4.6 Article

A dandelion-like carbon microsphere/MnO2 nanosheets composite for supercapacitors

期刊

JOURNAL OF ENERGY CHEMISTRY
卷 23, 期 1, 页码 82-90

出版社

ELSEVIER SCIENCE BV
DOI: 10.1016/S2095-4956(14)60121-2

关键词

manganese oxide nanosheet; carbon microsphere (CMS); composite electrode; supercapacitor

资金

  1. National Natural Science Foundation of China [51203071, 21163010, 51363014, 51362018]
  2. Chinese Ministry of Education [212183]
  3. Natural Science Funds for Distinguished Young Scholars of Gansu Province [1111RJDA012]

向作者/读者索取更多资源

This article reported the electrochemical performance of a novel cabon microsphere/MnO2 nanosheets (CMS/MnO2) composite prepared by a in situ self-limiting deposition method under hydrothermal condition. The results of scanning electron microscopy (SEM) and transmission electron microscopy (TEM) revealed that MnO2 nanosheets homogeneously grew onto the surface of CMS to form a loose-packed and dandelion-like core/shell microstructure. The unique microstructure plays a basic role in electrochemical accessibility of electrolyte to MnO2 active material and a fast diffusion rate within the redox phase. The results of cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectrometry indicated that the prepared CMS/MnO2 composite presented high capacitance of 181 F.g(-1) and long cycle life of 61% capacity retention after 2000 charge/discharge cycles in 1 mol/L Na2SO4 solution, which show strong promise for high-rate electrochemical capacitive energy storage applications.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Electrochemistry

Insights into sodium-ion batteries through plateau and slope regions in cyclic voltammetry by tailoring bacterial cellulose precursors

Fujuan Wang, Tianyun Zhang, Fen Ren

Summary: This study investigates the sodium ions storage behaviors in porous carbon materials by modifying the bacterial cellulose precursor with sulfuric acid and two-step carbonization. The changes in structural parameters help improve the plateau and slope capacity of hard carbon. The results show that pre-carbonization of bacterial cellulose precursors via H2SO4 treatment introduces oxygen groups, which benefits the enhancement of slope and plateau capacity. The obtained bacterial cellulose-based carbon material exhibits good discharging capacity and enhanced plateau-slope capacity.

ELECTROCHIMICA ACTA (2023)

Article Electrochemistry

Capacitive charge storage mechanism in sanmartinite to be determined by qualitative and quantitative electrochemical analysis

Jian-Fei Gao, Jing-Feng Hou, Ling-Bin Kong

Summary: Pseudocapacitive behavior is a highly studied topic in the field of electrochemistry. Accurately distinguishing between capacitive, pseudocapacitive, and battery behavior is a challenging task. Moreover, the discovery of non-Faraday capacitive charge storage mechanism in non-carbon-based materials has posed difficulties in defining the electrochemical behavior of newly discovered materials. This study presents the first report on the pseudocapacitance behavior of sanmar-tinite (ZnWO4), showing ideal rectangular cyclic voltammetry curves and isosceles triangle galvanostatic charge/discharge curves. The calculated value of b, 0.88, further confirms that the kinetic process is controlled by surface capacitance.

ELECTROCHIMICA ACTA (2023)

Article Electrochemistry

Construction of diphenic acid molecular welded Ti3C2 with enlarged and stable interlayer spacing towards high rate alkali metal ions storage

Bei Zhao, Mao-Cheng Liu, Dong-Ting Zhang, Ya-Qin Wang, Hao Chen, Ling-Bin Kong, Cheng-Gong Chang

Summary: Ti3C2-MXene has been widely studied for energy storage applications due to its adjustable surface chemistry, excellent electronic conductivity, and unique layered structure. However, the diffusion kinetics of alkali metal ions in Ti3C2 is limited by the interlayer spacing. In this study, a diphenic acid (DHA) molecular welding strategy is used to prepare DHA-Ti3C2 with enlarged interlayer spacing, improving ion diffusion rate and structure stability. DHA-Ti3C2 exhibits high rate capability and long-term cycle stability with specific capacities of 444 mAh g(-1) and 156 mAh g(-1) after 200 cycles and 1700 cycles in Li+/Na+ batteries, respectively. This study provides a strategy to efficiently tune the layered structure of 2D materials for optimal alkali metal ions storage performance.

