Article
Chemistry, Physical
Bo Sun, Sibo Wang, Xiao Li, Wei Zhang, Jiao Li, Qingqing Pan, Fangbin Liu, Zhongmin Su
Summary: Developing stable and efficient electrocatalysts for clean energy production has been achieved through the preparation of nickel and Mo2C nanoparticles coated with N-doped carbon layers. The resulting Ni/Mo2C@NC electrocatalyst exhibits excellent electrocatalytic hydrogen generation activity and stability. This article presents a general approach for preparing transition metal combined molybdenum carbide electrocatalysts for sustainable energy generation and conversion.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Chemistry, Multidisciplinary
Qiuyue Chen, Xuguang An, Qian Liu, Xiaoqiang Wu, Lisi Xie, Jing Zhang, Weitang Yao, Mohamed S. Hamdy, Qingquan Kong, Xuping Sun
Summary: In this study, Cu2O particles self-supported on Cu foam with enriched oxygen vacancies were developed as efficient catalysts for selective reduction of nitrite to ammonia. The catalyst exhibited a high NH3 yield rate and Faradaic efficiency under experimental conditions, providing a new approach for rational design of Cu-based catalysts for NH3 electrosynthesis.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Mingxiu Duan, Tie Shu, Jingwei Li, Daliang Zhang, Li-Yong Gan, Ke Xin Yao, Qiang Yuan
Summary: Efficient and durable electrocatalysts with highly dispersed Ru clusters anchored on Na+, K+-decorated porous carbon have been successfully prepared through hydrothermal and annealing treatment. The resulting Ru/Na+, K+-PC exhibits ultralow overpotential, high mass activity, and long-term durability, surpassing commercial Pt/C benchmark. Density functional theory calculations suggest that the presence of Na and K ions efficiently decreases the energy barrier for H-OH bond breaking, favoring the Volmer step.
Article
Electrochemistry
Wenjie Jiang, Jinli Chen, Guangfu Qian, Huibing He, Hao Zhang, Xiaoyan Zhuo, Fang Shen, Lin Luo, Shibin Yin
Summary: In this study, a novel strategy for designing low-cost and stable catalysts for electrochemical hydrogen production was reported. The worm-like Co5.47N decorated WO2 hybrids self-supported on nickel foam with carbon encapsulated structure exhibited excellent activity for hydrogen and oxygen evolution reaction. Experimental results showed high stability and small overpotentials for overall water splitting, highlighting the potential of this catalyst for practical applications.
ELECTROCHIMICA ACTA
(2021)
Article
Chemistry, Multidisciplinary
Tianmi Luo, Jianfeng Huang, Yuzhu Hu, Chengke Yuan, Junsheng Chen, Liyun Cao, Koji Kajiyoshi, Yijun Liu, Yong Zhao, Zhenjiang Li, Yongqiang Feng
Summary: This study develops a design of electrocatalysts with high efficiency, low cost and large current output suitable for water electrolysis. The optimized product shows outstanding electrocatalytic performance and robust durability. This research provides a new clue for the construction of novel electrocatalyst in the field of energy storage and conversion.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Songsong Li, Lu Wang, Hui Su, Anh N. Hong, Yanxiang Wang, Huajun Yang, Lei Ge, Weiyu Song, Jian Liu, Tianyi Ma, Xianhui Bu, Pingyun Feng
Summary: This study reports the synthesis of high efficiency electrocatalysts based on S-doped NiFeP and improves the reaction performance by tuning the electronic structure. The research provides a new strategy for designing highly active non-noble metal catalysts.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Sankar Sekar, Dae Hyun Sim, Sejoon Lee
Summary: In this study, high-performance partially graphitized activated-carbon nanobundles were synthesized through high-temperature KOH activation of biomass human hair ashes, serving as efficient electrocatalysts for hydrogen evolution reaction (HER).
Article
Chemistry, Multidisciplinary
Kai Song, Huanhuan Zhang, Zhiping Lin, Zongpeng Wang, Lili Zhang, Xinxing Shi, Shijie Shen, Shichang Chen, Wenwu Zhong
Summary: Novel CoPS3/CoS2 heterojunctions were successfully created through an intuitive phosphatization process. The significant stress effect and interface interaction at these heterojunctions improved the catalyst's electronic structure, exposure of active sites, electrical conductivity, and hydrogen adsorption capabilities. The CoPS3/CoS2 heterojunction exhibited superior electrocatalytic activity for hydrogen evolution reaction.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Xin Wang, Jun Wang, Bin Wei, Nan Zhang, Junyuan Xu, Hongwei Miao, Lifeng Liu, Chenliang Su, Ying Li, Zhongchang Wang
Summary: Defect engineering in ultrathin tungsten telluride nanosheets improves hydrogen evolution by introducing tungsten vacancies through oxygen plasma etching, leading to a significant reduction in overpotential and Tafel slope for more efficient performance.
