Article
Chemistry, Physical
Dedy Setiawan, Hyungjin Lee, Hyeri Bu, Doron Aurbach, Seung-Tae Hong, Munseok S. Chae
Summary: A new host material, Na0.04MoO3•0.49(H2O), is successfully developed for magnesium batteries, showing good electrochemical performance and capacity retention at ambient temperatures and in nonaqueous electrolytes.
Article
Engineering, Environmental
Yuehua Man, Yating Fei, Liping Duan, Ruiqi Tian, An Li, Zeyu Yuan, Xiaosi Zhou
Summary: Magnesium-ion batteries (MIBs) are a promising alternative to lithium-ion batteries, but their current cathode materials have issues with structural instability and poor cycle performance. This study focuses on exploring high-performance cathode materials for MIBs, specifically investigating vanadium oxide nanoflowers. The synthesized V5O12 center dot 6H(2)O nanoflowers exhibit encouraging electrochemical properties, making them a potential cathode material for MIBs.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Physical
Cuicui Li, Lu Lin, Wanlong Wu, Xiaoqi Sun
Summary: The authors present a new polyanion cathode material, KVPCH, which exhibits high redox potential and contains structural water, enabling efficient reversible Mg2+ intercalation at high potential. This work provides effective paths for the design of cathode materials for Mg-ion batteries.
Article
Engineering, Environmental
Dedy Setiawan, Hyojeong J. Kim, Jeyne Lyoo, Seung-Tae Hong, Munseok S. Chae
Summary: In this study, a novel cathode material, layered iron vanadate, was proposed for use in non-aqueous magnesium-ion batteries (MIBs). The material exhibited high reversible capacity and average voltage, as well as stable cycle life. The reversibility of the magnesium intercalation reaction on the material was confirmed through experimental analysis. This study offers valuable insights for the design and development of high-performance cathodes for non-aqueous MIBs.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Metallurgy & Metallurgical Engineering
Qin Zhang, Yaobo Hu, Jun Wang, Fusheng Pan
Summary: In this work, CuS submicron spheres were synthesized using a low-temperature strategy and applied as a high-performance cathode for rechargeable magnesium batteries (RMBs). The CuS cathodes exhibited fast diffusion kinetics and remarkable storage performance due to the presence of nano needle-like particles on their surface. The investigation of the storage mechanism revealed a two-step conversion reaction controlled by diffusion during the electrochemical reaction process.
JOURNAL OF MAGNESIUM AND ALLOYS
(2023)
Article
Chemistry, Physical
Adnan Ali Khan, Imran Muhammad, Rashid Ahmad, Iftikhar Ahmad, Najeeb Ullah
Summary: In this paper, a novel cathode material, quinone functionalized hexahydroxytriphenylene (HHTP) and diphenylbutadiynebis (boronic acid) (DPB) based porous polymer (QHHTP-DPB), is suggested for magnesium-ion batteries (MIBs). The material exhibits a stable and highly porous structure with strong affinities for magnesium ions. Theoretical calculations indicate that the polymer can achieve a high theoretical capacity of 720.48 mAh/g and a positive low open-circuit voltage of 0.39 V. The results suggest that the designed quinone functionalized HHTP-DPB porous polymer could be a potential cathode material for MIBs.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Weizhi Kou, Jiajia Wu, Qi Zhang, Yuhong Shen, Runjie Bi, Yuhong Li, Xiaowei Miao, Tinghai Yang, Gang Yang
Summary: This study successfully improved the diffusion kinetics of magnesium ions in the VO2 host by constructing VO2/GO composite as a cathode material, which enhanced the electrochemical performance of magnesium batteries. The experimental results demonstrated that the VO2/GO cathode material exhibited high discharge capacity, significant discharge platform, and satisfactory cycling capacity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Jinglian Zhu, Xu Zhang, Haiguang Gao, Yuting Shao, Yana Liu, Yunfeng Zhu, Jiguang Zhang, Liquan Li
Summary: Rechargeable magnesium batteries face challenges due to strong coulombic effects, but this study presents a high-performance system using hierarchical nano-micro hybrids to improve accessibility and reduce charge transfer resistance, achieving high discharge capacity, outstanding rate performance, and excellent cycling performance.
