Article
Materials Science, Ceramics
Zhangfa Huang, Zhijun Liu, Hua Hu, Jianxin Wang, Ming Chen, Baohua Cao, Qin Wang, Jun Yang, Wanbing Guan, Tongxiang Liang
Summary: A Co-containing composite cathode material with low thermal expansion coefficient and good compatibility has been prepared by the solid-liquid method. The cathode exhibits low polarization resistance and high power density, making it a promising material for intermediate temperature solid oxide fuel cells.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Caterina Sanna, Wenjing Zhang, Paola Costamagna, Peter Holtappels
Summary: The study reports the synthesis and electrochemical characterization of composite cathodes made from a mixture of LSCF and GDC nanofibers. The electrodes showed low polarization resistance at 650 degrees C, indicating promising potential for practical applications.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Ceramics
Leire Caizan-Juanarena, Javier Zamudio-Garcia, David Marrero-Lopez
Summary: This study investigated the electrochemical properties and ORR subprocesses of Pr6O11-infiltrated cathodes with different porous backbone layers. The results showed that a backbone layer with high ionic conductivity can decrease the polarization resistance, but also increase the series resistance.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Sung Eun Jo, SungHyun Jeon, Hyong June Kim, Byung Chan Yang, Kyoungjae Ju, Turgut M. Gur, WooChul Jung, Jihwan An
Summary: This study presents a novel method for achieving uniform functional coatings on high-tortuosity structures using powder atomic layer deposition (ALD). The authors successfully applied a ZrO2 coating to a porous composite electrode for solid oxide fuel cells, resulting in effective suppression of chemical degradation and improved power density. The findings have important implications for high-performance and durable electrodes in energy conversion/storage devices.
Article
Chemistry, Physical
Sea-Fue Wang, Yung-Fu Hsu, Yi-Le Liao, Shih-Ting Huang, Piotr Jasinski
Summary: The perovskite NdSrCo2O5+delta (NSCO) shows high electrical conductivity and is used as the cathode material for Ce0.8Gd0.2O2-delta (GDC)-supported microtubular solid oxide fuel cells (MT-SOFCs). By varying design parameters, the MT-SOFC with an outer tube diameter of 1.86 mm, an electrolyte thickness of 180 um, and a 5NSCO-5GDC composite cathode exhibits the best performance, with high power density and mechanical integrity. The results demonstrate the high electrochemical activity of the NSCO-GDC composite and exceed existing MT-SOFCs in terms of power density.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Changkun Cai, Manyi Xie, Ke Xue, Yu Shi, Shuting Li, Yuanyuan Liu, Shengli An, Hong Yang
Summary: This study successfully synthesized Ba2+-doped LBSCF materials and found that compared to undoped LSCF, Ba2+-doped LBSCF exhibits higher electrical conductivity and lower polarization resistance at 500-800 degrees Celsius, leading to a higher maximum power density for IT-SOFC technology.
Article
Chemistry, Multidisciplinary
Kyeong Eun Song, Sung Hun Woo, Seung Wook Baek, Hyunil Kang, Won Seok Choi, Jun Young Park, Jung Hyun Kim
Summary: In the SmBa1-xCaxCo2O5+d oxide systems, different compositions exhibited various electrical conductivity and metal-insulator transition behaviors. Among them, SBCCO-0.8 showed the highest electrical conductivity, while SBCCO-0.9 demonstrated excellent ASR characteristic at high temperature. The crystal structures of SBCCO were identified as orthorhombic, with unique X-ray diffraction peaks.