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Physical
Qianqian Du, Ruihua Zhao, Tianyu Guo, Lu Liu, Xiaojun Chen, Jie Zhang, Jianping Du, Jinping Li, Liqiang Mai, Tewodros Asefa
Summary: This study reports a successful synthesis of Mo2C nanodots electrocatalyst by dispersing nanodots in 3D cage-like carbon microparticles using rationally designed Mo-based xerogels as precursors. The process maintains the structure while demonstrating excellent electrocatalytic activity and relative stability. The work also shows a promising synthetic route and procedure for other well-dispersed yet stable nanocatalysts.
Article
Chemistry, Multidisciplinary
Minghui Ning, Fanghao Zhang, Libo Wu, Xinxin Xing, Dezhi Wang, Shaowei Song, Qiancheng Zhou, Luo Yu, Jiming Bao, Shuo Chen, Zhifeng Ren
Summary: Electrochemical reconstruction was used to synthesize bifunctional catalysts Fe-0.01-Ni&Ni0.2Mo0.8N and Fe-0.01&Mo-NiO with state-of-the-art HER and OER performance. The electrolyzer based on these catalysts exhibited record-high performance for seawater electrolysis and good durability under harsh industrial conditions.
ENERGY & ENVIRONMENTAL SCIENCE
(2022)
Article
Chemistry, Multidisciplinary
Xiaoli Jiang, Haeseong Jang, Shangguo Liu, Zijian Li, Min Gyu Kim, Chuang Li, Qing Qin, Xien Liu, Jaephil Cho
Summary: This study addresses the crucial challenges in improving the hydrogen evolution reaction in alkaline media by synthesizing a Ru2P/WO3@NPC heterostructure electrocatalyst. The catalyst demonstrates outstanding HER activity and durability, outperforming state-of-the-art Pt/C, with electron density redistribution promoting water dissociation and hydrogen desorption on specific sites within the catalyst.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Tang Tang, XiaoZhi Liu, Xuan Luo, Zhuangzhuang Xue, Hai-Rui Pan, Jiaju Fu, Ze-Cheng Yao, Zhe Jiang, Zhen-Hua Lyu, Lirong Zheng, Dong Su, Jia-Nan Zhang, Liang Zhang, Jin-Song Hu
Summary: By embedding sub-nanometer Ir clusters in graphene-loaded high-density Ni nanocrystals, an unconventional bilateral compressive strained Ni-Ir interface is achieved, which exhibits efficient synergistic HOR sites. The Ni-Ir(BCS)/G catalyst shows significantly enhanced HOR activity with 7.95 and 2.88 times higher mass activity than commercial Ir/C and Pt/C, respectively, along with improved CO tolerance, making it one of the most active state-of-the-art HOR catalysts.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Xiaobin Liu, Xudong Zhao, Li-Zhen Fan
Summary: The study introduces a controllable strategy for preparing cobalt-nickel alloy nanoparticles encapsulated in nitrogen-doped porous carbon through annealing a bimetal-organic framework. The optimized hierarchical Co2Ni@NC nanoparticles exhibit abundant synergistic active sites for the oxygen evolution reaction (OER) with a small overpotential and excellent long-term stability in alkaline electrolyte. Density functional theory calculations elucidate the underlying synergistic effect mechanism of the Co-Ni model.
Article
Chemistry, Physical
Yanlin Qin, Yunzhen Chen, Xuezhi Zeng, Yingchun Liu, Xuliang Lin, Wenli Zhang, Xueqing Qiu
Summary: In this study, carboxymethylated enzymatic hydrolysis lignin (EHL) was used as a biomacromolecule frame to improve the electrocatalytic activity and stability of molybdenum nickel alloy. The results showed that the MoNi4-NiO heterojunction improved the overpotentials and stability of the hydrogen evolution reaction. This work provided an effective strategy for improving the performance of noble-metal-free electrocatalysts.
