Article
Chemistry, Physical
Edgardo Leal Villarroel, Juan Seguel, Pedro Rodriguez, Elodie Blanco, Nestor Escalona, Gina Pecchi, Catherine Sepulveda
Summary: This study investigates the catalytic performance of Ru impregnated perovskites-based catalysts in the conversion of levulinic acid into higher valuable chemicals at different reaction temperatures. The Ru/BaZrO3 catalyst, with stronger basic sites, has a direct influence on the reaction.
Article
Chemistry, Physical
Dan Luo, Jing Qian, Haojie Zhang, Chao Lin, Qi Xiao, Xiaopeng Li
Summary: This study reports an innovative approach to improve the electrolysis performance of intermediate-temperature solid oxide electrolysis cells (IT-SOECs) by modifying the interface of the hydrogen electrode and electrolyte. A nanocomposite with an even distribution of NiO and BZCY was synthesized and utilized to fabricate a double-layer hydrogen electrode structure. The optimized electrode microstructure provides both adequate gas diffusion pathway and enlarged three-phase boundary for effective electrochemical reaction.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Review
Chemistry, Physical
Nikolai A. Danilov, Inna A. Starostina, George N. Starostin, Anna V. Kasyanova, Dmitry A. Medvedev, Zongping Shao
Summary: Proton-conducting oxide materials have protonic defects in their crystal structure due to their interaction with hydrogen-containing atmospheres, resulting in superior ionic conductivity. Barium cerate, barium zirconate, and barium cerate-zirconate are widely studied as proton-conducting electrolyte materials. Y and Yb co-doped Ba(Ce,Zr)O-3 is considered one of the most promising systems.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
S. N. Shkerin, A. V. Rudakova, K. M. Bulanin, A. Sh Khaliullina, A. N. Meshcherskikh, E. G. Vovkotrub, L. A. Dunyushkina
Summary: This study investigated the effects of yttrium doping and strontium nonstoichiometry on the local environment of cations and vibrational properties of SrZrO3. The results showed that yttrium ions can be partitioned over both A- and B-sites in strontium-deficient zirconates with dopant concentrations more than 2%.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Multidisciplinary
Berke Piskin, Fatih Piskin
Summary: A comprehensive study was conducted on single-phase BaZr0.80Y0.20O3-delta thin films produced by RF magnetron sputtering. The study involved the production of a sputter target and the preparation of thin films, followed by the electrochemical evaluation of these films. Results showed that BaZr0.80Y0.20O3-delta thin films prepared using a deformable compaction die and RF sputtering exhibited improved conductivity.
Article
Chemistry, Physical
D. Catalan-Martinez, L. Navarrete, M. Tarach, J. Santos-Blasco, E. Vollestad, T. Norby, M. Budd, P. Veenstra, J. M. Serra
Summary: Electrolysis based on renewable energies is a promising solution for carbon-free hydrogen generation and storage. Recent developments in proton ceramic electrolysis cells operating at intermediate temperatures show superior energy efficiency. This study optimizes a proton ceramic Single Engineering Unit (SEU) design for steam electrolysis using a computational fluid dynamics model. The proposed SEU design allows efficient and adaptable pressurized hydrogen generation.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Amir Masoud Dayaghi, Reidar Haugsrud, Marit Stange, Yngve Larring, Ragnar Strandbakke, Truls Norby
Summary: Proton conducting oxide electrolytes with increased thermal expansion coefficient by partially substituting Ba and Zr with Sr and Ce while maintaining a cubic structure and minor n-type conduction, have potential applications in proton ceramic electrochemical cells at intermediate temperatures.
SOLID STATE IONICS
(2021)
Article
Multidisciplinary Sciences
Xiaobo Zheng, Jiarui Yang, Peng Li, Qishun Wang, Jiabin Wu, Erhuan Zhang, Shenghua Chen, Zechao Zhuang, Weihong Lai, Shixue Dou, Wenping Sun, Dingsheng Wang, Yadong Li
Summary: In this study, we propose an antioxidation strategy to mitigate anode corrosion by constructing a heterostructured Ir-Sn pair-site catalyst. The formation of Ir-Sn dual-site at the heterointerface and the resulting strong electronic interactions considerably reduce the corrosion of catalysts. The optimized catalyst exhibits high mass activity and outstanding long-term stability.