ELECTROCHIMICA ACTA (2023)

Article Chemistry, Analytical

An underlying nickel difluoride material as bifunctional electrode for energy storage and hydrogen evolution reaction

Zheng-Hua He, Jian-Fei Gao, Ling -Bin Kong

Summary: Supercapacitors (SC) and hydrogen evolution reactions (HER) play important roles in electrochemical storage and conversion. Developing low-cost and high-performance materials for SCs and HER devices is crucial. Nickel-based materials have advantages as both positive materials for SCs and hydrogen evolution catalysts. In this study, NiF2 material with rutile phase structure was prepared and showed excellent electrochemical performance, including high specific capacitance and good rate performance in alkaline electrolyte, and stable hydrogen evolution at low overpotential in acidic electrolyte. Therefore, NiF2 holds great promise as a future electrode material for SCs and HER.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2023)

Article Chemistry, Physical

Construction of Mo2N nanoparticles embedded in N, O-doped carbon sheets and its supercapacitive behaviors

Yongtao Tan, Yuling Zhu, Haibo Li

Summary: The Mo2N nanoparticles embedded in N, O co-doped carbon sheets composite (Mo2NNPs/NOCS) is a promising electrode material for supercapacitors. These nanoparticles are fabricated by in-situ growth on the surface of self-sacrifice C3N4. The optimized material shows a maximum specific capacitance of 294 F g-1 at 0.5 A g-1. Moreover, when assembled with a commercial activated carbon YP50 as a positive electrode, the supercapacitor device achieves a high energy density of 13.6 Wh kg-1 in an acid electrolyte.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Chemistry, Physical

Solvothermally prepared hydrated VO2(B) for aqueous zinc ion batteries with high capacity and excellent rate capability

Meng-Xin Bai, Zheng-Hua He, Jing-Feng Hou, Jian-Fei Gao, Ling-Bin Kong

Summary: In this study, a solvothermal method was used to prepare curled hydrated VO2(B) nanosheets with modified morphology and structure. The VO2(B) exhibited high specific capacity and retention rate, as well as impressive energy and power density. Such excellent performance was attributed to the suitable nanostructure, high capacitance-controlled kinetic behavior, fast Zn2+ diffusion, and sustained crystal water structure. The energy storage mechanism of the material was H+/Zn2+ co-insertion.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Materials Science, Multidisciplinary

Fast-charging cathode materials for lithium & sodium ion batteries

Meimei Yuan, Hongjun Liu, Fen Ran

Summary: This article highlights the key kinetically limiting factors in the fast-charging process from the perspective of cathodic materials and describes the currently reported fast-charging cathode materials with improved rapid ions diffusion capability and fast reaction kinetics. It discusses a series of strategies, including nanostructure, doping, and multiple-system, while emphasizing the importance of pseudocapacitive contribution in constructing fast-charging lithium-ion batteries and sodium-ion batteries.

MATERIALS TODAY (2023)

Article Chemistry, Multidisciplinary

Salting out in Hofmeister Effect Enhancing Mechanical and Electrochemical Performance of Amide-based Hydrogel Electrolytes for Flexible Zinc-Ion Battery

Guanghua Cao, Lei Zhao, Xiwei Ji, Yuanyou Peng, Meimei Yu, Xiangya Wang, Xiangye Li, Fen Ran

Summary: In this study, a gelatin-ZnSO4 hydrogel electrolyte membrane is fabricated, which exhibits high mechanical strength and ionic conductivity. The application of this electrolyte membrane in supercapacitors and zinc-ion batteries demonstrates its excellent mechanical and electrochemical performance for flexible energy storage devices.
Article Chemistry, Physical

Construction and regulation of molybdenum carbide/carbon hollow microtube composite and its supercapacitive behaviors

Yongtao Tan, Yuling Zhu, Haibo Li

Summary: The crystal structure has a significant impact on the electrochemical performance. In this study, the molybdenum carbide/carbon hollow microtube (MoC/CHMT) composite was synthesized by carbonating polydopamine-encapsulated Mo-MOF material. The crystal structure of molybdenum carbide in the composite was controlled by adjusting the mass of dopamine during polymerization. The optimized MoC/CHMT exhibited hollow microtubes morphology with small molybdenum carbide nanoparticles on the surface, and it achieved a high specific capacitance of 513.5 F g(-1) at a current density of 0.5 A g(-1). The YP50//MoC/CHMT device showed a maximum energy density of 17.5 Wh kg(-1).

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Materials Science, Multidisciplinary

Bioabsorbable fabrication of molybdenum nitride/carbon nanocomposites for supercapacitors and metal ion batteries with robust stability

Qiang-Hong Wu, Huan-Zhong Zeng, You-Zhi Wu, Fen Ran

Summary: A new bioabsorbable method for preparing molybdenum nitride combined with porous carbon materials has been developed in this study. The obtained composite material exhibits good electrochemical performance as anode material in supercapacitors and batteries.

