4.6 Article

Structure and Properties of Regenerated Cellulose Filaments Prepared from Cellulose Carbamate-NaOH/ZnO Aqueous Solution

期刊

ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 2, 期 11, 页码 2604-2612

出版社

AMER CHEMICAL SOC
DOI: 10.1021/sc500559g

关键词

Cellulose filaments; Cellulose carbamate; Orientation; Mechanical properties; Dye properties

资金

  1. National Natural Science Foundation of China [51273151]
  2. Program for New Century Excellent Talents in University [NCET-11-0415]
  3. Natural Science Foundation of Hubei Province [2009CDA040]

向作者/读者索取更多资源

In this work, regenerated cellulose (RC) filaments were successfully spun from cellulose carbamate in a NaOH/ZnO aqueous solution on a pilot scale. The structure and properties of the RC filaments were characterized using SEM, FT-IR, elemental analysis, C-13 NMR, XRD, 2D WAXD, tensile testing, and dye testing. The nitrogen-free and sulfur-free RC filaments exhibited a bright surface and circular cross section. The filaments demonstrated a typical cellulose II crystal structure and a relatively high degree of orientation. Improved tenacity and structure were obtained in the RC fibers due to improved post-processing spinning steps and an increased drawing ratio. The tenacity of the fibers was determined in the range of 1.69-2.36 cN/dtex, which was comparable with that of commercial viscose rayon. Furthermore, the RC filaments showed improved dye properties compared with viscose rayon. The described carbamate pathway provided a simple and environmentally friendly method, offering an alternate to the environmental drawbacks of the viscose process.

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