Article
Chemistry, Applied
Jing Zhang, Yi-min Wu, Hong-li Zhang, Ting-hui Yan, Yu-zhong Huang, Jia-xing Jiang, Ji-Jun Tang
Summary: In this study, a novel castor oil-glycerol-based waterborne polyurethane was successfully synthesized, with the addition of glycerol achieving higher bio-content and significantly enhancing the mechanical properties and thermal stability of the material.
PROGRESS IN ORGANIC COATINGS
(2021)
Article
Chemistry, Applied
Haihua Wang, Guangyu Hu, Xuan Liu, Liyuan Guo, Xiaorui Li, Ruiyuan Guo, Yanyu Li
Summary: The dispersibility and long-term stability of hydrophobic polyaniline (PANI) in water have been significantly improved by chemically modifying PANI-12Br(II) to achieve N-alkylation and chemical crosslinking.
PROGRESS IN ORGANIC COATINGS
(2022)
Article
Chemistry, Applied
Yurany Villada, Helen Inciarte, Claudia Gomez, Sandra Cardona, Laura M. Orozco, Diana Estenoz, Luis Rios
Summary: Castor oil and dehydrated castor oil were used to synthesize alkyd-urethane resins through a two-stage process. The synthesized resins still contained hydroxyl groups, making them suitable for further urethane linkages. The cured films exhibited similar properties in terms of hardness, adhesion, chemical and water resistance, and gloss. Drying time was influenced by factors such as temperature, presence of double bonds, and solvent.
PROGRESS IN ORGANIC COATINGS
(2023)
Article
Engineering, Environmental
Rulin Shen, Mingjun Long, Chendong Lei, Liming Dong, Guipeng Yu, Juntao Tang
Summary: In this study, the mechanical properties of vegetable oil-based waterborne polyurethane (WPUs) were improved by incorporating sustainable diols. The resulting films demonstrated higher tensile strength and toughness compared to state-of-the-art systems. Among the different diols investigated, WPU-B films exhibited superior performance and increased corrosion resistance. This research provides strategies for controlling the physical properties of environmentally friendly WPUs and developing high-performance coatings for anticorrosion applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Polymer Science
Gaston Pascual, Mirta Aranguren, Veronica Mucci
Summary: Waterborne polyurethanes with high biobased content were synthesized for use as coatings for metals and woods. Blending different polyurethane dispersions improved the film's handling characteristics. The performance of the films was characterized, and properties such as transparency, modulus, and thermal degradation were adjusted by blending different dispersions.
Article
Chemistry, Applied
Henghui Deng, Qian Chen, Fei Xie, Caimei Zhao, Jun Pan, Qiaoyun Cheng, Chaoqun Zhang
Summary: In this study, tunicate cellulose nanocrystals (TCNCs) were added to castor oil-based waterborne polyurethane (WPU) to prepare bio-based nanocomposites through solution blending. The effect of TCNCs content on the dispersion size and stability, as well as the properties of the composite films, was investigated. The unique properties of TCNCs, such as high crystallinity, aspect ratio, and modulus, improved the stability of WPU and showed reinforcing/toughening effects and compatibility. Flexible strain sensors were fabricated by coating silver nanowires (AgNWs) on the composite films, exhibiting excellent sensitivity in monitoring human movement.
CARBOHYDRATE POLYMERS
(2023)
Article
Food Science & Technology
Yuye Zhong, Tao Zhang, Wenshuo Zhang, Guannan Wang, Zhenhong Zhang, Pingping Zhao, Xinghai Liu, Houbin Li
Summary: To overcome the limitations of pure gelatin film, researchers successfully grafted quaternary ammonium groups onto a novel castor oil-based waterborne polyurethane to create composite films. The mechanical properties, thermal stability, water permeability, and oxygen permeability of these films improved significantly with the increase in waterborne polyurethane concentration. The composite films also demonstrated strong antibacterial properties against Escherichia coli and Staphylococcus aureus, and extended the shelf life of strawberries to more than 6 days. Therefore, this new composite material has the potential to serve as an alternative food packaging material.
FOOD PACKAGING AND SHELF LIFE
(2023)
Article
Chemistry, Physical
Yong-A Choe, Su-Il Kim, Kyong-Sik Ju
Summary: This study evaluated the use of acrylic pimaric acid (APA) as a bio-based substitute for the aromatic diacid monomer in high oil length alkyd resins. The results showed that HOARs containing 9% APA exhibited excellent gloss, pencil hardness, impact strength, and alkaline resistance. Moreover, the price of these resins decreased by about 20% compared to conventional AR, making them a valuable binder in the field of protective paint.
