Article
Materials Science, Multidisciplinary
Chao Xing, Chang-Yu Liu, Chao Lai, Shan-Qing Zhang
Summary: This study focused on tuning the interlayer spacing of a graphene oxide (GO) membrane using poly-ethyleneimine (PEI) and developing a robust composite nanofiltration membrane. The PEI/GO@PAN membrane exhibited excellent rejection performance and high flux, making it a promising candidate for dye/salt separation applications.
Article
Engineering, Chemical
Keizo Nakagawa, Shintaro Araya, Kai Ushio, Misato Kunimatsu, Tomohisa Yoshioka, Takuji Shintani, Eiji Kamio, Kuo-Lun Tung, Hideto Matsuyama
Summary: Two-dimensional (2D) laminar membranes are being studied for organic solvent nanofiltration, but controlling interlayer spacing and stable solvent permeation remain challenges. In this study, GO membranes with TEOA crosslinker were found to effectively suppress swelling and the affinity between TEOA and solvents correlated with interlayer spacing, indicating the importance of crosslinker-solvent affinity in controlling membrane performance.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Junhyeok Kang, Yunkyu Choi, Jeong Pil Kim, Ji Hoon Kim, Ju Yeon Kim, Ohchan Kwon, David Inhyuk Kim, Dae Woo Kim
Summary: By generating nanopores on the basal plane of graphene and tuning the pore size, a high-performance nanoporous graphene membrane was fabricated, showing ultrafast organic solvent permeation properties and a sharp molecular weight cut-off.
JOURNAL OF MEMBRANE SCIENCE
(2021)
Article
Nanoscience & Nanotechnology
Wen-Hai Zhang, Ming-Jie Yin, Qiang Zhao, Cheng-Gang Jin, Naixin Wang, Shulan Ji, Cody L. Ritt, Menachem Elimelech, Quan-Fu An
Summary: The study presents a highly stable and ultrapermeable zeolitic imidazolate framework-8 (ZIF-8)-nanocrystal-hybridized graphene oxide membrane prepared using ice templating and in situ crystallization of ZIF-8. The selective growth of ZIF-8 in microporous defects enhances water permeability and mechanical integrity, leading to a 30-fold increase in permeability compared to graphene oxide membranes (GOms). The technique also improves permselectivity and offers potential for developing next-generation nanofiltration membranes.
NATURE NANOTECHNOLOGY
(2021)
Article
Engineering, Environmental
Huihui Deng, Jing Huang, Cunqi Qin, Tianhui Xu, Huagang Ni, Peng Ye
Summary: Graphene-based membranes, especially the composite membrane of hydroxylated graphene (GOH) and graphene oxide (GO), exhibit high water permeability and effective molecule retention, making them suitable for separation applications.
JOURNAL OF WATER PROCESS ENGINEERING
(2021)
Article
Engineering, Chemical
Ya Li, Ran Bi, Yanlei Su, Yafei Li, Chao Yang, Xinda You, Jianliang Shen, Jinqiu Yuan, Runnan Zhang, Zhongyi Jiang
Summary: The study demonstrates a post-modification approach to regulate the pore size of NF membranes by using a small molecule, PABA. The PABA-modified membranes show high water permeance and excellent dye/salt selectivity, with outstanding physicochemical stability. This provides a facile method for precise pore size tuning of NF membranes.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Engineering, Chemical
Shabin Mohammed, Jamaliah Aburabie, Raed Hashaikeh
Summary: This study demonstrates a facile approach to fabricate a highly wrinkled selective layer on polyamide (PA) membranes through bio-inspired modification of the support layer with Y-type zeolites. Incorporating smaller dimension zeolites produced by a unique ball milling technique resulted in a defect-free selective layer. The membranes exhibited fast transport and excellent salt rejection for various salt solutions.
Article
Engineering, Chemical
Haoze Zeng, Jing Guo, Yanqiu Zhang, Dingyu Xing, Fan Yang, Junhui Huang, Sichao Huang, Lu Shao
Summary: This study utilizes glycerol as an additive to improve the permeability of nanofiltration membranes while maintaining their rejection effect. By regulating the membrane structure and preventing shrinkage during heat treatment, nanofiltration membranes with outstanding performance were synthesized.
JOURNAL OF MEMBRANE SCIENCE
(2022)
Article
Biotechnology & Applied Microbiology
Hao Zhang, Xingya Li, Tongwen Xu
Summary: Graphene oxide (GO) membranes with subnanometer-scale two-dimensional channels show great potential as separation membranes for water-ion and ion-ion selectivity. We discuss strategies such as d-spacing modulation, surface functionalization, and heterostructure creation to enhance the ion sieving properties of GO membranes based on the understanding of water and ion transport behavior. Furthermore, we highlight the existing challenges and prospects of GO membranes for practical applications in ionic separation.
