期刊
JOURNAL OF MATERIALS CHEMISTRY A
卷 1, 期 22, 页码 6535-6538出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ta10918f
关键词
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资金
- NSF of China [20771090, 20931005, 91022004]
- Doctoral Program of Higher Education of China [20096101110005]
- NSF of Shaanxi, China [2009JZ001]
A new porous metal-organic framework based on paddle-wheel Zn-2 units and an unsymmetrical pyridyl dicarboxylate, contains a 3D intersecting pore system with uncommon stepwise adsorption and hysteretic desorption behavior for N-2, CO2 and H-2 gases at low temperature, and shows high selectivity for CO2 over N-2 at ambient temperature.
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