Article
Polymer Science
Hossein Pahlavani, Javad Shabani Shayeh, Amideddin Nouralishahi, Maryam Sharifi Paroushi
Summary: In this study, the researchers investigated the enhancing effects of graphene porous on the supercapacitive performance of a polyaniline/graphene porous nanocomposite. The inclusion of graphene porous significantly increased the specific capacitance of the nanocomposite, while maintaining good electrochemical stability.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Engineering, Electrical & Electronic
Anoud Saud Alshammari, Nidhi Puri, Swati Chaudhary
Summary: In this study, a GO/PANI nanocomposite electrode material was prepared by mechanical vibration method for enhanced supercapacitor applications. The hybrid nanocomposite exhibited high capacitance and exceptional mechanical stability, demonstrating promising potential for energy storage applications.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2023)
Article
Chemistry, Physical
Sha Peng, Ben Liu, Xingying Zhang, Wenhui Li, Shaoyun Chen, Chenglong Hu, Xueqing Liu, Jiyan Liu, Jian Chen
Summary: This article introduces a PANI@PS/FTO electrode prepared using the Langmuir-Blodgett technique, which demonstrates high specific capacitance and rate capability, with capacitance retention ranging from 69.2% to 85.5%.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Samad Dalvand, Zahra Khoushab, S. Morteza Mousavi-Khoshdel, Hossein Ghafuri, Hamid Reza Esmaili Zand, Mehran Omidvar
Summary: In this study, a novel nanocomposite GO@Fe3O4-IL-W was successfully synthesized for high-performance supercapacitors. The morphologies and structures of the materials were characterized using various techniques. The electrochemical behavior of the nanocomposite was investigated, and it exhibited high specific capacitance and excellent cyclic stability. Additionally, a symmetric supercapacitor device based on GO@Fe3O4-IL-W showed promising energy storage capabilities.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2023)
Article
Materials Science, Ceramics
Wei Hau Low, Siew Shee Lim, Chiu Wee Siong, Chin Hua Chia, Poi Sim Khiew
Summary: The bimetallic oxide/graphene nanocomposite is considered a promising electrode material for supercapacitors due to its admirable electrochemical activity and excellent electrical conductivity. By utilizing a unique approach to exploit the graphene/MnV2O6 nanomaterial, a high specific capacitance, high columbic efficiency, and high energy density were achieved, demonstrating the potential of this nanocomposite as a high performance supercapacitor electrode.
CERAMICS INTERNATIONAL
(2021)
Article
Chemistry, Physical
Fuquan Ma, Zhongai Hu, Long Jiao, Xiaotong Wang, Yuanyuan He, Yuying Yang, Zhimin Li
Summary: The study successfully prepared organic molecular electrodes by using polyhydric organic molecules and decorating them with graphene hydrogel, enhancing capacitance and energy density. By utilizing two different organic molecules as positive and negative electrodes, an all-carbon asymmetric supercapacitor was constructed, achieving high energy density and power output, capable of lighting up LED lights.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Jing Tang, Songlin Zhang, Jiahao Guo, Huachen Zhang
Summary: Transition metal sulfides, such as rGO-modified VS4, have been synthesized as efficient and stable composite catalysts for the oxygen reduction reaction (ORR). The catalyst exhibits superior ORR activity, methanol tolerance, and long-term durability due to the strong bond cooperation between VS4 and rGO.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Yuying Yang, Dalan Qian, Jingyue Yang, Yaling Xiong, Yanzhe Chen, Yilun He, Zhongai Hu
Summary: In this study, chrysin (CHY) molecules were immobilized on graphene oxide (GO) surfaces via π-π interactions to obtain organic molecular-modified reduced graphene oxide (RGO) composite electrode material (CHY/RGO). The CHY molecules contribute to capacitance through faradic reactions and act as spacers to prevent graphene nanosheet accumulation, facilitating electrolyte ion migration. As a result, CHY/RGO exhibits excellent capacitance performance with a specific capacitance of 707F g-1 (1 A g-1) and 100% capacitance retention after 10,000 cycles. Furthermore, a symmetrical supercapacitor (CHY/RGO//CHY/RGO) demonstrates impressive energy storage performance, achieving an energy density of 38 Wh kg-1 at a power density of 800 W kg-1 and capable of lighting 50 LEDs when two devices are connected in series. Density functional theory (DFT) calculations reveal that CHY molecules are adsorbed parallel to RGO through π-π stacking and alter the charge distribution on RGO surfaces. Consequently, CHY/RGO composites offer higher capacitance and superior cycle stability, making them a promising choice for future energy storage electrode materials.