Article
Chemistry, Applied
Haoyu Zheng, Feng Han, Noriko Sata, Remi Costa
Summary: This study evaluates the performance of hydrogen production through proton conducting ceramic cell electrolysis at intermediate temperatures. Optimizing materials and cell design to improve faradaic efficiency could make it an effective technology for converting high temperature waste heat into hydrogen.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Chemistry, Physical
Sathish Rajendran, Naresh Kumar Thangavel, Samia Alkatie, Yi Ding, Leela Mohana Reddy Arava
Summary: Tri-doping of barium cerium zirconate with rare earth elements Pr, Gd, and Y was studied to enhance sinterability, chemical stability, and proton conductivity. Varying the concentrations of dopants showed significant effects on the microstructure and conductivity of the electrolyte materials. The tri-doped electrolytes exhibited excellent chemical stability and high proton conductivity values at elevated temperatures.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Nanoscience & Nanotechnology
Ziyi Zhu, Mingyang Zhou, Kai Tan, Zidai Fan, Dan Cao, Zhijun Liu, Meilong Chen, Yu Chen, Min Chen, Jiang Liu
Summary: The development of solid oxide cell (SOC) based on proton-conducting electrolyte is hindered by performance degradation caused by mismatch in thermal expansion coefficients between the electrolyte and the oxygen electrode. This paper proposes a solution by increasing the TEC of the electrolyte and demonstrates the improved stability of SOC with Fe-doped electrolyte and oxygen electrode materials. The Fe doping increases the TEC of BaZr0.3Ce0.5Y0.1Yb0.1O3-delta electrolyte and decreases the TEC of PrNi0.5Co0.5O3-delta oxygen electrode material.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Materials Science, Ceramics
Melanie Francois, Victoire Lescure, Olivier Heintz, Lionel Combemale, Frederic Demoisson, Gilles Caboche
Summary: BaZr0.85Y0.15O3-δ was synthesized by a continuous hydrothermal process in supercritical water. The formation mechanism of this oxide was proposed based on XRD, TEM, and XPS analysis, which involves the precipitation of core-shell nanoparticles. The conductivity of the oxide reached 2.5 x 10-3 S cm-1 at 600℃ in wet H2 (3% H2O), and its conduction was mainly protonic below 575℃ according to electrochemical impedance spectroscopy measurements.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Maria Balaguer, Yoo Jung Sohn, Dietmar Kobertz, Sergey Kasatikov, Andrea Fantin, Michael Mueller, Norbert H. Menzler, Olivier Guillon, Mariya E. Ivanova
Summary: Innovations in materials science are crucial for addressing technological challenges, requiring the design of materials with tailored properties. This study developed ceramic materials in the BaZr0.8Y0.2-xMnxO3-delta series, finding that thermal expansion and hydration decrease, and total electrical conductivity reduces with increasing Mn content. XPS analysis and NEXAFS indicated varying oxidation states of Mn atoms depending on ambient conditions, suggesting a hydration mechanism mediated by Mn oxidation and proton attachment to oxygen neighbors.
SOLID STATE IONICS
(2022)
Article
Chemistry, Inorganic & Nuclear
Kenji Arai, Yusuke Asai, Yoko Kokubo, Miwa Saito, Miki Inada, Katsuro Hayashi, Teruki Motohashi
Summary: The bonding nature of hydroxide ions in two proton-conducting oxy-hydroxides, BZT and BZW, was studied using FT-IR spectroscopy at temperatures of 40-600°C. A broad absorption peak at 2500-4000 cm-1, attributed to O-H stretching vibration, was deconvoluted into four components representing proton sites in the crystal lattice. The different temperature variations of peak intensities indicated a difference in proton site preference between BZT and BZW, suggesting the importance of B-site cationic order in proton distribution and conduction properties.
