期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 2, 期 21, 页码 7754-7758出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ta00884g
关键词
-
Metallo-supramolecular polymers composed of Ni(II) ions and bis(2,9-dimethyl-1,10-phenanthroline) showed ionic conductivity, which enhanced by about four orders of magnitude with increasing relative humidity from 30 to 98% RH, in the film state. Four Ni(II)-based polymers with different counter anions were synthesized to investigate the ionic conduction mechanism. The highest ionic conductivity (5 x 10(-2) S cm(-1)) at 98% RH was observed in the polymer with chloride ions as the counter anion. The Grotthuss-type proton transfer mechanism was indicated by the low activation energy (0.21 eV) for the ionic conduction. The polymer film prepared on an interdigitated electrode showed dynamic humidity-sensing properties based on the quick and large current-response to humidity change.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据