期刊
ECS ELECTROCHEMISTRY LETTERS
卷 2, 期 1, 页码 A6-A9出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/2.007301eel
关键词
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资金
- Energy Science in the Age of Global Warming of Global Center of Excellence (G-COE) program of the Ministry of Education, Culture, Sports, Science and Technology of Japan [J-051]
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) [24656581]
- Grants-in-Aid for Scientific Research [24656581] Funding Source: KAKEN
We electrochemically inserted various amounts of lithium into LiMn2O4 and investigated the relaxation structure after termination of lithium insertion by using X-ray diffraction measurement and Rietveld analysis. The mole fraction of the Li-lean phase decreased and that of the Li-rich phase increased with the relaxation time after lithium insertion. It is considered that the Li-lean phase containing excess lithium formed during the lithium insertion process separated into two phases, the Li-lean phase without excess lithium and the Li-rich phase, during the relaxation process after termination of lithium insertion. (c) 2012 The Electrochemical Society. All rights reserved.
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