4.6 Article

One-step technique for production of bi-functional low molecular semiconductor-polymer composites for flexible OFET applications

期刊

JOURNAL OF MATERIALS CHEMISTRY C
卷 1, 期 19, 页码 3190-3193

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3tc30163j

关键词

-

资金

  1. EU [7FR]
  2. START project of Foundation for Polish Science
  3. Polish Ministry of Science [N N507 399939]

向作者/读者索取更多资源

A novel one-step solution based technique to produce bi-functional semiconductor-dielectric composites for organic field effect transistor (OFET) applications has been developed. By changing the parameters and components, one can produce the composites with semiconductors on the top or at the bottom of the polymer film suitable for fabrication of OFETs with n-or p-type channels and with top and bottom configurations of electrodes.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Review Chemistry, Multidisciplinary

Organic Semiconductor/Insulator Blends for Elastic Field-Effect Transistors and Sensors

Lukasz Janasz, Michal Borkowski, Paul W. M. Blom, Tomasz Marszalek, Wojciech Pisula

Summary: Organic semiconductors face limitations in their practical applicability due to low environmental stability and poor charge carrier mobilities. Blending with thermoplastic polymers and elastomers can overcome these restrictions and induce new material properties, showcasing great potential for flexible and stretchable electronics. Improved device properties such as charge carrier mobility, life-time, sensing ability, and mechanical behavior are achieved through blending with insulators, offering promise for various electronic devices and semiconductor classes.

ADVANCED FUNCTIONAL MATERIALS (2022)

Article Engineering, Electrical & Electronic

Flexible photovoltaic cells based on two-dimensional materials and their hybrids

Pawel J. Kowalczyk, Pawel Krukowski, Dorota A. Kowalczyk, Katarzyna Pabianek, Iaroslav Lutsyk, Maciej Rogala, Pawel Dabrowski, Adam Busiakiewicz, Michatl Piskorski, Witold Kozlowski, Beata Luszczynska, Ruslana Udovytska, Jaroslaw Jung, Jacek Ulanski, Jacek Baranowski, Simon A. Brown, Guang Bian

Summary: This study demonstrates that the graphene work function can be increased by adding a layer of molybdenum or rhenium oxides, and a single layer of MoO3-x can also increase the work function of graphene. This provides potential for practical applications of graphene in electronics.

PRZEGLAD ELEKTROTECHNICZNY (2022)

Article Engineering, Electrical & Electronic

Thermal removing the primary coating layer from the fiber optic surface

Piotr Weglarski, Jaroslaw Jung

Summary: The article introduces a new technology for thermal removal of the acrylic coating layer from optical fibers, determining the decomposition temperature of the coating and designing a prototype device for automatic removal of protective layers from optical fibers terminals. The efficiency of the proposed method and device is compared with existing systems, showing faster removal of acrylic layers while maintaining good quality of optical fibers.

PRZEGLAD ELEKTROTECHNICZNY (2022)

Article Materials Science, Multidisciplinary

Polarization-Sensitive Photodetectors Based on Directionally Oriented Organic Bulk-Heterojunctions

Aleksandr Perevedentsev, Hadhemi Mejri, Luis A. Ruiz-Preciado, Tomasz Marszalek, Uli Lemmer, Paul W. M. Blom, Gerardo Hernandez-Sosa

Summary: This report introduces polarized organic photodetectors based on directionally oriented blends of poly(3-hexylthiophene) and benchmark polymer or nonfullerene acceptors. A novel postprocessing scheme is advanced to ameliorate high dark-currents. The resulting polarized photodetectors exhibit broad enhancement in performance and show potential in photoelasticity analysis.

ADVANCED OPTICAL MATERIALS (2022)

Article Chemistry, Multidisciplinary

Mechanical Fatigue Resistance of Polydiketopyrrolo-Pyrrole-Dithienylthieno[3,2-b]thiophene-Based Flexible Field-Effect Transistors

Pawel Kubik, Witold Waliszewski, Andrzej Nosal, Mariusz Tomczyk, Adrian Adamski, Maciej Gazicki-Lipman, Paul W. M. Blom, Tomasz Marszalek, Wojciech Pisula

Summary: This study reports the fatigue behavior of flexible transistors based on semiconducting polymers. The transistors show high operational stability and reliability, despite the presence of mechanical defects in thin polymer films.