FRONTIERS IN CHEMISTRY
(2021)
Article
Chemistry, Physical
Leyu Shen, Zhihong Du, Yang Zhang, Xu Dong, Hailei Zhao
Summary: The study shows that medium-entropy perovskites Sr(FeαTiβCoγMnζ)O3-δ (SFTCM) have potential as cathode materials for IT-SOFC, with lower thermal expansion coefficients, suppressed strontium surface segregation, and more stable polarization resistance while slightly reducing catalytic activity towards oxygen reduction reaction.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Chemistry, Physical
Zhenwei Wang, Haibin Sun, Jiao Li, Xue Guo, Qiangqiang Hu, Zanzhong Yang, Fangyong Yu, Guochang Li
Summary: By infiltrating ESB, the polarization resistances and activation energy of LSCF cathodes were significantly reduced, improving the oxygen reduction reaction process and enhancing the performance of intermediate-temperature solid oxide fuel cells.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Materials Science, Ceramics
K. P. Padmasree, Ke-Yu Lai, Arumugam Manthiram
Summary: The calcium cobaltite Ca(3-x)La(x)Co(4-y)CuyO(9+delta) doped with x and y = 0 and 0.1 showed slightly affected electrical and thermal properties, with the undoped sample exhibiting improved symmetrical cell performance in intermediate-temperature solid oxide fuel cells.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Mingsong Hu, Meiran Chen, Yingchao Wang, Huining Zhao, Jungu Xu, Xin Tang
Summary: A new p-n semiconductor heterojunction of NaCrO2-CeO2 is proposed as a potential electrolyte for IT-SOFC with high ionic conductivity and power density. The heterostructure exhibits a substantial number of oxygen vacancies, with protons as the primary charge carriers. Semiconductor band arrangement calculations elucidate the mechanisms responsible for the enhanced ion transport and inhibited electron flow, contributing to the robust power output and ionic conductivity.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Ceramics
P. Safarzadeh Kermani, N. Rezaei, M. Ghatee
Summary: The study investigated the effects of phlogopite mica addition on BCAS glass seals, finding that a mica content of over 10% does not reach full density, while adding 5% phlogopite enhances mechanical properties of BCAS seals. It was also observed that the sintering temperature and mica content need to be carefully controlled within certain ranges for optimal performance.
CERAMICS INTERNATIONAL
(2021)
Article
Materials Science, Ceramics
Hongpeng Fan, Zhijun Liu, Yang Wu, Qin Wang, Jun Yang, Wanbing Guan, Liang Han, Jianxin Wang
Summary: The performance of solid oxide fuel cells is improved by physically mixing Ce0(.9)Gd0(.1)O(1.95) (GDC) in La0(.6)Sr0(.4)CoO(3-)(& delta;) (LSC) cathode. The grain size and chemical compatibility of the powder were analyzed using X-ray diffraction, and scanning electron microscopy was used to observe the microstructure of powder and cells. The LSC-GDC (5:5) cathode showed the minimal thermal expansion coefficient, smallest cathode polarization resistance, lowest activation energy, highest power density, and long-term stability.
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
(2023)
Article
Chemistry, Physical
Fei Han, Lijun Guo, Haochen Shi, Jialing Sun
Summary: Perovskite-type cathode Ba1-xCo0.7Fe0.2Nb0.1O3-delta (B1-xCFN, x = 0.0-0.15) shows a cubic perovskite structure with decreasing porosity as A-site deficiency increases, and the interfacial polarization resistance of B0.9CFN drops significantly at 800 degrees Celsius. Additionally, lattice oxygen generation is the major rate-limiting step when oxygen partial pressure is higher than 0.01 atm, and Ba deficiency accelerates the ionization process of oxygen atoms in the cathode bulk. The performance of single-cell B0.9CFN/SDC/Ni0.9Cu0.1-SDC is superior to other cathodes at operation temperature, indicating B0.9CFN as a better cathode for IT-SOFC.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Thermodynamics
Fulan Zhong, Zhiyu Li, Yu Luo, Huihuang Fang, Kongfa Chen, Chen Zhou, Chongqi Chen, Li Lin, Lilong Jiang
Summary: In this study, we fabricated a series of cobalt-based spinel oxides as cathodes for direct ammonia solid oxide fuel cell (DA-SOFC). The results showed that the oxide with nickel exhibited higher electronic conductivity and oxygen reduction reaction (ORR) activity, leading to a higher power density.
