期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 8, 页码 2487-2490出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta14784c
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Here we report a breakthrough increase in porosity of a BEA zeolite (1.1822 cm(3) g(-1)) through mesopore creation (mesopores contribute to 93% pore volume with an average pore diameter of 10.5 nm) by employing a sequential treatment of alkali and ammonium nitrate without causing any structural damage to the zeolite. The material exhibited enhanced catalytic properties in the tert-butylation of phenol in terms of phenol conversion and 2,4 di-TBP selectivity in the solvent-free liquid phase reaction.
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