APPLIED SURFACE SCIENCE
(2023)
Article
Chemistry, Physical
Annette Jayam Somasundaram, Huifang Xiao, Sabarison Pandiyarajan, Ai-Ho Liao, Sharmila Lydia, Ho-Chiao Chuang
Summary: Herein, the in-situ preparation of manganese ferrite (MnFe2O4) grafted polyaniline (Pani), a magnetic nanocomposite, was reported for potential photocatalytic and supercapacitor applications. The physical characterization of the prepared nanoparticle and nanocomposite was conducted using various spectroscopic and microscopic analyses. The results showed that the nanocomposite exhibited faster degradation of malachite green dye and higher capacitance compared to MnFe2O4 nanoparticles, indicating its potential as a promising material for both photocatalytic and supercapacitor applications.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Energy & Fuels
Xiangxiang Du, Xuejun Shi, Yanling Li, Kesheng Cao
Summary: The N, S-co-doped graphene hydrogel (N/SGH) was prepared using a hydrothermal approach with thiourea as a dopant, followed by the growth of polyaniline (PANI) on its surface. The resulting N/SGH electrode showed enhanced electrochemical performances, and further improvement was achieved by introducing PANI to the composite electrode, leading to high specific capacitance and stable cycle performance.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Energy & Fuels
Atefeh Omidi-Dargahi, Hossein Dehghani, Ali Ehsani
Summary: In this study, the covalently functionalized aromatic-aliphatic amino acids were added to graphene sheets to synthesize NiCo2O4 and blended with functionalized graphene oxide (FGO) as electrochemical electrodes for energy storing applications. The characterization and electrochemical performance evaluation showed that the modified graphene exhibited stable dispersion and the blended material displayed high specific capacitance and exceptional cyclic stability.
JOURNAL OF ENERGY STORAGE
(2024)
Article
Energy & Fuels
Chen Zhang, Aijuan Xie, Wanqi Zhang, Jianing Chang, Chenyang Liu, Linyang Gu, Xiaoxiao Duo, Fei Pan, Shiping Luo
Summary: The Copper manganese oxide-graphene (CuMn2O4-RGO) composite was prepared using the sol-gel method and physical grinding, and then applied as electrode materials for supercapacitors. Various characterization techniques were used to analyze the structure and morphology of the composites. Through electrochemical tests, it was found that the CuMn2O4-RGO composite at a mass ratio of 1:1 exhibited excellent electrochemical properties, with higher capacitance and energy density compared to pure CuMn2O4 and RGO. The composite shows promising potential as an electrode material for supercapacitors.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Chemistry, Physical
Sara Ramandi, Mohammad H. Entezari
Summary: This study reports the preparation of a Graphene@ZIF-67/polyaniline nanotube (PANI-NT) composite using stirring and sonication at room temperature. The composite exhibits high specific surface area and specific capacitance, as well as good reversibility and cyclic stability.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Wen Long Liu, Yong Qiang Guo, Tao Lin, Hong Chao Peng, Ya Ping Yu, Fan Yang, Sheng Chen
Summary: A hierarchical MXene@PANI-ACC electrode was fabricated to address the self-stacking issue of MXene nanosheets during electrode preparation. The electrode exhibited excellent electrochemical performance and showed great promise for high-performance energy storage devices.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Zihan Chen, Xihong Zu, Liheng Chen, Yi Qi, Wenbin Jian, Yaoying Wu, Wenli Zhang, Xuliang Lin, Guobin Yi, Quanbing Liu, Zilun Tang, Jianyu Wu, Huafeng Dong, Yanlin Qin
Summary: Here, the authors report a method to fabricate a flexible self-supporting and lightweight 3D electrode for flexible solid-state supercapacitors. The electrode utilizes vertically grown Fe-MnCo2O4 nanowire arrays to improve electron propagation and enhance the utilization efficiency and cycle performance of MnCo2O4.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Si Eun Kim, Hyun Ji Yang, Soonyoung Choi, Eunbyul Hwang, Minseong Kim, Hyun-Jong Paik, Ji-Eun Jeong, Young Il Park, Jin Chul Kim, Byeong-Su Kim, Sang-Ho Lee
Summary: This study successfully conducted metal-free cationic ring-opening polymerization using tris(pentafluorophenyl)borane (BCF) as a catalyst, resulting in well-controlled branched cyclic polyglycidol (BC-PGD) structure. By operating in nonpolar solvents and achieving a recycling polymerization process under ambient conditions with unpurified reagents, a phase separation of PGD with uniform molecular weight distribution was achieved.