INTERNATIONAL JOURNAL OF GREEN ENERGY
(2022)
Review
Materials Science, Multidisciplinary
Hanchen Tian, Zheyu Luo, Yufei Song, Yucun Zhou, Mingyang Gong, Wenyuan Li, Zongping Shao, Meilin Liu, Xingbo Liu
Summary: In recent years, the hydrogen economy has gained strong support from governments and industrial bodies worldwide. Protonic ceramic electrochemical cells (PCECs) have attracted significant attention due to their lower operation temperature, reversible operation, and potential for further development. However, there are still many challenges that need to be addressed. This review aims to provide insightful perspectives on the critical challenges facing PCEC development, prioritize future efforts, and propose promising directions for advancement.
INTERNATIONAL MATERIALS REVIEWS
(2023)
Article
Electrochemistry
Yuting Xu, Jirong Mou, Ting Liu, Mei Li, Wenhao Pan, Lei Zhong, Jianlin Huang, Meilin Liu
Summary: A tubular template-assisted strategy was employed to fabricate cobalt nanoparticles embedded in one-dimensional N-doped porous tubular carbon composites. The catalyst exhibited outstanding oxygen reduction reaction performance, superior durability, and tolerance to methanol, making it suitable for zinc-air batteries.
Article
Chemistry, Physical
Xuejiao Li, Lei Zhang, Liuming Yan, Meilin Liu, Zhongfeng Tang
Summary: In this study, reactive molecular dynamics simulations were used to investigate the defect structures and ion transport mechanism of yttrium-doped barium zirconate (BZY) electrolyte. The study found that a slightly elongated O-O distance in the hydrated system promotes proton hopping and the weak interaction between dopants and protons facilitates proton diffusion in the dislocation system. The dopant concentration and proton concentration were identified as important factors affecting proton conduction.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Engineering, Environmental
Ting Liu, Shuang Cheng, Luping Li, Xu Ji, Gyutae Nam, Xingbin Yan, Meilin Liu
Summary: Rechargeable aqueous batteries are hindered by durability, capacity, and Coulombic efficiency issues. However, a new Ni-Zn system with concentrated gel electrolyte, ZnO@C anode, and Ni(OH)2 cathode shows improved stability and capacity. The battery also achieves a high midpoint discharge voltage and maintains high CE, with K+ insertion dominating the reaction mechanism.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Zheyu Luo, Yucun Zhou, Xueyu Hu, Weining Wang, Yong Ding, Weilin Zhang, Tongtong Li, Nicholas Kane, Zhijun Liu, Meilin Liu
Summary: This study reports a new class of hexavalent Mo/W-doped proton-conducting electrolyte, BaMo(W)(0.03)Ce0.71Yb0.26O3-delta, which exhibits excellent durability and high ionic conductivity. This material demonstrates significantly enhanced chemical stability against high concentrations of steam and carbon dioxide, while maintaining similar ionic conductivity. P-ReSOCs based on this material show high peak power densities in the fuel cell mode and can operate stably during steam electrolysis.
Article
Materials Science, Multidisciplinary
Fan He, Feng Zhu, Dongliang Liu, Yucun Zhou, Kotaro Sasaki, YongMan Choi, Meilin Liu, Yu Chen
Summary: The electrochemical activity and durability of an air electrode with Pr0.2Ba0.2Sr0.2La0.2Ca0.2CoO3-d (PBSLCC) is boosted through A-site entropy engineering. PBSLCC electrode demonstrates enhanced oxygen reaction activity and excellent durability compared to binary and ternary double perovskites. The high-entropy perovskite PBSLCC offers a rational design for air electrodes in reversible solid oxide electrochemical cells (R-SOECs) with high activity and durability.
Review
Materials Science, Multidisciplinary
Tong Hu, Fan He, Meilin Liu, Yu Chen
Summary: Solid oxide cells (SOCs) have gained widespread attention for their high efficiency in converting various fuels to electricity, renewable electricity to green hydrogen or value-added commodities, and tri-generation of power, heat, and hydrogen. Enhancing the electrocatalytic activity of electrodes through in situ/operando regulation of reaction processes on hetero-structured electrodes has been proven effective in improving the performance and durability of SOCs. The unique compositions, structures, and microscopic features of the heterostructures play a critical role in enhancing the electrocatalytic activity and durability of the electrodes.