RARE METALS (2023)

Article Chemistry, Multidisciplinary

Designing CoHCF@FeHCF Core-Shell Structures to Enhance the Rate Performance and Cycling Stability of Sodium-Ion Batteries

Zu-Tao Pan, Zheng-Hua He, Jing-Feng Hou, Ling-Bin Kong

Summary: Prussian blue analogs, specifically CoHCF and FeHCF, have different performance as sodium-ion battery cathode materials. The core-shell structure of CoHCF@FeHCF improves rate performance and cycling stability compared to unmodified CoHCF.
Article Chemistry, Multidisciplinary

Hollow nanocages of vanadium nitride-based electrode material designed for superior charging/discharging stability supercapacitors

Hao Dang, Lu Wang, Yuanyou Peng, Tianqi He, Fen Ran

Summary: Vanadium nitride quantum dot composites are prepared by in situ replacement using a ZIF-8 dodecahedral structure, resulting in a material with good electrochemical performance and enhanced cycling stability.

NEW JOURNAL OF CHEMISTRY (2023)

Article Chemistry, Multidisciplinary

Strengthened Interficial Adhesive Fracture Energy by Young's Modulus Matching Degree Strategy in Carbon-Based HTM Free MAPbI3 Perovskite Solar Cell with Enhanced Mechanical Compatibility

Wen-Wu Liu, Cai-Xia Li, Chong-Yang Cui, Guang-Long Liu, Yi-Xiao Lei, Ya-Wen Zheng, Shi-Ji Da, Zhi-Qiang Xu, Rong Zou, Ling-Bin Kong, Fen Ran

Summary: This study demonstrates the use of a soft-structured long-chain 2D pentanamine iodide (PI) to improve the quality and stability of carbon-based perovskite solar cells (PSCs). The PI effectively passivates defects at grain boundaries and reduces residual stress during high temperature annealing. As a result, the photoelectric conversion efficiency and operational stability of PSCs are significantly enhanced.
Article Chemistry, Physical

A pinning structure via composing laminar rGO with fragmented MoS2 toward fast and stable sodium and lithium-ion storage

Rui Liu, Huanzhong Zeng, Yuanyou Peng, Yumeng Wang, Fen Ran

Summary: The diffusion rate of ions in the anode materials is crucial for the fast-charging performance of lithium and sodium-ion batteries. By designing MoS2/rGO composite materials with pinned structures, the ion diffusion rate and capacity can be improved, resulting in high capacity and stability for fast-charging.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Engineering, Environmental

Integrating supercapacitor with sodium hyaluronate based hydrogel as a novel All-In-One wound Dressing: Self-Powered electronic stimulation

Xiangya Wang, Weijie Zhang, Qi Zhou, Fen Ran

Summary: This study introduces a novel all-in-one self-powered electronic stimulated wound dressing, which integrates a supercapacitor with a sodium hyaluronate based hydrogel. The wound dressing is able to perform electrical stimulation without the need for an external power supply, enabling patients to receive treatment anywhere and anytime. The introduction of sodium hyaluronate promotes cell proliferation and accelerates wound healing, while also improving the electrochemical performance of the supercapacitor. This all-in-one wound dressing has excellent mechanical properties, high water absorption capacity, and good biocompatibility, meeting the practical requirements for clinical wound dressings.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Chemistry, Applied

In-situ coating and surface partial protonation co-promoting performance of single-crystal nickel-rich cathode in all-solid-state batteries

Maoyi Yi, Jie Li, Mengran Wang, Xinming Fan, Bo Hong, Zhian Zhang, Aonan Wang, Yanqing Lai

Summary: In this study, polyacrylic acid (PAA) was used as a binder for the cathode in all-solid-state batteries. Through H+/Li+ exchange reaction, a uniform PAA-Li coating layer was formed on the cathode surface, improving the stability of the cathodic interface and the crystal structure. The SC-NCM83-PAA cathode exhibited superior cycling performance compared to traditional PVDF binder.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Arbitrary skin metallization by pencil-writing inspired solid-ink rubbing for advanced energy storage and harvesting

Yonghan Zhou, Zhongfeng Ji, Wenrui Cai, Xuewei He, Ruiying Bao, Xuewei Fu, Wei Yang, Yu Wang

Summary: By learning from the pencil-writing process, a solid-ink rubbing technology (SIR-tech) has been invented to develop durable metallic coatings on diverse substrates. The composite metallic skin by SIR-tech outperforms pure liquid-metal coating and shows great potential for various applications.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Coupling Sb2WO6 microflowers and conductive polypyrrole for efficient potassium storage by enhanced conductivity and K plus diffusivity

Ruiqi Tian, Hehe Zhang, Zeyu Yuan, Yuehua Man, Jianlu Sun, Jianchun Bao, Ming-Sheng Wang, Xiaosi Zhou

Summary: In this study, polypyrrole-encapsulated Sb2WO6 microflowers were synthesized and demonstrated to exhibit excellent potassium storage properties and cycling stability. The improved performance of Sb2WO6@PPy was attributed to the unique microflower structure, enhanced electronic conductivity, and protective PPy coating.