Review
Polymer Science
Jun Su Kang, Namhee Kim, Taehyung Kim, Myungeun Seo, Byeong-Su Kim
Summary: This review discusses the introduction of asymmetry into a supramolecular system via external chiral stimuli and the mechanisms of photon-to-matter chirality transfer at the supramolecular level. It also covers asymmetric photochemical reactions and the creation of a chiral bias upon CPL irradiation.
MACROMOLECULAR RAPID COMMUNICATIONS
(2022)
Article
Polymer Science
Si Eun Kim, Yu-Ri Lee, Minseong Kim, Eunyong Seo, Hyun-Jong Paik, Jin Chul Kim, Ji-Eun Jeong, Young Il Park, Byeong-Su Kim, Sang-Ho Lee
Summary: Controlling the topology of a polymer is crucial for determining its physical properties and processing. In this study, a synthetic approach using a frustrated Lewis pair was proposed to obtain highly tunable hyperbranched polyglycidol. The results showed that different Lewis bases led to different polymer topologies. By investigating the relationship between the polymer topology and its properties, important theoretical insights were provided for controlling polymer topology.
Article
Chemistry, Multidisciplinary
Minseong Kim, Jinwoo Park, Kyung Min Lee, Eeseul Shin, Suebin Park, Joonhee Lee, Chanoong Lim, Sang Kyu Kwak, Dong Woog Lee, Byeong-Su Kim
Summary: This study presents a peptidomimetic approach using poly(ethylene glycol) (PEG) as a platform to evaluate the compositional relationship between key amino acid residues and the role of the polyether backbone in interfacial adhesive interactions. The results reveal highly synergistic surface interactions among PEGtides and the critical role of catechol-amine synergy and diverse hydrogen bonding. Molecular dynamics simulations verify these findings. This study provides insights into the design of simplified peptidomimetic polymers within a polyether backbone.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Polymer Science
Jihye Park, Yeji Yu, Joo Won Lee, Byeong-Su Kim
Summary: Polymers with carboxylic acid functionalities are widely used in various applications. However, synthesizing such polymers via traditional radical polymerization methods is challenging. This study presents a novel approach using a functional epoxide monomer to overcome the limitations, allowing for the controlled synthesis of polymers with carboxylic acid groups.
Article
Chemistry, Physical
Kwangho Yoo, Gue Seon Lee, Hyo Won Lee, Byeong-Su Kim, Jeung Gon Kim
Summary: Mechanochemistry has been successfully applied to polymer synthesis, achieving efficiency, greenness, and new products. In this study, solid monomers were reacted with secondary butyl lithium under high-speed ball-milling, establishing an alkyl-anion-promoted polymerization process. However, the mechanism of the mechanochemical process differs from that of conventional anionic polymerizations, with mechanical force fracturing the newly formed polymer chains and generating macroradicals that participate in the polymerization process.
FARADAY DISCUSSIONS
(2023)
Article
Polymer Science
Soonyoung Choi, Junhee Kim, Eunyong Seo, Hyocheol Jung, Ji-Eun Jeong, Young Il Park, Jin Chul Kim, Dong Woog Lee, Byeong-Su Kim, Sang-Ho Lee
Summary: The topologies of polymers can significantly affect the performance of polymeric materials. In this study, the addition of 4-vinylphenylboronic acid introduced a dynamic covalent bond to polyglycidols with different topologies. The formation of dual crosslinked polymer networks, consisting of dynamic and static covalent bonds, was confirmed. Mechanical tests revealed that the crosslinked network with a branched cyclic structure exhibited higher self-healing efficiency and modulus compared to hyperbranched networks.
Article
Chemistry, Multidisciplinary
Junhee Kim, Soonyoung Choi, Jinsu Baek, Yong Il Park, Jin Chul Kim, Ji-Eun Jeong, Hyocheol Jung, Tae-Hyuk Kwon, Byeong-Su Kim, Sang-Ho Lee
Summary: Topology control plays a critical role in determining the physical properties and potential applications of polymers, especially those with abundant hydrogen bonding donors and acceptors. This study focuses on poly(glycidoxy carbonyl benzoic acid)s (PGCs) and investigates the high-level control of inter- and intramolecular hydrogen bonding in topology-controlled PGCs. By introducing aromatic carboxylic acids into polyglycidols (PGs) through post-polymerization modification, three types of topology-controlled PGCs (linear, hyperbranched, and branched cyclic structures) were prepared. These PGCs showed pH-dependent self-association properties in solution and strong adhesive properties in the bulk state, with the branched cyclic PGC demonstrating a 2.6-fold enhanced adhesive property when mixed with topology-controlled PGs. This cooperative hydrogen bonding between polymer chains is expected to contribute to the development of advanced adhesives and have high potential in biological and biomedical applications due to its excellent biocompatibility.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Polymer Science
Sumin Lee, Woo Hyuk Jung, Minseong Kim, Dong June Ahn, Byeong-Su Kim
Summary: This study developed a method for the synthesis of degradable polyesters through the ring-opening alternating copolymerization of cyclic anhydrides and epoxides. The interplay between monomers was investigated, and the influence of monomer structure on the properties of the resulting polyesters was explored.