JOURNAL OF POWER SOURCES
(2022)
Article
Engineering, Environmental
Chunli Zuo, Wen Tang, Binxu Lan, Fangyu Xiong, Han Tang, Shijie Dong, Wenwei Zhang, Chen Tang, Jiantao Li, Yushan Ruan, Shibo Xi, Qinyou An, Ping Luo
Summary: Magnesium ion batteries (MIBs) are gaining significant attention as a promising candidate for the next generation energy storage system. The investigation of Mg(Mg0.5V1.5)O-4 as a potential cathode material has shown promising results in terms of fast reaction kinetics and superior performance, paving the way for the development and improvement of MIBs.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Inorganic & Nuclear
Nikita D. Luchinin, Dmitry A. Aksyonov, Anatoly Morozov, Sergey Ryazantsev, Victoria A. Nikitina, Artem M. Abakumov, Evgeny Antipov, Stanislav S. Fedotov
Summary: This paper presents the synthesis, crystal structure, and electrochemical properties of a new titanium-based phosphate material, alpha-TiPO4. The material exhibits reversible electrochemical activity, good rate capability, and stable cycling, showing promise as a negative electrode material for metal-ion batteries.
INORGANIC CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Eun Gong Ahn, Jin-Hoon Yang, Joo-Hyoung Lee
Summary: A garnet-type intercalation cathode active material, Mg3Si3(MoO6)2, is proposed for high-performance Mg-ion batteries, demonstrating high average discharge voltage, low ion migration barrier, and minimal volume change. These findings provide an additional direction for developing competent Mg-ion batteries for future energy storage applications.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Physical
Jing Xu, Zhengnan Wei, Shaokang Zhang, Xuanxuan Wang, Yihan Wang, Mengyuan He, Kejing Huang
Summary: Transition metal dichalcogenides have emerged as promising materials in the energy field due to their unique structural arrangement. In this work, ordered flower-like WSe2 nanosheet was successfully synthesized through a simple hydrothermal method and showed excellent performance as a cathode in rechargeable Mg-ion batteries.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Danlin Yan, Yingbo Huang, Yanxia Yu, Gengyu Cao
Summary: In this study, nanostructured β-NaVO3 was synthesized by a solution method and investigated as an anode material for sodium-ion batteries. The material exhibited enhanced performance and cycle stability, as well as pseudocapacitive behavior.
NEW JOURNAL OF CHEMISTRY
(2023)
Article
Multidisciplinary Sciences
Kai Wang, Zhenqi Gu, Zhiwei Xi, Lv Hu, Cheng Ma
Summary: The study proposes the use of lithium titanium chloride as a room-temperature ionic conductive and compressible active material for energy-dense all-solid-state Li-based batteries. The experimental results show that using this material as the positive electrode active material, in combination with a lithium-indium alloy negative electrode and solid-state electrolytes, can achieve high discharge capacity, cell voltage, and cycling stability.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Dominika Baster, Lukasz Kondracki, Emad Oveisi, Sigita Trabesinger, Hubert H. Girault
Summary: Sodium-vanadium hexacyanoferrate shows high and stable working potential in a liquid organic electrolyte, achieving excellent capacity retention after 200 cycles. Vanadium substitution in the Prussian blue crystal structure improves cycle life and represents progress in developing cathode materials for Na-ion batteries.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Jingjing Wu, Bo Yuan, Yuyang Gu, Yifan Zhang, Zhongyuan Yan, Lida Zhang, Xusheng Yang, Haijiao Zhang, Ling Bai, Ziquan Li, Zhen-Dong Huang
Summary: A multifunctional BiOCl/amorphous antimony oxide (AAO) hetero-hybrid with the molar ratio of Bi3+/Sb3+ in 1/3 (1-BOC/3-AAO) is successfully developed by scalable ball-milling strategy. It exhibits exceptional visible light photocatalytic degradation performance of RhB and superior anodic potassium ion storage performance for potassium ion batteries. The hetero-hybrid possesses large specific surface area, narrow band gap, improved utilization of visible light, effectively suppressed recombination and highly enhanced transfer efficiency of the photogenerated charge carriers.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Multidisciplinary
Titus Masese, Godwill Mbiti Kanyolo, Yoshinobu Miyazaki, Miyu Ito, Noboru Taguchi, Josef Rizell, Shintaro Tachibana, Kohei Tada, Zhen-Dong Huang, Abbas Alshehabi, Hiroki Ubukata, Keigo Kubota, Kazuki Yoshii, Hiroshi Senoh, Cedric Tassel, Yuki Orikasa, Hiroshi Kageyama, Tomohiro Saito
Summary: Honeycomb-layered oxides with monovalent or divalent, monolayered cationic lattices have diverse crystalline features and are attractive for next-generation energy storage applications. This study investigates the composition and properties of global honeycomb-layered oxides, specifically Ag2M2TeO6 (M=Ni,Mg,etc), which exhibit Ag atom bilayers with sub-valent states within Ag-rich crystalline domains and Ag-deficient domains. The material shows high ionic conductivity and oxygen-hole electrochemistry during silver-ion extraction, and the bilayered structure and sub-valent states are theoretically understood by spontaneous symmetry breaking of SU(2)x U(1) gauge symmetry interactions. These findings suggest that bilayered frameworks have research applications beyond energy storage.