JOURNAL OF ENERGY CHEMISTRY (2024)

Review Chemistry, Applied

Physics-based battery SOC estimation methods: Recent advances and future perspectives

Longxing Wu, Zhiqiang Lyu, Zebo Huang, Chao Zhang, Changyin Wei

Summary: This paper presents a comprehensive survey on physics-based state of charge (SOC) algorithms applied in advanced battery management system (BMS). It discusses the research progresses of physical SOC estimation methods for lithium-ion batteries and presents future perspectives for this field.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

d-d Orbital coupling induced by crystal-phase engineering assists acetonitrile electroreduction to ethylamine

Honggang Huang, Yao Chen, Hui Fu, Cun Chen, Hanjun Li, Zhe Zhang, Feili Lai, Shuxing Bai, Nan Zhang, Tianxi Liu

Summary: The d-d orbital coupling induced by crystal-phase engineering effectively adjusts the electronic structure of electrocatalysts, improving their activity and stability, which is significant for electrocatalyst research.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

In-doping collaboratively controlling back interface and bulk defects to achieve efficient flexible CZTSSe solar cells

Quanzhen Sun, Yifan Li, Caixia Zhang, Shunli Du, Weihao Xie, Jionghua Wu, Qiao Zheng, Hui Deng, Shuying Cheng

Summary: In this study, indium (In) ions were introduced into flexible Cu2ZnSn(S,Se)(4) (CZTSSe) solar cells to modify the back interface and passivate deep level defects in CZTSSe bulk. The results showed that In doping effectively inhibited the formation of secondary phase and V-Sn defects, decreased the barrier height at the back interface, passivated deep level defects in CZTSSe bulk, increased carrier concentration, and significantly reduced the V-OC deficit. Eventually, a flexible CZTSSe solar cell with a power conversion efficiency of 10.01% was achieved. This synergistic strategy of interface modification and bulk defects passivation through In incorporation provides a new approach for fabricating efficient flexible kesterite-based solar cells.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Toward a comprehensive hypothesis of oxygen-evolution reaction in the presence of iron and gold

Negah Hashemi, Jafar Hussain Shah, Cejun Hu, Subhajit Nandy, Pavlo Aleshkevych, Sumbal Farid, Keun Hwa Chae, Wei Xie, Taifeng Liu, Junhu Wang, Mohammad Mahdi Najafpour

Summary: This study investigates the effects of Fe on the oxygen-evolution reaction (OER) in the presence of Au. The study identifies two distinct areas of OER associated with Fe and Au sites at different overpotentials. Various factors were varied to observe the behaviors of FeOxHy/Au during OER. The study reveals strong electronic interaction between Fe and Au, and proposes a lattice OER mechanism based on FeOxHy.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Exploring the impact of Nafion modifier on electrocatalytic CO2 reduction over Cu catalyst

Yingshi Su, Yonghui Cheng, Zhen Li, Yanjia Cui, Caili Yang, Ziyi Zhong, Yibing Song, Gongwei Wang, Lin Zhuang

Summary: This study systematically investigates the key roles of Nafion on Cu nanoparticles electrocatalyst for CO2RR. The Nafion modifier suppresses the hydrogen evolution reaction, increases CO2 concentration and mass transfer process, and activates CO2 molecule to enhance C2 product generation. As a result, the selectivity of the hydrogen evolution reaction is reduced and the efficiency of C2 products is significantly improved.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Electronic structure and spin state regulation of vanadium nitride via a sulfur doping strategy toward flexible zinc-air batteries

Daijie Deng, Honghui Zhang, Jianchun Wu, Xing Tang, Min Ling, Sihua Dong, Li Xu, Henan Li, Huaming Li

Summary: By doping sulfur into vanadium nitride, the S-VN/Co/NS-MC catalyst exhibits enhanced oxygen reduction reaction activity and catalytic performance. When applied in liquid and flexible ZABs, it shows higher power density, specific capacity, and cycling stability.