CHEMICAL PHYSICS LETTERS
(2022)
Article
Chemistry, Applied
Wenbo Zhang, Henghui Deng, Lijuan Xia, Lan Shen, Chaoqun Zhang, Qiming Lu, Shaolong Sun
Summary: In this study, a series of vegetable oil-based waterborne polyurethane composites were prepared through the construction of a novel semi-interpenetrating polymers network using carboxymethyl chitosan (CA) as the secondary polymer phase. The results showed that as the CA content increased, there was a significant increase in the crosslinking density and glass transition temperature of the composite films, with excellent storage stability observed in the composite dispersions.
CARBOHYDRATE POLYMERS
(2021)
Article
Chemistry, Applied
Bin Lyu, Henian Zhang, Dangge Gao, Jianzhong Ma
Summary: In this study, polyols based on inedible sapium sebiferum oil were prepared and used to prepare modified castor oil-based waterborne polyurethane. The modified films showed good anti-graffiti and thermal properties, as well as improved tensile strength and elongation at break.
PROGRESS IN ORGANIC COATINGS
(2022)
Article
Materials Science, Multidisciplinary
Yuehong Zhang, Zhenqiang Wu, Lei Shi, Langlang Dai, Ruijing Liu, Lei Zhang, Bin Lyu, Shunhua Zhao, Vijay Kumar Thakur
Summary: A novel castor oil-based multifunctional polyol (CM) is synthesized through mild thiol-ene photo induced reactions using castor oil (CO) and 1-thioglycerol (MPD) as building blocks. The resulting CM is combined with CO to prepare castor oil-based water-borne polyurethane emulsion with desirable mechanical properties and water resistance.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2023)
Article
Engineering, Environmental
Weihao Zhang, Tongyao Wang, Zhanhong Zheng, Rafael L. Quirino, Fei Xie, Yufeng Li, Chaoqun Zhang
Summary: This study successfully prepared green and safety plant oil-based non-isocyanate waterborne polyurethanes by carbonating linseed oil and polymerizing it with different diamines and hydrophilic moiety. Aromatic diamines, aliphatic diamines, and poly-ether diamines were used as chain extenders to tailor the performance of the resulting polyurethanes, and the robustness of the preparation route was evaluated.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Chaoqun Zhang, Haiyan Liang, Dunsheng Liang, Zirun Lin, Qian Chen, Pengju Feng, Qingwen Wang
Summary: The newly developed multifunctional castor-oil-based waterborne polyurethane has high tensile strength and excellent self-healing efficiency, with the ability to fully recover its original mechanical properties after multiple reprocessings. The material exhibits a wide range of glass-transition temperatures, providing the films with versatile shape-memory effects.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Applied
Laura M. Orozco, Sandra Cardona, Claudia Gomez, Helen Inciarte, Yurany Villada, Luis Rios
Summary: This study suggests using KHSO4 as a re-usable catalyst in the dehydration of castor oil, which offers desired yields, easy separation, and low environmental impact. The catalyst showed good stability in five consecutive experiments. Partial transformation of KHSO4 into K2SO4 and K2S2O7 during the reaction led to a decrease in acidity.
PROGRESS IN ORGANIC COATINGS
(2021)
Article
Polymer Science
Mengqing Shi, Jin Yang, Xiwen Wang
Summary: This study synthesized a series of bio-based waterborne polyurethanes with high bio-based content, excellent performance, and degradability by adjusting the castor oil content. Experimental results showed that the mechanical properties changed with the increase of castor oil content.
JOURNAL OF POLYMER RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Younes Ahmadi, Mohammad Tahir Siddiqui, Qazi Mohd Rizwanul Haq, Sharif Ahmad
ARABIAN JOURNAL OF CHEMISTRY
(2020)
Review
Polymer Science
Younes Ahmadi, Sharif Ahmad
Article
Engineering, Chemical
Mohammad Irfan Bakshi, Halima Khatoon, Sharif Ahmad
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2020)
Article
Materials Science, Multidisciplinary
Sajid Iqbal, Halima Khatoon, R. K. Kotnala, Sharif Ahmad
JOURNAL OF MATERIALS SCIENCE
(2020)
Article
Chemistry, Applied
Mohammad Irfan Bakshi, Sharif Ahmad
PROGRESS IN ORGANIC COATINGS
(2020)
Article
Chemistry, Applied
Halima Khatoon, Sajid Iqbal, Sharif Ahmad
Summary: The study synthesized and characterized Ethelynediamine modified graphene oxide covalently functionalized with poly(p-phenylenediamine) nanofiller, and their composites with safflower oil polyurethane were prepared as coatings on carbon steel. Under harsh acidic environments, the MGO-PPPDA/PU composite coating exhibited significantly enhanced corrosion protection ability compared to MGO/PU and PPPDA/PU nanocomposite coatings, as revealed by various corrosion testing techniques.