Article
Chemistry, Multidisciplinary
Ziquan Li, Jinquan Wen, Yuqing Cai, Fengting Lv, Xu Zeng, Qian Liu, Titus Masese, Chuanxiang Zhang, Xusheng Yang, Yanwen Ma, Haijiao Zhang, Zhen-Dong Huang
Summary: A new Bi-Ti-EG compound is reported as a high-capacity and stable anode material for potassium storage. It possesses a long-range disordered layered framework that can facilitate electrolyte ingress into Bi nanoparticles, thereby enhancing the storage capacity and cycling stability.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Daichi Kato, Peng Song, Hiroki Ubukata, Haruki Taguro, Cedric Tassel, Kohei Miyazaki, Takeshi Abe, Kousuke Nakano, Kenta Hongo, Ryo Maezono, Hiroshi Kageyama
Summary: Based on ab initio structure searches using evolutionary algorithms, we explored the LaF3-LaX3 (X=Cl, Br, I) system and predicted the structures of LaF2X and LaFX2 (X=Br, I) compounds. LaF2Br and LaFI2 were successfully synthesized and LaF2I showed similar structure but different layer stacking. LaF2I exhibits fluoride ion conductivity comparable to that of non-doped LaF3 and has the potential for better ionic conductivity with appropriate doping. This study demonstrates that structure prediction using evolutionary algorithms can accelerate the discovery of mixed-anion compounds, particularly those with an ordered anion arrangement.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Physical
Shintaro Tachibana, Chengchao Zhong, Kazuto Ide, Hisatsugu Yamasaki, Takeshi Tojigamori, Hidenori Miki, Takashi Saito, Takashi Kamiyama, Keiji Shimoda, Yuki Orikasa
Summary: Fluoride-ion conducting solid materials have potential applications in solid electrolytes for sensing devices and next-generation rechargeable batteries. Previous materials have been limited to single-anion compounds, but the introduction of multiple anions can lead to the formation of anion-ordering crystal structures with new fluoride-ion conducting layers. The fluorosulfide La2+xSr1-xF4+xS2 is found to exhibit fluoride-ion conduction due to the presence of sulfide ions increasing the number of interstitial sites for fluoride ions.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Inorganic & Nuclear
Hiroki Ubukata, Daichi Kato, Shougo Kitade, Thibault Broux, Cedric Tassel, David Schnieders, Richard Dronskowski, Hiroshi Kageyama
Summary: Lanthanide hydride chalcogenides LnHSe and LnHTe crystallize in 2H and 1H structures, respectively. We expanded the LnHCh (Ch = O, Se, and Te) family to include LnHS (Ln = La, Nd, Gd, and Er) and found that larger Ln prefers the 2H structure while smaller Er prefers the 1H structure. The stability of the 2H structure can be attributed to the relatively small electrostatic repulsion between ChLn6 octahedra.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Zefeng Wei, Hiroki Ubukata, Chengchao Zhong, Cedric Tassel, Hiroshi Kageyama
Summary: In this study, a pressure-induced order-disorder transition of anions was observed in a layered perovskite Sr2LiHOCl2. Different synthesis conditions led to different orderings of oxygen and hydrogen in the crystal structure, and the pressure played a critical role. This finding expands the understanding of anion ordering patterns and provides insights for improving the ionic conduction in solids.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Jing Chang, Tong Zhang, Shengchuang Qiu, Na Huang, Dawei Pang, Haoran Li, Titus Masese, Haijiao Zhang, Ziquan Li, Zhen-Dong Huang
Summary: A highly efficient g-C3N4 photocatalyst (SF-CN) is developed using a one-pot thermal polymerization method in a salt fog environment. SF-CN is an oxygenated ultrathin porous carbon nitride with an intermolecular triazine-heptazine heterostructure, exhibiting improved band gap, specific surface area, and photocurrent response compared to pristine g-C3N4. Theoretical simulations show that SF-CN has better photocatalytic hydrogen evolution capability than pure triazine and heptazine carbon nitrides. SF-CN achieves an excellent visible light PHE rate of 18.13 mmol h(-1) g(-1), 259.00 times higher than pristine g-C3N4.