PROGRESS IN MATERIALS SCIENCE
(2023)
Article
Chemistry, Physical
Tongtong Li, Shengchi Huang, Nicholas Kane, Jeng-Han Wang, Zheyu Luo, Weilin Zhang, Gyutae Nam, Bote Zhao, Yabing Qi, Meilin Liu
Summary: This study investigates the correlation between the structural evolution of Nb2O5 and its electrochemical properties during lithiation through in situ Raman spectroscopy. The lithium storage mechanism is unraveled using DFT calculations, including adsorption site preference, electronic structure, and specific pathways for lithium transport. This work provides important insights for the design of high-rate lithium storage materials based on niobium compounds.
ACS ENERGY LETTERS
(2023)
Article
Nanoscience & Nanotechnology
Nicholas Kane, Zheyu Luo, Yucun Zhou, Yong Ding, Alex Weidenbach, Weilin Zhang, Meilin Liu
Summary: Proton-conducting reversible solid oxide cells are a promising technology for efficient conversion between electricity and chemical fuels, making them well-suited for the deployment of renewable energies and load leveling. The bilayer electrolyte design combines a highly conductive electrolyte with a highly stable protection layer, enhancing chemical stability while maintaining high electrochemical performance.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Haoyu Li, Hyong June Kim, ThomasJae Garcia, Geonwoo Park, Yong Ding, Meilin Liu, Jihwan An, Min Hwan Lee
Summary: In this study, a highly effective approach to enhance air electrode performance and durability in solid oxide electrolyzer cells (SOECs) was presented. An ultrathin layer of metallic Ru was deposited onto (La0.6Sr0.4)(0.95)Co0.2Fe0.8O3-& delta; (LSCF) using plasma-enhanced atomic layer deposition (PEALD), resulting in the formation of SrRuO3 perovskite structure which played a crucial role in improving OER durability and reducing resistance to the ORR.
Article
Chemistry, Physical
Zhikai Shi, Chengwei Mao, Lei Zhong, Jiayao Peng, Meilin Liu, Hexing Li, Jianlin Huang
Summary: By incorporating molybdenum into the Ni3S4 lattices grown on carbonized wood, a novel electrocatalyst MoNi3S4/CW was created for overall water splitting. The addition of molybdenum optimizes the adsorption energy of hydrogen/oxygen species and regulates the local charge density of active sites, promoting the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). The electrolyzer composed of Mo-Ni3S4/CW electrodes shows low cell voltage and superior durability for overall water splitting.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Multidisciplinary
Ziming Wang, Ting Tan, Ke Du, Qimeng Zhang, Meilin Liu, Chenghao Yang
Summary: This study reports a new cathode for CO2 electrolysis, consisting of a high-entropy perovskite material coated with in situ exsolved CuFe alloy@FeOx nanoparticles. The cathode exhibits a consistently high current density and excellent stability under pure CO2 conditions, due to the introduction of oxygen vacancies and the extension of the triple-phase boundary.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Yoojin Ahn, Tongtong Li, Shengchi Huang, Yong Ding, Shineui Hwang, Weining Wang, Zheyu Luo, Jeng-Han Wang, Gyutae Nam, Meilin Liu
Summary: The mixed phase material d-H,M-Nb2O5 is reported as an excellent anode material for lithium-ion batteries, with the ability to store lithium quickly and maintain stability and reversibility during cycling. The unique structure of d-H,M-Nb2O5 promotes fast charging and high capacity retention over a large number of cycles.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
Wenwu Li, Jiajun Wen, Anjie Chen, Jeng-Han Wang, Meilin Liu, Ho Seok Park
Summary: The incorporation of Al and P into Ge leads to the synthesis of AlGexP (x = 6, 2, 2/3) series materials, which exhibit excellent Li-storage performance with high cycling stability and rate performance. The AlGe2P/C composite shows great potential for real-world applications.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Review
Chemistry, Physical
Yibo Hu, Haoyan Cheng, Haiting Chen, Shuge Dai, Kexing Song, Xin Ma, Meilin Liu, Hao Hu
