Article
Chemistry, Physical
Hao Tang, Ariel Rebekah Barr, Guoqing Wang, Paola Cappellaro, Ju Li
Summary: Spin qubits associated with color centers show promise for various quantum technologies, but their intrinsic properties need to be known precisely under external conditions such as temperature and strain. This research develops a first-principles method to determine the temperature dependence of color centers' properties and demonstrates its accuracy with the NV-center in diamond. This method can be applied to different color centers and is useful for designing high-precision quantum sensors.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2023)
Article
Physics, Multidisciplinary
Zezhu Wei, V. F. Mitrovic, D. E. Feldman
Summary: The use of heat transport interferometry can reveal anyonic statistics in charge insulators, even in the absence of charged excitations. By studying the heat transport through different interferometer geometries in Kitaev spin liquids, such as Fabry-Perot and Mach-Zehnder, drastically different behaviors can be observed, demonstrating the effectiveness of this method.
PHYSICAL REVIEW LETTERS
(2021)
Article
Optics
Qin-Qin Wang, Si-Jing Tao, Wei-Wei Pan, Zhe Chen, Geng Chen, Kai Sun, Jin-Shi Xu, Xiao-Ye Xu, Yong-Jian Han, Chuan-Feng Li, Guang-Can Guo
Summary: Identifying the general mechanics behind the equilibration of a complex isolated quantum system towards a state described by only a few parameters has been the focus of attention. In this study, the relaxation of the spin subsystem in an isolated spin-orbit coupling quantum system is experimentally investigated, and the underlying mechanism of generalized thermalization is experimentally verified for the first time.
LIGHT-SCIENCE & APPLICATIONS
(2022)
Article
Multidisciplinary Sciences
Cheng Chi, Qiao Jiang, Zhixin Liu, Liheng Zheng, Meiling Jiang, Han Zhang, Feng Lin, Bo Shen, Zheyu Fang
Summary: The study demonstrates selective manipulation of photon spin angular momentum at a deep subwavelength scale via electron-induced OSHE in Au nanoantennas, suggesting an information encoding scheme with robustness, privacy, and high level of integration for future quantum applications.
Article
Materials Science, Multidisciplinary
Ji Zou, Shu Zhang, Yaroslav Tserkovnyak
Summary: We theoretically investigate the dynamics of two spin qubits interacting with a magnetic medium. We show that a sizable long-lived entanglement can be established between the spin qubits via the magnetic environment, in the absence of any coherent coupling. Moreover, we demonstrate that maximally entangled two-qubit states can be achieved in this scheme when complemented by proper postselection.
Article
Quantum Science & Technology
Yu-Min Guo, Yi Shen, Li-Jun Zhao, Lin Chen, Mengyao Hu, Zhiwei Wei, Shao-Ming Fei
Summary: Quantum catalytic transformations are crucial in converting quantum entangled states under local operations and classical communications (LOCC). The key issues lie in the existence and limits of catalytic states, with necessary conditions based on the Schmidt coefficients of entangled source and target states. Investigation into lower bounds on dimensions of catalytic states is conducted, along with a detailed protocol for quantum mixed state transformation under entanglement-assisted LOCC.
QUANTUM INFORMATION PROCESSING
(2021)
Article
Materials Science, Multidisciplinary
Jian-Yin Huang, Pei-Yun Li, Zong-Quan Zhou, Chuan-Feng Li, Guang-Can Guo
Summary: Er3+:Y2SiO5 is a material of interest for quantum memories and transducers, with recent research showing significant improvements in electron spin and nuclear spin coherence lifetimes at subkelvin temperatures. This enhanced coherence could be valuable for further applications in fiber-based quantum networks.
Article
Multidisciplinary Sciences
Qi Zhang, Yuhang Guo, Wentao Ji, Mengqi Wang, Jun Yin, Fei Kong, Yiheng Lin, Chunming Yin, Fazhan Shi, Ya Wang, Jiangfeng Du
Summary: The nitrogen-vacancy (NV) center in diamond is crucial for achieving high-fidelity single-shot readout of qubits, with a new spin-to-charge conversion method introduced to suppress spin-flip errors. This technique shows potential for exceeding fault-tolerant thresholds and may have applications in integrated optoelectronic devices.
NATURE COMMUNICATIONS
(2021)
Article
Physics, Multidisciplinary
Liang Fang, Hongya Wang, Yize Liang, Han Cao, Jian Wang
Summary: This study demonstrates the spin-orbit mapping of light in a few-mode fiber, showing high efficiency, large bandwidth, availability for short pulses, and scalability to high-order OAM states.
PHYSICAL REVIEW LETTERS
(2021)
Article
Materials Science, Ceramics
Clifton H. Bumgardner, Frederick M. Heim, David C. Roache, Alex Jarama, Morgan C. Price, Christian P. Deck, Xiaodong Li
Summary: Evaluation of SiC/SiC CMCs in tension and bending under different loading conditions reveals insights into crack initiation, stress redistribution mechanisms, and microstructural influences. The study reaffirms the current state of these composites for energy applications and provides valuable information for further improvements in SiC/SiC and other CMCs.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Physics, Multidisciplinary
Mohamad Niknam, Lea F. Santos, David G. Cory
Summary: The research proposes and experimentally measures an entropy that quantifies correlations among qubits in a nearly isolated quantum system. Due to spin-spin interactions, information flows from a central spin to surrounding ones forming clusters of multispin correlations that grow over time. A nuclear magnetic resonance experiment is used to directly measure the amplitudes of multispin correlations and compute the evolution of what is called correlation Renyi entropy, which continues to grow even after the equilibration of entanglement entropy. The study also analyzes how the saturation point and timescale for the equilibration of the correlation Renyi entropy depend on the system size.