ADVANCED MATERIALS INTERFACES (2022)

Editorial Material Chemistry, Multidisciplinary

Editorial: Molecular Design and Morphology Control of Semiconducting Polymers for High-Performance Transistors and Photovoltaics

Mengmeng Li, Haijun Bin, Tomasz Marszalek

FRONTIERS IN CHEMISTRY (2022)

Article Multidisciplinary Sciences

Fully inkjet-printed flexible organic voltage inverters as a basic component in digital NOT gates

Adam Luczak, Kalyan Y. Mitra, Reinhard R. Baumann, Ralf Zichner, Beata Luszczynska, Jaroslaw Jung

Summary: Inkjet printing is a scalable fabrication method for basic electronic elements. The study demonstrates fully inkjet printed flexible electronic circuits, including an organic voltage inverter acting as a NOT logic gate. The printed circuits show stable electrical parameters even after three years of storage under ambient conditions.

SCIENTIFIC REPORTS (2022)

Article Biochemistry & Molecular Biology

Photoinduced Amyloid Fibril Degradation for Controlled Cell Patterning

Kuebra Kaygisiz, Adriana M. Ender, Jasmina Gacanin, L. Alix Kaczmarek, Dimitrios A. Koutsouras, Abin N. Nalakath, Pia Winterwerber, Franz J. Mayer, Hans-Joachim Rader, Tomasz Marszalek, Paul W. M. Blom, Christopher Synatschke, Tanja Weil

Summary: This study introduces photoresponsive amyloid-like fibrils as adaptive functional materials to precisely arrange cells on surfaces.

MACROMOLECULAR BIOSCIENCE (2023)

Article Biochemistry & Molecular Biology

Molecular Dynamics and Structure of Poly(Methyl Methacrylate) Chains Grafted from Barium Titanate Nanoparticles

Aleksandra Wypych-Puszkarz, Onur Cetinkaya, Jiajun Yan, Ruslana Udovytska, Jaroslaw Jung, Jacek Jenczyk, Grzegorz Nowaczyk, Stefan Jurga, Jacek Ulanski, Krzysztof Matyjaszewski, Joanna Pietrasik, Marcin Kozanecki

Summary: Core-shell nanocomposites consisting of barium titanate nanocrystals grafted onto poly(methyl methacrylate) chains were prepared. The nanocomposites exhibited enhanced dielectric permittivity and improved thermal stability. The presence of ceramic nanoparticles affected the molecular dynamics and structure of the polymer chains.

MOLECULES (2022)

Article Materials Science, Multidisciplinary

Role of oxygen within end group substituents on film morphology and charge carrier transport in thiophene/phenylene small-molecule semiconductors

Witold Waliszewski, Zachary S. Parr, Agnieszka Michalska, Roman Halaksa, Hanna Zajaczkowska, Piotr Sleczkowski, Marios Neophytou, Beata Luszczynska, Paul W. M. Blom, Christian B. Nielsen, Tomasz Marszalek, Wojciech Pisula

Summary: In this study, the impact of end group polarity on the thin film morphology, crystallinity and charge carrier transport of PTTPs was investigated. The results showed that increasing the substrate temperature improves the effective charge carrier mobility by promoting higher film crystallinity and larger grains. The polarity of the end groups also influences the effective mobility, with higher polar groups leading to lower mobility. Additionally, the reliability factor differs for different end groups. The insights gained from this study are important for the implementation of PTTP derivatives in various organic electronic devices.

ORGANIC ELECTRONICS (2022)

Article Polymer Science

The structure and dynamics of bottlebrushes: Simulation and experimental studies combined

Wojciech Raj, Krzysztof Halagan, Slawomir Kadlubowski, Paulina Maczugowska, Kosma Szutkowski, Jaros law Jung, Joanna Pietrasik, Stefan Jurga, Andrzej Sikorski

Summary: A new simulation method was used to study the complex macromolecular structure of bottlebrushes, and its applicability was confirmed by comparing with experimental results. Experimental techniques such as gel permeation chromatography - multiangle laser light scattering, pulsed-field gradient spin echo nuclear magnetic resonance, and static and dynamic light scattering were used for characterization. The research findings contribute to a better understanding of the properties and behavior of bottlebrushes.

