsami-Jones, Vicki Stone, Raine Kortet, Jarkko Akkanen, Peng Zhang, Jukka Kekalainen, Alena Sevcu, Jussi V. K. Kukkonen
Summary: This paper provides an overview of the definition, categorization, challenges, and prospects of advanced materials (AdMas) in toxicology. Solutions for addressing AdMas are proposed, including the development of legal frameworks considering human and environmental risks and the use of classification to facilitate the identification of hazards associated with new AdMas.
ENVIRONMENTAL SCIENCE-ADVANCES
(2023)
Article
Environmental Sciences
Han Zhang, Chun Hu, Peng Zhang, Tong Ren, Wu Cai
Summary: The use of catalyst materials as biological fillers in wastewater treatment offers a new approach to enhance microbial degradation and achieve economic and energy saving benefits. In this study, the commonly used catalyst/carrier gamma-Al2O3 is used as a filler to treat kitchen-oil wastewater with low biodegradability, resulting in a COD removal rate of approximately 50%. The complexation of cationic vacancies on the surface of Al2O3 with extracellular polymeric substances (EPS) secreted by microorganisms in wastewater leads to the polarization of electron distribution on the biofilm. This enables efficient degrading bacteria to be enriched at the reaction interface, allowing them to obtain electrons and maintain electron dynamic balance, ultimately enhancing the degradation of pollutants. The aluminum vacancies on the surface of Al2O3 accelerate the microbial degradation process. The cationic vacancies in the catalyst structure facilitate the acquisition of exogenous electrons by microorganisms without the need for external energy, providing a new idea for improving wastewater degradation using catalytic fillers.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)