3.8 Article

Thermoelectric properties of Ca0.8Dy0.2MnO3 synthesized by solution combustion process

期刊

NANOSCALE RESEARCH LETTERS
卷 6, 期 -, 页码 -

出版社

SPRINGER
DOI: 10.1186/1556-276X-6-548

关键词

electrical conductivity; solution combustion process; Seebeck coefficient; power factor; Ca0.8Dy0.2MnO3

资金

  1. Ministry of Knowledge and Economy (MKE), Republic of Korea
  2. Korea Evaluation Institute of Industrial Technology (KEIT) [2008EAPHMP250000] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  3. National Research Foundation of Korea [핵C6A1501] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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High-quality Ca0.8Dy0.2MnO3 nano-powders were synthesized by the solution combustion process. The size of the synthesized Ca0.8Dy0.2MnO3 powders was approximately 23 nm. The green pellets were sintered at 1150-1300 degrees C at a step size of 50 degrees C. Sintered Ca0.8Dy0.2MnO3 bodies crystallized in the perovskite structure with an orthorhombic symmetry. The sintering temperature did not affect the Seebeck coefficient, but significantly affected the electrical conductivity. The electrical conductivity of Ca0.8Dy0.2MnO3 increased with increasing temperature, indicating a semiconducting behavior. The absolute value of the Seebeck coefficient gradually increased with an increase in temperature. The highest power factor (3.7 x 10(-5) Wm(-1) K-2 at 800 degrees C) was obtained for Ca0.8Dy0.2MnO3 sintered at 1,250 degrees C. In this study, we investigated the microstructure and thermoelectric properties of Ca0.8Dy0.2MnO3, depending on sintering temperature.

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