POLYMER (2022)

Article Engineering, Electrical & Electronic

Influence of heat treatment on H2S gas sensing features of NiO thin films deposited via thermal evaporation technique

Davoud Dastan, Ke Shan, Azadeh Jafari, Tomasz Marszalek, Mustafa K. A. Mohammed, Lin Tao, Zhicheng Shi, Yingxin Chen, Xi -Tao Yin, Najlaa D. Alharbi, Farzan Gity, Somayeh Asgary, Mohammad Hatamvand, Lida Ansari

Summary: In this study, NiO thin films were prepared on Ni foil using thermal evaporation method to investigate their structural, morphological and H2S gas sensing properties. XRD analysis revealed a FCC phase with preferred (111) and (200) Bragg reflections. Increasing the oxidation temperature led to an increase in crystallite size and size of nanoclusters on the film surface. EDS patterns showed an increase in O peak intensity with increasing oxidation temperature, indicating enhanced oxygen content. Raman spectrum revealed Ni-O vibrations in the thin films. Gas sensing results demonstrated sensitivity to 20 ppm H2S at 700 degrees C and no significant change in response for higher concentrations. The deposition temperature influenced the response of the sensors.

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING (2023)

Article Chemistry, Physical

Symmetry-breaking charge transfer and intersystem crossing in copper phthalocyanine thin films

Esther del Pino Rosendo, Okan Yildiz, Wojciech Pisula, Tomasz Marszalek, Paul W. M. Blom, Charusheela Ramanan

Summary: Intermolecular interactions in pi-stacked chromophores strongly influence their photophysical properties, and thereby also their function in photonic applications. The photophysical properties differ based on the molecular organization of alpha-CuPc and beta-CuPc, both in solution and in thin film.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2023)

Article Materials Science, Multidisciplinary

Continuity of thin layers of an organic semiconductor induced by the modification of the gate insulator

Adam Luczak, Witold Waliszewski, Krzysztof Jerczynski, Aleksandra Wypych-Puszkarz, Jacek Rogowski, Joanna Pietrasik, Marcin Kozanecki, Jacek Ulanski, Krzysztof Matyjaszewski

Summary: This study explores the unusual improvement in the performance of organic field effect transistors by adding a very small amount (below 1 wt%) of hybrid nanoparticles containing TiO2 to the gate dielectric poly(methyl methacrylate) (PMMA). The presence of these hybrid nanoparticles increases the roughness of the dielectric layers and creates spikes which act as heterogeneous nucleation centers for the crystallizing semiconductor. As a result, even ultrathin layers of the semiconductor can form continuous crystalline domains.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Materials Science, Multidisciplinary

Translating efficient fluorescence into persistent room-temperature phosphorescence by doping bipolar fluorophores into polar polymer matrix

Mengjiao Dong, Liyun Liao, Chensheng Li, Yingxiao Mu, Yanping Huo, Zhong-Min Su, Fushun Liang

Summary: This study investigates the influence of the polarity of polymer matrices on persistent room-temperature phosphorescence (pRTP). It is discovered that intense phosphorescence emission can be achieved in highly polar matrices such as polyacrylic acid (PAA). The dipole-dipole interaction between the polar fluorophore and polar matrix is proposed to stabilize the excited state and facilitate the generation of efficient room-temperature phosphorescence emissions.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

High spatial resolution X-ray scintillators based on a 2D copper(i) iodide hybrid

Han-Jiang Yang, Weijia Xiang, Xiangzhou Zhang, Jin-Yun Wang, Liang-Jin Xu, Zhong-Ning Chen

Summary: This article reports a 2D copper(I)-based cluster material for X-ray imaging, which exhibits ultra-high spatial resolution, high photoluminescence efficiency, and low detection limit. The material shows excellent linear response to X-ray dose rates and light output, and has the best spatial resolution among reported lead-free metal halide hybrids.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Review Materials Science, Multidisciplinary

Interlayer and intermolecular excitons in various donor-acceptor heterostructures: applications to excitonic devices