PROGRESS IN ORGANIC COATINGS
(2021)
Article
Biochemistry & Molecular Biology
Ashiq Hussain Pandit, Safiya Nisar, Khalid Imtiyaz, Masood Nadeem, Nasreen Mazumdar, M. Moshahid Alam Rizvi, Sharif Ahmad
Summary: The synthesized N,O-CMCS/MAGG hydrogel showed promising applications in localized delivery of anticancer drugs. The hydrogel exhibited pH-responsive swelling behavior, good mechanical properties, excellent self-healing and thixotropic properties due to the reversible Schiff base linkages. The Dox-loaded hydrogel demonstrated significant killing effect against breast cancer cells, indicating its potential in anticancer drug delivery.
Article
Engineering, Electrical & Electronic
Sajid Iqbal, Halima Khatoon, R. K. Kotnala, Sharif Ahmad
Summary: Magnesium ferrite nanorods and magnesium ferrite/polythiophene (MgFe2O4/PTh) composites were fabricated using sol-gel and in-situ emulsion polymerization approaches to investigate electromagnetic interference (EMI) shielding activity in the X-band region. The synergistic effect of magnesium ferrite nanorods and conducting PTh in the composites led to high shielding effectiveness, attributed to the high dielectric and magnetic loss, making them potentially useful as lightweight, high-performance EMI shielding materials.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Chemistry, Applied
Abu Darda, Halima Khatoon, Weqar Ahmad Siddiqi, Sharif Ahmad
Summary: This study synthesized sustainable oleo-polyurethanes using Pithecellobium Dulce seed oil and formulated nanocomposite coatings with improved antibacterial and anticorrosive properties. The addition of tungsten oxide and polythiophene nanofillers enhanced the performance of the coatings.
PROGRESS IN ORGANIC COATINGS
(2022)
Article
Nanoscience & Nanotechnology
Rangnath Ravi, Abhijeet Mishra, Anamika, Sharif Ahmad
Summary: This study reported a novel green synthesis method using oleo-polyol as a surface modifier and synthesis agent for bimetallic magnetic magnesium ferrite nanoparticles. The nanoparticles exhibited superior anticancer activity compared to other metal oxides and magnesium oxide nanoparticles.
ACS APPLIED BIO MATERIALS
(2022)
Article
Nanoscience & Nanotechnology
Rangnath Ravi, Abhijeet Mishra, Sharif Ahmad, Sharif Ahmad
Summary: This article reports the green synthesis of bimetallic magnetic nanoparticles using oleo-polyol as a surface modifier and synthesis agent. The properties of the synthesized nanoparticles and their application as anticancer agents against lung cancer cells have been investigated. The effects of calcination temperature on particle size, crystallite size, and saturation magnetization have also been analyzed.
ACS APPLIED BIO MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
H. M. Khan, S. Mumtaz, A. Waheed, J. Ahmad, M. E. Mazhar, W. Abbas, I Khan, M. N. Usmani, S. Bakhtawara, A. Javed, G. A. Ashraf, S. Ahmad, R. Naz
Summary: The study investigated the effect of Indium-Manganese substitution on the structural, electrical, and dielectric properties of hexaferrites prepared using the sol-gel auto combustion method. It was found that the lattice constant c decreased and grain size reduced with increasing In-Mn substitution concentration. Improved dielectric properties make these materials useful for applications in inductors, transformers, isolators, and magnetic memory devices.
JOURNAL OF OVONIC RESEARCH
(2021)
Article
Nanoscience & Nanotechnology
Ashiq Hussain Pandit, Nasreen Mazumdar, Khalid Imtiyaz, M. Moshahid Alam Rizvi, Sharif Ahmad
ACS APPLIED BIO MATERIALS
(2020)
Article
Chemistry, Multidisciplinary
Mohammad Irfan Bakshi, Sharif Ahmad
NEW JOURNAL OF CHEMISTRY
(2020)
Article
Materials Science, Composites
Neha Kanwar Rawat, Halima Khatoon, Sayma Kahtun, Sharif Ahmad
COMPOSITES COMMUNICATIONS
(2019)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)