JOURNAL OF SOLID STATE CHEMISTRY
(2023)
Article
Chemistry, Physical
Shota Maeda, Yusuke Shiratori, Daisuke Kurashina, Takaya Fujisaki, Kwati Leonard, Hiroshige Matsumoto
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2020)
Article
Physics, Applied
Naoki Tanimoto, Masaya Nagai, Masaaki Ashida, Yuji Okuyama, Yukimune Kani
Summary: The photoluminescence in solid electrolytes is shown to be sensitive to the atomic structure of the defect complex which determines ionic conduction. By comparing photoluminescence spectra, specific atomic arrangements associated with each sample's photoluminescence characteristics can be identified based on previous investigations.
JAPANESE JOURNAL OF APPLIED PHYSICS
(2021)
Article
Chemistry, Physical
Junji Hyodo, Shogo Kato, Shintaro Ida, Tatsumi Ishihara, Yuji Okuyama, Takaaki Sakai
Summary: Proton-conducting oxides have attracted attention as electrolyte materials for electrochemical devices operating at intermediate temperatures. Quantifying oxygen ion transport number is crucial for predicting fuel utilization efficiency in solid oxide fuel cells (SOFCs). This study evaluated the oxygen ion conductivities in Ba-doped LaYbO3 and revealed that proton conduction dominates in wide areas, particularly at temperatures below 600 degrees C.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Physical
Jose Carlos Madrid Madrid, Junko Matsuda, Kwati Leonard, Hiroshige Matsumoto, Kulbir Kaur Ghuman
Summary: This study focuses on understanding the oxygen-ion transport through mixed grain boundaries (GBs) in yttria-stabilized zirconia (YSZ), an electrolyte commonly used in solid oxide fuel cells (SOFCs). The study found that at the optimum Y2O3 concentration and specific grain orientations, the mixed GBs showed higher oxygen-ion diffusivity.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Electrochemistry
Kwati Leonard, Yuji Okuyama, Mariya E. Ivanova, Wilhelm A. Meulenberg, Hiroshige Matsumoto
Summary: Acceptor-doped barium zirconate cerate electrolytes have potential applications in highly efficient and environmentally friendly electrochemical devices. By optimizing the ionic conductivity, the Ba(ZrxCe10-x)(0.08)Y0.2O3-delta (1 <= x <= 9) material shows superior conductivity for moderate temperature electrolysis.
Article
Physics, Applied
Masaya Nagai, Yuto Furutani, Hikaru Takehara, Tomohide Morimoto, Masaaki Ashida, Yuji Okuyama, Yukimune Kani
Summary: Terahertz conductivity of doped ceria was measured at different temperatures, showing higher activation energy in doped ceria compared to stabilized zirconia, possibly due to lattice expansion. Terahertz spectroscopy can also be used to study fast microscopic ionic conduction in solid-oxide electrolytes, inaccessible through conventional impedance measurements.
PHYSICAL REVIEW APPLIED
(2021)
Article
Crystallography
Hartmut Schlenz, Stefan Baumann, Wilhelm Albert Meulenberg, Olivier Guillon
Summary: The aim of this work is to predict suitable chemical compositions for the development of new ceramic oxygen gas separation membranes, avoiding doping with toxic cobalt or expensive rare earths. By evaluating experimental data, determining missing crystallographic information using bond-valence modeling, and utilizing machine learning to generate training data sets, suitable compositions of cubic perovskite-type phases can be predicted, achieving higher electronic and oxygen conductivities for practical applications.
Article
Biochemistry & Molecular Biology
Kai Wilkner, Robert Muecke, Stefan Baumann, Wilhelm Albert Meulenberg, Olivier Guillon
Summary: In this study, a sensitivity analysis was conducted using a 1D transport model to identify the key parameters for oxygen transport membranes. The results showed that the ambipolar conductivity of the material and the total pressure in the gas phase were related to the limitations of oxygen transport. This model is useful for guiding the development of high-performance gas separation membranes.