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Multidisciplinary
Nan Yan, Yan Gao, Junjie Yang, Zhimin Fang, Jiangshan Feng, Xiaojun Wu, Tao Chen, Shengzhong (Frank) Liu
Summary: To improve the efficiency of wide-band gap perovskite solar cells, the issue of open-circuit voltage deficit needs to be addressed. By passivating the perovskite surface with ammonium salts, the V-oc deficit can be effectively reduced. Surface gradient passivation using p-FPEAI demonstrates the most efficient passivation effect, leading to a record-efficiency of 21.63%.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Lifeng Wang, Naiqing Ren, Yu Yao, Hai Yang, Wei Jiang, Zixu He, Yang Jiang, Shuhong Jiao, Li Song, Xiaojun Wu, Zhong-Shuai Wu, Yan Yu
Summary: A stable solid electrolyte interphase (SEI) composition, sodium bromide (NaBr), was predicted to suppress Na dendrite growth. The use of 1,2-dibromobenzene (1,2-DBB) additive in the electrolyte resulted in a desirable NaBr-rich stable SEI layer. The Na||Na3V2(PO4)(3) cell with the electrolyte containing 1,2-DBB achieved an extraordinary capacity retention of 94% after 2000 cycles at a high rate of 10 C. This study provides a design philosophy for dendrite-free Na metal anode and can be expanded to other metal anodes.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Engineering, Environmental
Lulu Du, Bo Zhang, Xiaofang Wang, Chenhui Dong, Liqiang Mai, Lin Xu
Summary: Solid-state lithium metal batteries (LMBs) have promising prospects due to their high energy density and safety. Developing high-performance solid electrolytes is crucial for practical application of LMBs. Composite polymer electrolytes (CPEs) consisting of inorganic fillers and polymer electrolytes have gained attention for their improved ionic conductivity and mechanical strength.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Wei Peng, Zhaoyang Wang, Ruihu Lu, Qi Li, Ziyun Wang, Yan Zhao, Lin Xu, Liqiang Mai
Summary: In this study, a novel metallic heterostructure composed of defect-rich nickel and amorphous/crystalline molybdenum nitride anchored on a carbon matrix (MoN/Ni@C) was fabricated and demonstrated as a superior electrocatalyst for the hydrogen evolution reaction (HER). The MoN/Ni@C electrocatalyst exhibited low HER overpotential and small Tafel slope, along with excellent stability in alkaline solution. Density functional theory calculations revealed that the interfacial electron transfer contributed to the distortion of Ni surface and the optimal thermoneutral hydrogen adsorption free energies on Mo and Ni active sites. The amorphous/crystalline structure in the MoN phase provided more active sites and promoted structural stability. This work provides new insights into designing non-noble-metal-based electrocatalysts with superior HER activities.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Chenxu Dong, Cheng Zhou, Yan Li, Yongkun Yu, Tianhao Zhao, Ge Zhang, Xinhui Chen, Kaijian Yan, Liqiang Mai, Xu Xu
Summary: In this study, the problem of shuttle effect and sluggish redox reaction in Li-S batteries was successfully addressed by modifying polypropylene separators. The Li-S batteries showed admirable cycling stability and capacity even after 400 cycles of testing. Thus, this research provides a new approach for using single atom catalysts in Li-S batteries.
Article
Chemistry, Multidisciplinary
Congcong Cai, Xinyuan Li, Ping Hu, Ting Zhu, Jiantao Li, Hao Fan, Ruohan Yu, Tianyi Zhang, Sungsik Lee, Liang Zhou, Liqiang Mai
Summary: Introducing anionic redox in layered oxides is effective but suffers from excessive oxidation of lattice oxygen. The development of a Na0.71Li0.22Al0.05Mn0.73O2 (NLAM) cathode material with Al substitution strategy strengthens the TMO2 skeleton and TM-O bonds, inhibiting excessive lattice oxygen oxidation. NLAM exhibits high capacity and good cyclability. In situ characterizations and theoretical calculations support the findings and provide insight for designing cathodes with reversible anionic redox.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ping Hu, Ting Zhu, Congcong Cai, Xuanpeng Wang, Lei Zhang, Liqiang Mai, Liang Zhou
Summary: A series of NASICON-type Na3+xMnTi1-xVx(PO4)(3) cathode materials are designed, demonstrating multi-electron reaction and high voltage platform. The optimized material Na3.2MnTi0.8V0.2(PO4)(3) achieves a reversible 3.2-electron redox reaction, enabling high discharge capacity and ultrahigh energy density.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Juncai Long, Shuangshuang Tan, Junjun Wang, Fangyu Xiong, Lianmeng Cui, Qinyou An, Liqiang Mai
Summary: Exploring diverse Mg(ORF)(2) electrolytes, the Mg(PFTB)(2)/AlCl3/MgCl2 based electrolyte demonstrates the highest oxidation stability, enabling the formation of a robust solid electrolyte interface and long-term cycling of over 2000 hours for symmetric cells and stable Coulombic efficiency of 99.5% over 3000 cycles for asymmetric cells. Moreover, the Mg||Mo6S8 full cell maintains a stable cycling over 500 cycles. This work provides guidance for understanding the structure-property relationships and electrolyte applications of fluoride alkyl magnesium salts.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Qi Sun, Zhaoyang Wang, Min Zhou, Jiantao Li, Ruihu Lu, Yuhan Wang, Xiaobin Liao, Yan Zhao
Summary: An order of magnitude activity enhancement of pristine Fe-N-C catalysts is achieved through cooperation with nitrogen-doped carbon micro-flower. This is realized by the axial coordination effect between Fe active center and nitrogen atoms in support, which can break the electronic distribution symmetry of FeNx moieties and induce electron delocalization and localization on Fe active center and N, respectively, enhancing the adsorption behavior of *OH intermediates. The catalyst exhibits remarkable electrochemical performance as a cathode catalyst of liquid Zn-air batteries.