Article
Multidisciplinary Sciences
Haoliang Huang, Yu-Chung Chang, Yu-Cheng Huang, Lili Li, Alexander C. Komarek, Liu Hao Tjeng, Yuki Orikasa, Chih-Wen Pao, Ting-Shan Chan, Jin-Ming Chen, Shu-Chih Haw, Jing Zhou, Yifeng Wang, Hong-Ji Lin, Chien-Te Chen, Chung-Li Dong, Chang-Yang Kuo, Jian-Qiang Wang, Zhiwei Hu, Linjuan Zhang
Summary: LiNiO2 catalyst exhibits super-efficient activity during the oxygen evolution reaction (OER) due to the formation of double O 2p holes states, as observed by operando XAS, XRD, and Raman spectroscopy. Designing efficient OER catalysts is crucial for energy conversion devices.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Yan Dong, Yang Liu, Yuanyuan He, Zhuoyao Chen, Jing Chen, Yuki Orikasa, Yoshiharu Uchimoto, Xiaoming Wang
Summary: By cyclic-voltammetry treatment, the facet orientation of Pd(c) is tuned to (111), resulting in significantly enhanced electrocatalytic activity of Pt-qms in oxygen reduction reaction (ORR), exhibiting 4-fold specific activity and 9-fold mass activity compared to commercial carbon-supported Pt nanoparticles.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Physical
Yu Chikaoka, Naomasa Nakata, Kenta Fujii, Saki Sawayama, Riko Ochi, Etsuro Iwama, Naohisa Okita, Yuta Harada, Yuki Orikasa, Wako Naoi, Katsuhiko Naoi
Summary: In this study, a dual-salt electrolyte system was developed for achieving high capacity and rapid charge-discharge in Mg2+ secondary batteries. The results showed that the use of the dual-salt system improved the Mg2+ insertion/extraction at the cathode/electrolyte interface and enhanced the electrochemical performance of nanoscale cathodes.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Yuqing Cai, Wenjing Liu, Fangfei Chang, Su Jin, Xusheng Yang, Chuanxiang Zhang, Ling Bai, Titus Masese, Ziquan Li, Zhen-Dong Huang
Summary: In this study, Ni, Fe, Mg, and Ti elements were introduced into Mn-based layered oxide to design a high-entropy compound HE-KMO, which demonstrated exceptional rate capability and cyclic stability.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Yan Dong, Zhenlan Li, Guocheng Zheng, Jiawei Zhang, Jiawei Zhou, Yuki Orikasa, Yoshiharu Uchimoto, Xiaoming Wang
Summary: The use of a quasi-monolayer Pt shell (Pt-qms) on a Pd core (Pd-c) can achieve cost and activity targets for the electrocatalytic oxygen-reduction reaction (ORR). In situ X-ray absorption spectroscopy was used to monitor the structural evolution of Pd(c)Pt(qms) during ORR, revealing that Pt-qms undergoes restructuring to form Pt clusters and holes while Pd-c remains stable. Protecting the structure of Pd-c is crucial in the development of high-performance Pd(c)Pt(qms) electrocatalysts.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Multidisciplinary Sciences
Hiroki Aizawa, Takuro Sato, Saori Maki-Yonekura, Koji Yonekura, Kiyofumi Takaba, Tasuku Hamaguchi, Taketoshi Minato, Hiroshi M. Yamamoto
Summary: By exploiting the chiral-induced spin selectivity (CISS) effect, the authors demonstrate enantioselectivity in the assembly of mesoscale helical supramolecules consisting of achiral molecules without the need for chiral catalysis. Unlike chiral molecules, the helical nature in these supramolecules is revealed to be mesoscopically incorporated by dislocation-induced discretized twists. The appearance of spin-polarized current further confirms the relevance of the CISS effect in these discretized helical supramolecules.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Hongfeng Zhan, Mengwei Dong, Shengchuang Qiu, Xiaoshan Wang, Lingfeng Chao, Zhendong Huang, Yonghua Chen, Hai Li, Xiao Huang, Shaozhou Li
Summary: In this study, an environmentally stable bifunctionalized boron nanosheet was successfully synthesized via a wet chemical route. The boron nanosheets were then hierarchically assembled into various well-ordered macroscopic forms using lyophilization, exhibiting unique structural features such as stacking-induced nanochannels for proton transport. The resulting suprastructures showed exceptional proton conductivity and humidity sensitivity, demonstrating the immense potential of boron nanomaterials in electrochemical applications.
CHEMICAL COMMUNICATIONS
(2023)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)