Summary: This review provides a comprehensive overview of the current research activities focused on the molecular structure-controlled synthesis of sulfur-containing polymer cathode materials to improve the electrochemical performance of Li-S batteries. The design strategies, synthetic methods, and electrochemical activities of sulfur-containing polymers are discussed, along with the existing problems and future development trends in Li-S systems.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Chemistry, Physical
Mei Gui Vanessa Wee, Amutha Chinnappan, Runxin Shang, Poh Seng Lee, Seeram Ramakrishna
Summary: Cooling processes, from residences to industries, require a lot of energy and are essential. This study introduces MIL-101(Cr), a new desiccant, to heat exchangers for more efficient cooling. By improving the synthesis method and using a special binder, the MIL-101(Cr)-coated heat exchanger shows improved water uptake capacity and lower regeneration temperature.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ao Zhen, Guanyu Zhang, Ao Wang, Feng Luo, Jiehua Li, Hong Tan, Zhen Li
Summary: In this study, a solvent-free microemulsion method was used to synthesize waterborne polyurethane (WPU) material with high retention of mechanical properties and satisfactory water absorption rates. The material showed excellent biocompatibility and has broad application potential in the field of biomedicine.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Wensong Ge, Rui Wang, Xiaoyang Zhu, Houchao Zhang, Luanfa Sun, Fei Wang, Hongke Li, Zhenghao Li, Xinyi Du, Huangyu Chen, Fan Zhang, Huifa Shi, Huiqiang Hu, Yongming Xi, Jiankang He, Liang Hu, Hongbo Lan
Summary: This paper reviews the research on the surface tension of eutectic gallium-indium alloys (EGaIn) in the field of stretchable electronics. It covers the principles of oxide layer formation, factors influencing surface tension, and methods for surface modification of liquid metals. The paper also discusses the applications of EGaIn surface modification in different fields and highlights the challenges still faced and the future outlook.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiang Song, Lianghao Jia, Zhengen Wei, Tao Xiang, Shaobing Zhou
Summary: This paper provides an overview of the application, preparation, and role of biomimetic structures in solar evaporators with improved evaporation rate and lifetime.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Wei Yuan, Qian Deng, Dong Pan, Xiang An, Canyang Zhao, Wenjun Su, Zhengmin He, Qiang Sun, Ran Ang
Summary: Optimizing the performance of n-type PbTe thermoelectric materials is crucial for practical applications. Dynamic doping has emerged as an effective method to improve the performance of n-type PbTe by optimizing the carrier concentration. This study demonstrates the significance of Mn alloying in enhancing the performance of Ag-doped n-type PbTe by creating a hierarchical structure to suppress thermal transport and improving the Seebeck coefficient.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Review
Chemistry, Physical
Xiaoyan Wang, Meiqi Geng, Shengjun Sun, Qian Xiang, Shiyuan Dong, Kai Dong, Yongchao Yao, Yan Wang, Yingchun Yang, Yongsong Luo, Dongdong Zheng, Qian Liu, Jianming Hu, Qian Wu, Xuping Sun, Bo Tang
Summary: This review provides a comprehensive analysis of the progress and challenges in the field of bifunctional electrocatalysts and efficient electrolyzers for seawater splitting. It summarizes recent advancements and proposes future perspectives for highly efficient bifunctional electrocatalysts and electrolyzers.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Jason K. Phong, Christopher B. Cooper, Lukas Michalek, Yangju Lin, Yuya Nishio, Yuran Shi, Huaxin Gong, Julian A. Vigil, Jan Ilavsky, Ivan Kuzmenko, Zhenan Bao
Summary: Dynamic block copolymers (DBCPs) combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers, resulting in the spontaneous self-assembly of high aspect ratio nanofibers with well-ordered PEG and PDMS domains. DBCPs with a periodic block sequence exhibit superior properties compared to those with a random sequence, including delayed onset of terminal flow and higher ionic conductivity values.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Hong Kyu Lee, Yasaswini Oruganti, Jonghyeon Lee, Seunghee Han, Jihan Kim, Dohyun Moon, Min Kim, Dae-Woon Lim, Hoi Ri Moon