CURRENT OPINION IN CHEMICAL ENGINEERING
(2023)
Article
Engineering, Chemical
Dong Wang, Na Zhang, Jiaojiao Zhang, Yuyao Qin, Sen Wang, Chuyang Y. Tang, Zhining Wang
Summary: This study presents a simple and versatile method to prepare novel polyamide nanofiltration membranes via a hydrogel-assisted interfacial polymerization process. The diffusion of piperazine was precisely controlled by adjusting the hydrogel composition and crosslinking degree, resulting in the formation of a thin film composite membrane with improved water permeance and Na2SO4 rejection due to the synergistic effect of decreased thickness and improved surface hydrophilicity.
Article
Engineering, Chemical
Weidong Li, Xiaofa Wang, Ming He, Zijun Zhang, Jiachuan Chen, Guihua Yang
Summary: In this study, a novel composite nanofiltration membrane was developed using sulfated cellulose nanofibril as the intermediate support layer. The results showed that increasing the surface charge of the intermediate support layer led to higher roughness and absolute value of surface zeta potential of the composite nanofiltration membrane. The membrane also exhibited excellent water permeability and ion rejection performance, making it a promising candidate for applications in desalination and other fields.
Article
Environmental Sciences
Peng Zhang, Yiran Wang, Pengni Li, Xiaomin Luo, Jianyan Feng, Hui Kong, Ting Li, Wenqi Wang, Xubing Duan, Ying Liu, Meng Li
Summary: A GO/Gr nanofiltration membrane with high stability was successfully engineered by post-hot-pressure treatment and forward pressure filtration. The membrane exhibited satisfactory permeability and selectivity, and showed high rejection rates for various solutes, demonstrating the potential of developing GO-based nanofiltration membranes.
SCIENCE OF THE TOTAL ENVIRONMENT
(2022)
Article
Nanoscience & Nanotechnology
LinSheng Zhu, XiaoXin Guo, YunQiang Chen, Zhou Chen, YiHong Lan, Yubin Hong, WeiGuang Lan
Summary: This study developed a method to modify graphene oxide (GO) membranes by adding phytic acid (PhA), which improved hydrophilicity and enlarged interlamellar spacing. The resulting composite membrane showed high water permeability, rejection rate, and structural stability. This research provides insights into the design and application of GO-based membranes for water separation.
ACS APPLIED NANO MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Shuai Pang, Daoling Peng, Yuwei Hao, Bo Song, Xiqi Zhang, Lei Jiang
Summary: Nanoconfinement effect has a significant impact on chemical reactivity. Chemists have designed various porous nanoconfined systems for catalyzing reactions, but achieving effective flow reactions under mild conditions remains challenging. In this study, multilayer aminated graphene oxide (GO-NH2) membranes were prepared to achieve rapid and efficient Knoevenagel condensation with directional flow. By reducing the interlayer spacing of GO-NH2 membranes, the conversion of the reaction increased, reaching nearly 100% at 22 degrees Celsius with a short reaction time when the interlayer spacing was 14.7 angstroms. Mechanistic studies showed that interlayer confinement enhanced the matching of reactants' frontier orbital symmetry. The characterization of catalysts and density functional theory calculation demonstrated that the delocalized pi electrons of graphitic domains on GO-NH2 could reduce the overall confined reaction energy level. This work provides insights for constructing artificial catalytic systems with high conversion under mild conditions.
Article
Environmental Sciences
Jenny Nambikkattu, Noel Jacob Kaleekkal, Joel Parayil Jacob
Summary: This study successfully addressed the issue of removing glucose from effluents in food, fermentation, and sugar industries, while ensuring compliance with COD standards for water discharge. By incorporating MgFe2O4 and ZnFe2O4 nanoparticles, the thin-film nanocomposite membranes achieved a glucose rejection rate of 96.52%.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2021)
Article
Biochemistry & Molecular Biology
Fasih Bintang Ilhami, Kai-Chen Peng, Yi-Shiuan Chang, Yihalem Abebe Alemayehu, Hsieh-Chih Tsai, Juin-Yih Lai, Yu-Hsuan Chiao, Chen-Yu Kao, Chih-Chia Cheng
Summary: The newly developed DOX/5-ALA-loaded A-PPG micelles exhibited excellent light and pH-responsive behavior, allowing rapid drug release within 1-2 minutes of laser irradiation. This led to enhanced cellular uptake and rapid production of reactive oxygen species in cancer cells, ultimately inducing apoptotic cell death through endocytosis.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2021)
Article
Biochemistry & Molecular Biology
Micah Belle Marie Yap Ang, Kiara Pauline O. Devanadera, Alyssa Nicole R. Duena, Zheng-Yen Luo, Yu-Hsuan Chiao, Jeremiah C. Millare, Ruth R. Aquino, Shu-Hsien Huang, Kueir-Rarn Lee
Summary: Cellulose acetate mixed-matrix membranes were fabricated using wet-phase inversion method with two types of montmorillonite nanoclays embedded. The addition of nanoclays improved membrane hydrophilicity, separation efficiency, and antifouling property. The modified membrane showed high rejection rates for various oil-in-water emulsions and excellent pure water flux.
