期刊
JOURNAL OF ENERGY CHEMISTRY
卷 23, 期 1, 页码 22-28出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S2095-4956(14)60113-3
关键词
carbon dioxide; epoxides; cyclic carbonate; polymer; capture capacity
资金
- National Science Foundation of China [21373202, 21173209]
- Chinese Academy of Sciences
- China Three Gorges University
We reported a bifunctional material, Cr-salen implanted conjugated microporous polymer (Cr-CMP), which is able to capture excellent CO2 amounts and has a remarkable catalytic activity towards the cycloaddition reaction of CO2 to epoxides forming cyclic carbonates at mild conditions without additional solvents. This heterogeneous Cr-CMP catalyst has a superior catalytic activity to its related homogeneous catalyst and can be reused more than ten times without a significant decrease in catalytic activity.
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