APPLIED SURFACE SCIENCE
(2023)
Article
Multidisciplinary Sciences
Nianyao Chai, Xiangyu Chen, Zhongle Zeng, Ruohan Yu, Yunfan Yue, Bo Mai, Jinsong Wu, Liqiang Mai, Yi-Bing Cheng, Xuewen Wang
Summary: In this study, a non-equilibrium, photoexcitation-induced passivation technique using ultrashort laser pulses was proposed to improve the performance of perovskite solar cells. By inducing ultrafast annealing, the technique efficiently passivated defects and improved the crystallinity of the tin oxide electron transport layer, resulting in enhanced carrier recombination suppression and charge transport. The technique showed high efficiency and rapid annealing, making it a promising approach for low-temperature manufacturing of perovskite solar cells.
NATIONAL SCIENCE REVIEW
(2023)
Article
Chemistry, Physical
Yuxiang Zhang, Jing Wang, Lina Shan, Bo Han, Qiang Gao, Zhao Cai, Chenggang Zhou, Xike Tian, Ruimin Sun, Liqiang Mai
Summary: In this study, a stable 1T-rich molybdenum sulfide material was successfully constructed using an electron-modulated and phosphate radical-stabilized strategy. The material exhibited excellent electrochemical performance in sodium-ion batteries, showcasing its high potential for practical applications.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Shihao Feng, Kun Li, Ping Hu, Congcong Cai, Jinfeng Liu, Xinyuan Li, Liang Zhou, Liqiang Mai, Bao-Lian Su, Yong Liu
Summary: Hollow carbon nanostructures (HCNs) have intriguing physicochemical properties and various applications, especially in electrochemical energy storage. However, the current solvent-based methods for preparing HCNs are not convenient, environmentally friendly, or scalable. In this study, a solvent-free block copolymer self-assembly approach was used to prepare various hollow hard carbon nanostructures with high electrochemical energy storage performance.
Article
Chemistry, Multidisciplinary
Yan Liu, Huimei Chen, Yan Yang, Chi Jiao, Wenkun Zhu, Yaping Zhang, Xiaojun Wu, Junjie Mao, Zhiwen Zhuo
Summary: In this study, an inner tandem catalyst with neighboring single atom active sites was proposed for efficient CO2 reduction. By enabling the directional migration of adsorbed intermediates, the inner tandem catalysis showed improved activity and selectivity, broadening the range of catalysts for wide catalysis.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Ze He, Jiawei Guo, Fangyu Xiong, Shuangshuang Tan, Yixu Yang, Ruyue Cao, Greta Thompson, Qinyou An, Michael De Volder, Liqiang Mai
Summary: This article introduces improvements made to the Daniell cell to make it rechargeable, including the use of ion exchange membranes as alternatives to salt bridges. These improvements result in increased energy density of the Daniell cell and allow for easy recycling and scalability to higher capacity cells.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Zhang Kai, Wu Xiaojun
Summary: In this study, a type of two-dimensional ferromagnetic material called Janus TiXY is predicted through systematic first-principles calculations. These materials exhibit spin ordering above room temperature and diverse electronic structures. The research demonstrates the transition of band gaps and spin splitting in these materials by flipping the spin direction. Furthermore, the interlayer magnetic coupling can be controlled by stacking configurations, and the intrinsic electronic properties can be maintained by applying a protective graphene layer. These findings make Janus TiXY monolayers promising candidates for practical spintronic applications and open up new avenues for designing novel two-dimensional ferromagnetic materials based on non-magnetic materials.
ACTA CHIMICA SINICA
(2023)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