Article
Polymer Science
Manuel Reyes De Guzman, Micah Belle Marie Yap Ang, Shu-Hsien Huang, Qing-Yi Huang, Yu-Hsuan Chiao, Kueir-Rarn Lee
Summary: Thin-film composite polyamide membranes produced through interfacial polymerization can function more efficiently by adjusting the chemical structure of participating monomers. Among the three diamine monomers considered, CHDA was found to be the most effective in producing TFC NF-like FO membranes with optimal performance.
Review
Polymer Science
Yu-Hsuan Chiao, Arijit Sengupta, Micah Belle Marie Yap Ang, Shu-Ting Chen, Teow Yeit Haan, Jorge Almodovar, Wei-Song Hung, S. Ranil Wickramasinghe
Summary: Forward osmosis (FO) is an important desalination method for producing potable water and treating different wastewater streams. Despite being environmentally friendly and energy-efficient, FO may suffer from four types of fouling that require appropriate cleaning measures for membrane performance recovery. Integration of zwitterionic moieties in FO membrane has shown promising results in enhancing antifouling properties and improving separation efficiency.
Article
Biochemistry & Molecular Biology
Micah Belle Marie Yap Ang, Yi-Ling Wu, Min-Yi Chu, Ping-Han Wu, Yu-Hsuan Chiao, Jeremiah C. Millare, Shu-Hsien Huang, Hui-An Tsai, Kueir-Rarn Lee
Summary: Wastewater effluents with high concentrations of dyes are highly toxic to the environment. Recycling and reusing water and dye in textile industries can save energy and costs. This study explores the use of different diamines to fabricate thin film composite polyamide membranes for dye desalination and finds that the reactivity of the diamines with TMC affects the surface morphology and thickness of the polyamide layer. Among the TFC membranes, TFCCHD exhibited the highest separation efficiency and has potential applications in dye desalination.
Article
Engineering, Chemical
Yu-Hsuan Chiao, Wei-Song Hung
Summary: The microstructure and properties of silk fibroin membranes can be controlled by treatment with different alcohols/water. SF membranes treated with highly polar methanol/water exhibit better hydrophilicity and separation efficiency, while SF membranes treated with low polar butanol/water show increased hydrophobicity and larger free volume.
SEPARATION AND PURIFICATION TECHNOLOGY
(2022)
Article
Engineering, Chemical
Yu-Hsuan Chiao, Keizo Nakagawa, Mayu Matsuba, Masanao Okamoto, Takuji Shintani, Yuji Sasaki, Tomohisa Yoshioka, Eiji Kamio, S. Ranil Wickramasinghe, Hideto Matsuyama
Summary: Membrane fouling is an inevitable issue in membrane separation processes. The fouling behavior is affected by the difference in driving forces between reverse osmosis (RO) and forward osmosis (FO). Factors such as foulant properties, type of draw solution, foulant layer structure, and fouling interaction with the membrane, all play important roles in determining fouling behavior.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Engineering, Chemical
Yu-Hsuan Chiao, Hao-Tung Lin, Micah Belle Marie Yap Ang, Yeit Hann Teow, S. Ranil Wickramasinghe, Yung Chang
Summary: In this study, PVDF surfaces were grafted with poly(GMA-co-SBMA) copolymers to obtain superhydrophilic and superoleophobic membranes. The modified membranes showed excellent fouling resistance and hemocompatibility, as well as improved water permeability. The zwitterionic moiety in the membranes reduced hydrophobic interactions, resulting in reduced fouling and improved antifouling performance. The modified PVDF membranes also exhibited high hemocompatibility and easier flux regeneration compared to pristine membranes.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Polymer Science
Januar Widakdo, Wen-Ching Lei, Anawati Anawati, Subrahmanya Thagare Manjunatha, Hannah Faye M. Austria, Owen Setiawan, Tsung-Han Huang, Yu-Hsuan Chiao, Wei-Song Hung, Ming-Hua Ho
Summary: This study successfully fabricated graphene-PVDF piezoelectric nanogenerators using different co-solvents to enhance durability, stability, and output. Adjusting the concentration of co-solvents such as acetone, THF, water, and EtOH led to varying viscosities and thicknesses of the solution. The addition of graphene and the combination with the four co-solvents resulted in a more dominant beta-phase, with THF showing the highest piezoelectric output among the co-solvents. Most of the output voltages were 0.071V, higher than those produced by other co-solvents.
