期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 1, 期 1, 页码 91-101出版社
AMER CHEMICAL SOC
DOI: 10.1021/sc3000459
关键词
Bark-derived PF resins; Liquefied bark; Bark extractives; Chemical structures; Curing characteristics; Liquid-state C-13 NMR
资金
- Ontario Research Fund-Research Excellence project: Bark Biorefinery
In this study, two types of biobased bark-derived phenol formaldehyde (PF) resins, namely, liquefied bark-PP and bark extractive-PF, were synthesized from acid-catalyzed phenol-liquefied bark and bark alkaline extractives, respectively. The biobased resins were characterized for their chemical compositions and molecular structures using the liquid-state C-13 nuclear magnetic resonance (NMR) technique. The results indicated that the introduction of bark components (either as liquefied bark or as bark extractives) to the phenolic resin synthesis affected resin structures and curing performance. Methylene ether bridges were found in the bark-derived PF resins. Bark components made the formation of para ortho-methylene linkage more favorable in bark-derived PF resins than in lab PF resins. Molecular structures of the liquefied bark-PF resin differed significantly from those of the bark extractive-PF resins. The liquefied bark-PF resin showed a higher ratio of para-para/ortho-para-methylene link (-CH2-), a higher unsubstituted/substituted hydrogen (-H/-CH2OH) ratio and a higher methylol/methylene (-CH2OH/CH2-) ratio than the bark extractive-PF resin. The tannin components of the bark extractives accelerated the curing rate of the resulting bark extractive-PF resin. The bark extractives made the ortho position of phenol react more favorably with formaldehyde than the para position. The liquefied bark with phenolated structures had more reactive sites toward formaldehyde than the bark extractives and accelerated the curing rate of the resulting liquefied bark-PF resin.
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