JOURNAL OF ENERGY CHEMISTRY (2024)

Review Chemistry, Applied

Self-assembly of perovskite nanocrystals: From driving forces to applications

Yi Li, Fei Zhang

Summary: Self-assembly of metal halide perovskite nanocrystals holds significant application value in the fields of display, detector, and solar cell due to their unique collective properties. This review covers the driving forces, commonly used methods, and different self-assembly structures of perovskite nanocrystals. Additionally, it summarizes the collective optoelectronic properties and application areas of perovskite superlattice structures, and presents an outlook on potential issues and future challenges in the development of perovskite nanocrystals.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Ag-integrated mixed metallic Co-Fe-Ni-Mn hydroxide composite as advanced electrode for high-performance hybrid supercapacitors

Anki Reddy Mule, Bhimanaboina Ramulu, Shaik Junied Arbaz, Anand Kurakula, Jae Su Yu

Summary: Direct growth of redox-active noble metals and rational design of multifunctional electrochemical active materials play crucial roles in developing novel electrode materials for energy storage devices. In this regard, silver (Ag) has attracted great attention in the design of efficient electrodes. The construction of multifaceted heterostructure cobalt-iron hydroxide (CFOH) nanowires (NWs)@nickel cobalt manganese hydroxides and/or hydrate (NCMOH) nanosheets (NSs) on the Ag-deposited nickel foam and carbon cloth (i.e., Ag/ NF and Ag/CC) substrates is reported. The as-fabricated Ag@CFOH@NCMOH/NF electrode delivered superior areal capacity value of 2081.9 μA h cm-2 at 5 mA cm-2. Moreover, as-assembled hybrid cell based on NF (HC/NF) device exhibited remarkable areal capacity value of 1.82 mA h cm-2 at 5 mA cm-2 with excellent rate capability of 74.77% even at 70 mA cm-2. Furthermore, HC/NF device achieved maximum energy and power densities of 1.39 mW h cm-2 and 42.35 mW cm-2, respectively. To verify practical applicability, both devices were also tested to serve as a self-charging station for various portable electronic devices.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Insights into ionic association boosting water oxidation activity and dynamic stability

Zanling Huang, Shuqi Zhu, Yuan Duan, Chaoran Pi, Xuming Zhang, Abebe Reda Woldu, Jing-Xin Jian, Paul K. Chu, Qing-Xiao Tong, Liangsheng Hu, Xiangdong Yao

Summary: In this study, it was found that Ni sites act as a host to attract Fe(III) to form Fe(Ni)(III) binary centers, which promote the oxygen evolution reaction (OER) activity and stability by cyclical formation of intermediates. Additionally, other ions can also catalyze the OER process on different electrodes.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Reversible Mn2+/Mn4+double-electron redox in P3-type layer-structured sodium-ion cathode

Jie Zeng, Jian Bao, Ya Zhang, Xun-Lu Li, Cui Ma, Rui-Jie Luo, Chong-Yu Du, Xuan Xu, Zhe Mei, Zhe Qian, Yong-Ning Zhou

Summary: The balance between cationic redox and oxygen redox is crucial for achieving high energy density and cycle stability in sodium batteries. This study demonstrates the reversible Mn2+/Mn4+ redox in a P3-Na0.65Li0.2Co0.05Mn0.75O2 cathode material through Co substitution, effectively suppressing the contribution of oxygen redox and improving structure stability.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

The initial stages of Li2O2 formation during oxygen reduction reaction in Li-O2 batteries: The significance of Li2O2 in charge-transfer reactions within devices

Daniela M. Josepetti, Bianca P. Sousa, Simone A. J. Rodrigues, Renato G. Freitas, Gustavo Doubek

Summary: Lithium-oxygen batteries have high energy density potential but face challenges in achieving high cyclability. This study used operando Raman experiments and electrochemical impedance spectroscopy to evaluate the initial discharge processes in porous carbon electrodes. The results indicate that the reaction occurs at the Li2O2 surface and the growth of Li2O2 forms a more compact and homogeneous structure.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Porous metal oxides in the role of electrochemical CO2 reduction reaction

Ziqi Zhang, Jinyun Xu, Yu Zhang, Liping Zhao, Ming Li, Guoqiang Zhong, Di Zhao, Minjing Li, Xudong Hu, Wenju Zhu, Chunming Zheng, Xiaohong Sun

Summary: This paper explores the challenge of increasing global CO2 emissions and highlights the role of porous metal oxide materials in electrocatalytic reduction of CO2 (CO2RR). Porous metal oxides offer high surface area and tunability for optimizing CO2RR reaction mechanisms.

JOURNAL OF ENERGY CHEMISTRY (2024)