Article
Chemistry, Multidisciplinary
Tsung-Han Huang, Xin-Yuan Tian, Yi-Yun Chen, Januar Widakdo, Hannah Faye M. Austria, Owen Setiawan, T. M. Subrahmanya, Wei-Song Hung, Da-Ming Wang, Ching-Yuan Chang, Chih-Feng Wang, Chien-Chieh Hu, Chia-Her Lin, Yu-Lun Lai, Kueir-Rarn Lee, Juin-Yih Lai
Summary: In this study, a PVDF/graphene-BaTiO3 nanocomposite was developed by synergistically utilizing graphene and BaTiO3 to enhance the piezoelectric properties of PVDF. This nanocomposite membrane integrates four functions, including solar evaporation, power generation, piezo-photodegradation, and self-cleaning/monitoring, and shows great potential for sustainable water and energy production.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Engineering, Chemical
Ping Xu, Kecheng Guan, Jun Hong, Yu-Hsuan Chiao, Zhaohuan Mai, Zhan Li, Mengyang Hu, Pengfei Zhang, Guorong Xu, Ralph Rolly Gonzales, Hideto Matsuyama
Summary: Recent studies have focused on the importance of porous substrates in interfacial polymerization, but the effect of porous support substrates on the structure and properties of polyamide nanofiltration (NF) membranes has been understudied. This study successfully fabricated and optimized various polyketone (PK) porous substrate supported NF membranes by adjusting pore structure and surface roughness. Structural optimization was achieved through changes in the PK casting solution concentration without additional modification steps. The results showed that the prepared hydrophilic fibrous PK membrane facilitated rapid and even diffusion of amine monomers, making it an ideal substrate for NF membranes. A polyamide film with a ridge-shaped nanostrip structure was easily formed on the PK-8 substrate, improving the permeance of the NF membrane with a slight reduction in salt rejection. Each PK substrate-supported NF membrane exhibited competitive separation performance. This study highlights the superiority of PK porous membranes and provides a simple strategy for NF membrane production and water treatment applications.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Engineering, Chemical
Ping Xu, Kecheng Guan, Yu-Hsuan Chiao, Zhaohuan Mai, Zhan Li, Mengyang Hu, Pengfei Zhang, Ralph Rolly Gonzales, Hideto Matsuyama
Summary: This study successfully developed a highly permeable and permselective polyamide nanofiltration (NF) membrane for Mg2+/Li+ separation by combining isophthaloyl chloride (IPC) with trimesoyl chloride through interfacial polymerization (IP). The properties of the polyamide layer could be finely tuned by adjusting the acyl chloride density of IPC. The NF membranes doped with IPC exhibited significant differences in positive chargeability and showed great potential for industrial applications.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Review
Chemistry, Physical
Januar Widakdo, Hannah Faye M. Austria, T. M. Subrahmanya, Edi Suharyadi, Wei-Song Hung, Chih-Feng Wang, Chien-Chieh Hu, Kueir-Rarn Lee, Juin-Yih Lai
Summary: This article focuses on the mechanism and working system of smart membranes that respond to external stimuli, as well as their potential applications in gas separation.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Physical
T. M. Subrahmanya, Po Ting Lin, Yu-Hsuan Chiao, Januar Widakdo, Cheng-Hsiu Chuang, Shaneza Fatma Rahmadhanty, Shiro Yoshikawa, Wei-Song Hung
Summary: The study demonstrates a novel graphene-PVDF membrane Joule heater for membrane distillation seawater desalination, leading to higher efficiency and lower energy consumption.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Review
Chemistry, Multidisciplinary
T. M. Subrahmanya, Ahmad Bin Arshad, Po Ting Lin, Januar Widakdo, H. K. Makari, Hannah Faye M. Austria, Chien-Chieh Hu, Juin-Yih Lai, Wei-Song Hung
Summary: Electrospun nanofiber membranes (ENMs) have unique advantages in water treatment, such as high specific surface area and mechanical robustness, and show potential in environmental, energy, and health sectors. In recent years, the preparation technology of ENMs has been continuously improved, playing a positive role in solving the problems of traditional electrospinning, with many challenges in future development.
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)