Taek Joon Kim, Sang-hun Lee, Dayeong Kwon, Jinsoo Joo

Summary: Donor-acceptor heterostructures using organic-inorganic halide perovskites, two-dimensional transition metal dichalcogenides, pi-conjugated organic small/macro molecules, and quantum dots are promising platforms for exciton-based photonics and optoelectronics. Hetero-interlayer excitons and hetero-intermolecular excitons formed through optical and/or electrical charge transfer in various heterostructures are important quasi-particles for light emission, detection, and harvesting systems.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Designing CMOS compatible efficient ohmic contacts to WSi2N4 via surface-engineered Mo2B monolayer electrodes

Liemao Cao, Xiaohui Deng, Zhen-kun Tang, Rui Tan, Yee Sin Ang

Summary: We investigate the interface properties between WSi2N4 and Mo2B, O-modified Mo2B, and OH-modified Mo2B nanosheets. We find that WSi2N4 and Mo2B form n-type Schottky contacts, while functionalizing Mo2B with O and OH leads to the formation of both n-type and p-type ohmic contacts with WSi2N4. Additionally, we demonstrate the emergence of quasi-ohmic contact with ultralow lateral Schottky barrier and zero vertical interfacial tunneling barriers in Mo2B(OH)2-contacted WSi2N4.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Soft nanocomposites of lead bromide perovskite and polyurethane prepared via coordination chemistry for highly flexible, stable, and quaternary metal alloy-printed light emitting diodes

Ga Eun Kim, Hae-Jin Kim, Heesuk Jung, Minwoo Park

Summary: This study presents a solution to the commercialization challenges of flexible LEDs based on MAPbBr(3) by incorporating polyurethane and an In-Ga-Zn-Sn liquid alloy. The designed devices showed high flexibility, efficiency, and durability, with improved electron injection and reduced defects, making them promising for next-generation displays.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Elucidating the effects of the sidechain substitution direction on the optoelectronic properties of isomeric diketopyrrolopyrrole-based conjugated polymers for near-infrared organic phototransistors

Tao Shen, Zeng Wu, Zhen Jiang, Dongsheng Yan, Yan Zhao, Yang Wang, Yunqi Liu

Summary: Sidechain engineering is an important molecular design strategy for tuning the solid-state packing and structural ordering of conjugated polymers. The effects of sidechain direction on the optoelectronic properties of polymers and device performance were systematically investigated in this study. The results demonstrate that tuning the sidechain substitution direction can effectively improve the molecular structure and light absorption properties of polymers, providing new insights for the rational design of functional polymers.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Phase-engineering compact and flexible CsPbBr3 microcrystal films for robust X-ray detection

Lotte Clinckemalie, Bapi Pradhan, Roel Vanden Brande, Heng Zhang, Jonathan Vandenwijngaerden, Rafikul Ali Saha, Giacomo Romolini, Li Sun, Dirk Vandenbroucke, Mischa Bonn, Hai I. Wang, Elke Debroye

Summary: In this study, a facile strategy using a non-conductive polymer was proposed to fabricate stable, pinhole-free thick films. The effect of introducing a second phase into CsPbBr3 perovskite crystals on their photophysical properties and charge transport was investigated. The dual phase devices exhibited improved stability and more effective operation at higher voltages in X-ray detection.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Photoluminescence and structural phase transition relationship in Er-doped BaTiO3 model ferroelectric system

Jingye Zou, Shenglan Hao, Pascale Gemeiner, Nicolas Guiblin, Omar Ibder, Brahim Dkhil, Charles Paillard

Summary: When rare-earth ions are embedded in a ferroelectric material, their photoluminescence can serve as an all-optical probe for temperature, electric field, and mechanical stimulus. However, the impact of ferroelectric phase transitions on photoluminescence is not well understood. In this study, we demonstrate changes in the photoluminescence of green emission bands during critical ferroelectric transitions in an Er-doped BaTiO3 material. We also find that the intensity ratio and wavelength position difference of sub-peaks provide information on the phase transitions.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Resonant tunneling induced large magnetoresistance in vertical van der Waals magnetic tunneling junctions based on type-II spin-gapless semiconductor VSi2P4

Jiangchao Han, Daming Zhou, Wei Yang, Chen Lv, Xinhe Wang, Guodong Wei, Weisheng Zhao, Xiaoyang Lin, Shengbo Sang