Summary: This study reports the moisture-triggered proton-conductivity switching behavior in Zn5FDC MOFs induced by the presence and absence of coordinating solvents, which illustrates the significant role of coordinating solvents in conductivity variation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Bommaramoni Yadagiri, Sanjay Sandhu, Ashok Kumar Kaliamurthy, Francis Kwaku Asiam, Jongdeok Park, Appiagyei Ewusi Mensah, Jae-Joon Lee
Summary: The molecular engineering of the interface modulator between the perovskite and hole transporting material is crucial for achieving satisfactory performance and stability of perovskite solar cells. In this study, cruciform-shaped dual functional organic materials were employed as surface passivation and hole transporting interfacial layers in perovskite solar cells. The use of these materials significantly improved the power conversion efficiency of the solar cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Joaquin Martinez-Ortigosa, Reisel Millan, Jorge Simancas, Manuel Hernandez-Rodriguez, J. Alejandro Vidal-Moya, Jose L. Jorda, Charlotte Martineau-Corcos, Vincent Sarou-Kanian, Mercedes Boronat, Teresa Blasco, Fernando Rey
Summary: This study investigates the synthesis of all-silica RTH zeolites using triisopropyl(methyl)phosphonium as the organic SDA. The results show the formation of two distinct crystalline phases under different synthesis conditions, with fluoride bonding to different silicon sites. It demonstrates the possibility of controlling the placement of fluoride in RTH zeolites through synthesis conditions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Luyao Zheng, Cong Liu, Wenbiao Zhang, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
Summary: This study successfully improves the efficiency and stability of water splitting by constructing a heterostructured electrocatalyst. The catalyst shows extraordinary performance and could offer an effective approach for the sustainable production of hydrogen.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Carlos A. Campos-Roldan, Raphael Chattot, Frederic Pailloux, Andrea Zitolo, Jacques Roziere, Deborah J. Jones, Sara Cavaliere
Summary: This study systematically evaluated the hydrogen evolution/oxidation reactions on a series of Pt-rare earth nanoalloys in alkaline media, and identified the effect of the lanthanide contraction. The experimental results revealed that the chemical nature of the rare earth modulates the adsorption and mobility of oxygenated-species, enhancing the kinetics of the reactions.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Sara Frank, Mads Folkjaer, Mads L. N. Nielsen, Melissa J. Marks, Henrik S. Jeppesen, Marcel Ceccato, Simon J. L. Billinge, Jacopo Catalano, Nina Lock
Summary: This study investigates the thermal decomposition of ZIF-67 and its correlation with structural evolution and electrocatalytic performance. The researchers used in situ X-ray absorption spectroscopy and total scattering techniques to analyze the process. They found that disorder emerges at lower temperatures and that extending the pyrolysis process can result in materials with superior electrochemical properties.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Zi-Yang Zhang, Hao Tian, Han Jiao, Xin Wang, Lei Bian, Yuan Liu, Nithima Khaorapapong, Yusuke Yamauchi, Zhong-Li Wang
Summary: By constructing Cu-0-Cu+-NH2 composite interfaces with the assistance of SiO2, the electrochemical CO2 reduction reaction (CO2RR) achieves high Faraday efficiency and current density for C2+ production, improving the productivity of carbon cycle.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)
Article
Chemistry, Physical
Ting Wang, Ruijuan Zhang, Pengda Zhai, Mingjie Li, Xinying Liu, Chaoxu Li
Summary: This study successfully exfoliated COFs using a simple electrochemical method, which resulted in improved photocatalytic performance for COFs and enriched the fabrication approach of COF exfoliation.
JOURNAL OF MATERIALS CHEMISTRY A
(2024)