Article
Chemistry, Physical
Hikaru Takehara, Masaya Nagai, Masaaki Ashida, Yuji Okuyama, Yukimune Kani
Summary: Yttrium-doped barium zirconate, a solid electrolyte with advantageous properties for fuel cells, was characterized using photoluminescence and photoluminescence excitation spectra to understand the atomic arrangement near the oxygen vacancy. The study found that the photoluminescence spectra consisted of recombination at the grain boundary region, recombination at a vacancy defect with an unpaired electron, and the transition of the electronic state of the oxygen vacancy. By analyzing the peak position and corresponding excitation spectrum, information on the atomic arrangement adjacent to the oxygen vacancies, which is crucial for designing materials with high protonic conductivity, was obtained.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Chemistry, Physical
Hirofumi Sumi, Hiroyuki Shimada, Konosuke Watanabe, Yuki Yamaguchi, Katsuhiro Nomura, Yasunobu Mizutani, Yuji Okuyama
Summary: This study investigates the effect of polarization resistances on current leakage and the distribution of relaxation times (DRT) analysis of electrochemical impedance spectra (EIS) for solid oxide cells (SOCs) with GDC electrolyte and protonic ceramic cells (PCCs) with BZYb electrolyte. The results show that the polarization resistances increase with increasing current density in SOC with GDC electrolyte, but exhibit the opposite tendency in PCC with BZYb electrolyte. This suggests that the effect of current leakage on polarization resistance is related to the conductivity of the electrolyte.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Biochemistry & Molecular Biology
Hong Huang, Ziyue Guo, Remzi Can Samsun, Stefan Baumann, Nikolaos Margaritis, Wilhelm Albert Meulenberg, Ralf Peters, Detlef Stolten
Summary: This study aims to adapt a solid oxide cell (SOC) to a membrane reactor for general chemical reactions. A proof-of-concept reactor is tested for syngas production using oxygen ion transport membranes (ITMs) for oxygen separation. ANSYS Fluent is used for CFD simulations, and results show that the oxygen permeation rate depends on various factors.
Article
Chemistry, Physical
Hikaru Takehara, Masaya Nagai, Masaaki Ashida, Yuji Okuyama, Yukimune Kani
Summary: We demonstrate that protons strongly inhibit certain phonons in hydrated barium zirconate. By conducting terahertz spectroscopy and infrared reflection spectroscopy measurements on anhydrous and hydrous acceptor-doped barium zirconate sintered pellets, we provide evidence for this effect. Last and Slater phonon modes are significantly suppressed with proton doping, while phonons are not damped with trivalent dopants. This phenomenon is attributed to the picosecond motion of protons, such as hydroxyl rotation and attempt motion of proton hopping, coupled with the phonon.
JOURNAL OF PHYSICAL CHEMISTRY C
(2023)
Article
Electrochemistry
Yuji Okuyama, Yoshiaki Harada, Yuichi Mikami, Kosuke Yamauchi, Tomohiro Kuroha, Hiroyuki Shimada, Yuki Yamaguchi, Yasunobu Mizutani
Summary: A proton current detector was developed using a proton conducting oxide to measure the proton current in a PCFC. An apparatus based on the electromotive force of an electrochemical cell was used to measure the amount of proton current flowing in the PCFC. The hydrogen ion current was determined by monitoring the water vapor pressure.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Yuji Okuyama, Keita Kasuga, Masaki Shimomura, Yuichi Mikami, Kosuke Yamauchi, Tomohiro Kuroha, Hirofumi Sumi
Summary: This study investigates the elementary reactions occurring within the electrode impedance of proton-conducting ceramic fuel cells. By observing the change in components when the gas on the anode was switched from light hydrogen to heavy hydrogen during the power generation and shutdown phases of the fuel cell, impedance components attributable to the steam production reaction were identified.
JOURNAL OF POWER SOURCES
(2023)
Article
Biochemistry & Molecular Biology
Kwati Leonard, Wendelin Deibert, Mariya E. Ivanova, Wilhelm A. Meulenberg, Tatsumi Ishihara, Hiroshige Matsumoto
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)