期刊
NANO ENERGY
卷 53, 期 -, 页码 83-90出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2018.08.038
关键词
Flexible photovoltaics; Silicon nanowires; Radial p-i-n junction; Thin film solar cells; Power-to-weight ratio; Aluminum foil
类别
资金
- National Key Research and Development Program of China [2016YFA0202102, 2017YFA0205003]
- National Natural Science Foundation of China (NSFC) [61674075]
- Jiangsu Excellent Young Scholar Program [BK20160020]
- Scientific and Technological Support Program in Jiangsu province [BE2014147-2]
- Jiangsu Shuangchuang Team's Personal Program
- Fundamental Research Funds for the Central Universities
Flexibility and power-to-weight (PTW) ratio are the key factors for promoting wearable or portable solar cell applications. Planar hydrogenated amorphous silicon (a-Si: H) thin films deposited directly on soft aluminum foils (AF) are usually subject to easy cracking and delamination due to the mechanical instability on AF surface. Here, an exceptionally robust three-dimensional (3D) construction of a-Si: H radial p-i-n junction solar cells on soft supermarket-available AF of 15 mu m thick is reported, where the discrete and firmly standing Si nanowire (SiNW) cores, grown and rooted on the soft AF surface, frame up a 3D architecture that protects the protrusive photo-active radial junctions from the unstable a-Si/Al bottom layer. An excellent flexibility and integrity of the 3D a-Si: H radial junctions have been achieved, even under bending to radius of 5 mm. Remarkably, without any diffusion barrier protection, a power conversion efficiency of 5.6% has been recorded, with an open-circuit voltage of 0.71 V and photo-current density of 14.2 mA/cm(2), leading to a high PTW ratio of > 1300 W/kg. Importantly, the overall fabrication cost can be largely slashed off, by similar to 46% compared to conventional a-Si: H solar cells, as the need for a bottom TCO contact/texturing layer, for a back-reflection coating and for a glass/polymer substrate are all exempted.
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