期刊
JOURNAL OF MATERIALS CHEMISTRY C
卷 1, 期 4, 页码 617-620出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2tc00439a
关键词
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资金
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT) Korea [23750208]
- CASIO Science Promotion Foundation
- Konica Minolta Science and Technology Foundation
- Futaba Electronics Memorial Foundation
- Grants-in-Aid for Scientific Research [13J07191, 23750208] Funding Source: KAKEN
A multifunctional composite film that exhibited thermoresponsive absorption and emission was fabricated using a thermochromic fluoran dye, its developer, and a luminescent europium(III) complex. The emissions from and coloration of this composite film could be reversibly changed and maintained via the thermochromic reaction taking place with in the fluoran dye-developer system. The coloration and decoloration of the composite film were caused by thermoresponsive control of the nanoscale aggregation of structures of the fluoran dye and its developer, whose molecular structure consisted of a long alkyl chain. The control of the phenomenon of photoluminescence could also be achieved via thermochromism, which was induced by intermolecular energy transfer from the Eu(III) ions in the excited state to the fluoran dye.
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