Review
Chemistry, Multidisciplinary
Jiyoung Lee, Byeong-Su Kim
Summary: In this review, the latest research trends in poly(ethylene oxide) (PEO)-based solid-state polymer electrolytes for lithium-ion batteries are discussed. The characteristics of PEO-based polymer electrolytes as the next-generation electrolytes for batteries are introduced. Strategies to address the challenges of low ionic conductivity, concentration polarization, and poor mechanical properties are covered based on recent literature findings. Lastly, the remaining challenges and future prospects of PEO-based solid-state polymer electrolytes are outlined.
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Multidisciplinary
Neha Choudhury, Ahyun Kim, Minseong Kim, Byeong-Su Kim
Summary: Poly(vinyl chloride) (PVC) is a widely used commodity plastic that is difficult to recycle and often discarded after use, causing environmental concerns. This study presents a mechanochemical degradation process that converts PVC into water-soluble biocompatible products. By introducing oxirane mechanophores into the polymer backbone and applying force, the polymer chain undergoes a ring-opening reaction, leading to the formation of acetals. Hydrolysis of the acetals further breaks down the polymer into low-molecular-weight fragments. This green alternative offers a solution to the environmental issues associated with PVC disposal.
ADVANCED MATERIALS
(2023)
Article
Polymer Science
Jiyoung Lee, Seonho Kim, Hyeoksu Kwon, Seungyun Jo, Du Yeol Ryu, U. Hyeok Choi, Byeong-Su Kim
Summary: Solid polymer electrolytes are potential alternatives to address safety concerns with liquid electrolytes. A new type of polyether-based single-ion-conducting solid polymer electrolyte was developed, which can be tailored with different functional groups. By introducing tri(ethylene glycol) and succinonitrile, the ionic conductivity of the electrolyte was significantly increased.
Article
Multidisciplinary Sciences
Jihye Park, Ahyun Kim, Byeong-Su Kim
Summary: Despite recent advancements in mechanochemical polymerization, understanding the unique mechanochemical reactivity during the ball milling polymerization process still requires extensive investigations. Here, the authors use solid-state anionic ring-opening polymerization to synthesize polyethers from various functional epoxide monomers. The critical parameters of the monomers are investigated to elucidate the unique reactivity of ball milling polymerization. The controllable syntheses of the desired polyethers are characterized via NMR, GPC, and MALDI-ToF analyses. Interestingly, bulky monomers exhibit faster conversions in the solid-state in clear contrast to that observed for solution polymerization. Particularly, a close linear correlation is observed between the conversion of the ball milling polymerization and melting point of the functional epoxide monomers, indicating melting point as a critical predictor of mechanochemical polymerization reactivity.
NATURE COMMUNICATIONS
(2023)
Article
Materials Science, Biomaterials
Gayoung Kwon, Jinsu Baek, Nuri Kim, Soonyoung Kwon, Nanhee Song, Seong-Cheol Park, Byeong-Su Kim, Dongwon Lee
Summary: By employing ultrastable polymeric micelles as drug carriers, the therapeutic efficacy and immunostimulating activity of oxidative stress amplifying hybrid prodrug (OSamp) could be fully maximized. Tumour-targeted OSamp-loaded micelles showed excellent colloidal stability and significant cytotoxicity to cancer cells, as well as induction of immunogenic cell death. In a syngeneic mouse tumour model, these micelles effectively inhibited tumour growth and activated adaptive immune responses, suggesting great translational potential as immunostimulating anticancer nanomedicine.
BIOMATERIALS SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Kihyuk Sung, Jinsu Baek, Soonyoung Choi, Byeong-Su Kim, Sang-Ho Lee, In-Hwan Lee, Hye-Young Jang
Summary: We have successfully synthesized a novel form of polyglycerol with an unprecedentedly low degree of branching (DB = 0.08-0.18), eliminating the need for glycidol protection. Leveraging the remarkable efficiency and selectivity of our Cu(triNHC) catalyst, we achieved a highly selective polymerization process. The ultralow-branched cyclic polyglycerol (DB = 0.08) synthesized at 0℃ showcased extraordinary characteristics, exhibiting the lowest diffusion coefficient and the highest molecular weight.
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)