Summary: Rare type-II spin-gapless semiconductors (SGSs) have attracted increasing attention due to their unique spin properties. In this study, the interface contacts and spin transport properties of different devices composed of VSi2P4 ferromagnetic layers were investigated. The results show that VSi2P4 is a promising material for designing vertical van der Waals heterostructures with a giant tunnel magnetoresistance (TMR) in spintronic applications.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Design of Cr-Ba-doped γ-Ga2O3 persistent luminescence nanoparticles for ratiometric temperature sensing and encryption information transfer

Tianqi Zhao, Renagul Abdurahman, Qianting Yang, Ruxiangul Aiwaili, Xue-Bo Yin

Summary: In this study, we designed and prepared Cr and Ba-doped gamma-Ga2O3 nanoparticles to achieve near-infrared emission and enhance the emission intensity. The emission mechanism was proposed based on the trap depth, band gap, and energy levels of Cr ions. The ratiometric temperature sensing and encryption information transfer demonstrated the potential applications of this technology.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Spin-gapless semiconducting characteristics and related band topology of quaternary Heusler alloy CoFeMnSn

Shuvankar Gupta, Jyotirmoy Sau, Manoranjan Kumar, Chandan Mazumdar

Summary: In this study, a new spin-gapless semiconductor material CoFeMnSn is reported, and its stable structure and spin-polarized band structure are determined through experimental realization and theoretical calculations. The compound exhibits a high ferromagnetic transition temperature, making it excellent for room temperature applications. The nearly temperature-independent resistivity, conductivity, and carrier concentration of the compound, adherence to the Slater-Pauling rule, and the high intrinsic anomalous Hall conductivity achieved through hole doping further confirm its spin-gapless semiconductor nature. Additionally, the compound's SGS and topological properties make it suitable for spintronics and magneto-electronics devices.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Two-dimensional metal-organic nanosheets composed of single-molecule magnets: structural modulation and enhanced magnetism utilizing the steric hindrance effect

Ikumi Aratani, Yoji Horii, Yoshinori Kotani, Hitoshi Osawa, Hajime Tanida, Toshiaki Ina, Takeshi Watanabe, Yohko F. Yano, Akane Mizoguchi, Daisuke Takajo, Takashi Kajiwara

Summary: In this study, two-dimensional arrays of single-molecule magnets (SMMs) based on metal-organic frameworks (MOFs) were systematically modified through Langmuir-Blodgett methods and chemical modifications. The introduction of bulky alkoxide groups induced structural changes and perpendicular magnetic anisotropy. This research provides a promising strategy for the construction of high-density magnetic memory devices using molecular spintronics.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Eulytite-type Ba3Yb(PO4)3:Tm/Er/Ho as a high sensitivity optical thermometer over a broad temperature range

Zonghao Lei, Houhe Dong, Lijie Sun, Bing Teng, Yanfei Zou, Degao Zhong

Summary: Researchers have successfully developed four different up-conversion phosphors based on the Eulytite-type host Ba3Yb(PO4)(3). The optical temperature sensing properties of these phosphors were thoroughly investigated, and it was found that Ba3Yb(PO4)(3):Tm/Er/Ho showed potential for optical temperature measurement applications.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Understanding trends in conductivity in four isostructural multifunctional crystals of Se substituted bis-dithiazolyl radicals

C. Roncero-Barrero, M. A. Carvajal, J. Ribas-Arino, I. de P. R. Moreira, M. Deumal

Summary: This study computationally investigates the conductivity of four isostructural compounds with different Se contents, and reveals the parameters that define their conductivity in stable organic radical materials. The results provide insights into the influence of Se content on the conductivity and highlight the importance of considering multiple parameters in understanding the trends in conductivity.

JOURNAL OF MATERIALS CHEMISTRY C (2024)

Article Materials Science, Multidisciplinary

Interplay between oxygen vacancies and cation ordering in the NiFe2O4 spinel ferrite

Remi Arras, Kedar Sharma, Lionel Calmels

Summary: In this study, we investigated the interplay between structural defects in NiFe2O4, showing that the complex formed by a Ni-Oh/Fe-Td-cation swap and a neutral oxygen vacancy is more stable than these two isolated defects, and significantly reduces the width of the minority-spin band gap.

JOURNAL OF MATERIALS CHEMISTRY C (2024)