PHYSICAL REVIEW LETTERS
(2021)
Article
Optics
Ling Hong, Xiyue Cao, Yuanyuan Chen, Lixiang Chen
Summary: In this study, the Hong-Ou-Mandel interference of spin-orbit hybrid photons is observed for the first time. Various forms of spin-orbit hybrid entangled photons are prepared using tunable q-plates as spin-orbit coupler devices. By harnessing the match degree in the temporal domain, the coalescence and anti-coalescence effects are observed, and the feasibility of quantum-enhanced photon polarization gears is demonstrated.
Article
Materials Science, Multidisciplinary
Liam Hanlon, Michael Olney-Fraser, Marcus W. Doherty, Lukas Razinkovas
Summary: The nitrogen-vacancy (NV) center in diamond is a highly studied defect with potential applications in quantum metrology and computation in ambient conditions. The ability to read out the spin state of the NV is crucial for its applications, and optical contrast is a key metric for electron spin readout fidelity. We propose a mechanism for high contrast readout using spin-to-charge conversion and electrode manipulation of NV energy levels, which predicts an optical spin contrast of 42% at room temperature and opens up alternative research pathways for the NV.
Article
Optics
W. F. Balthazar, D. G. Braga, V. S. Lamego, M. H. M. Passos, J. A. O. Huguenin
Summary: The paper introduces an all-optical setup to generate various X states using spin-orbit modes and a high intensity laser beam. By simulating spin-orbit tomography, the researchers were able to reconstruct the density matrix and study discord and concurrence for different states, showing good agreement with theoretical predictions. Additionally, two different optical circuits were proposed for preparing the single-photon spin-orbit X state.
Article
Quantum Science & Technology
D. M. Tennant, X. Dai, A. J. Martinez, R. Trappen, D. Melanson, M. A. Yurtalan, Y. Tang, S. Bedkihal, R. Yang, S. Novikov, J. A. Grover, S. M. Disseler, J. Basham, R. Das, D. K. Kim, A. J. Melville, B. M. Niedzielski, S. J. Weber, J. L. Yoder, A. J. Kerman, E. Mozgunov, D. A. Lidar, A. Lupascu
Summary: In this study, the properties of a spin chain implemented with superconducting flux circuits are explored, serving as a connectivity medium between two superconducting qubits. The experiment demonstrates that the chain has long-range, cross-chain correlations and enables interactions between the two end qubits mediated by the coupler chain. This work is of direct relevance to near term quantum annealing processors for generating long-range, coherent coupling between qubits.
NPJ QUANTUM INFORMATION
(2022)
Article
Nanoscience & Nanotechnology
Artur Trifonov, Stefan Grisard, Alexander N. Kosarev, Ilya A. Akimov, Dmitri R. Yakovlev, Julian Hoecker, Vladimir Dyakonov, Manfred Bayer
Summary: The optical properties of a methylammonium lead triiodide single crystal were studied, and an experimental photon-echo polarimetry method was developed to accurately determine the biexciton binding energy and optical coherence times.
Article
Chemistry, Multidisciplinary
Jeannine Gruene, Giacomo Londi, Alexander J. Gillett, Basil Staehly, Sebastian Lulei, Maria Kotova, Yoann Olivier, Vladimir Dyakonov, Andreas Sperlich
Summary: The development of non-fullerene acceptors (NFAs) in organic photovoltaics (OPV) has led to a significant progress in power conversion efficiencies, reaching nearly 20%. However, triplet states have been found to negatively affect device performance, leading to non-radiative losses and device degradation. A study using various spin-sensitive methods and quantum-chemical calculations identified the presence of triplet excitons in OPV blends, providing insights into the pathways for triplet formation and suggesting potential for improved charge generation to enhance OPV efficiencies.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Erik Kirstein, Evgeny A. . Zhukov, Dmitri R. . Yakovlev, Nataliia E. Kopteva, Carolin Harkort, Dennis Kudlacik, Oleh Hordiichuk, Maksym V. Kovalenko, Manfred Bayer
Summary: This research investigates the coherent spin dynamics of Ruddlesden-Popper (PEA)2PbI4 perovskites through picosecond pump-probe Kerr rotation experiments in an external magnetic field. The study identifies the Larmor spin precession of resident electrons with a spin dephasing time of 190 ps, as well as a long longitudinal spin relaxation time of 25 μs in weak magnetic fields. A significant anisotropy of the electron g-factor is also found, with in-plane value of +2.45 and out-of-plane value of +2.05. Furthermore, the exciton out-of-plane g-factor is measured to be +1.6 using magneto-reflectivity. This work contributes to the understanding of the spin-dependent properties and spin dynamics of two-dimensional perovskites.
Article
Chemistry, Multidisciplinary
Roman A. Babunts, Yulia A. Uspenskaya, Nikolai G. Romanov, Sergei B. Orlinskii, Georgy V. Mamin, Elena V. Shornikova, Dmitri R. Yakovlev, Manfred Bayer, Furkan Isik, Sushant Shendre, Savas Delikanli, Hilmi Volkan Demir, Pavel G. Baranov
Summary: Semiconductor colloidal nanoplatelets based on CdSe with magnetic Mn2+ ions show modified magneto-optical and spin-dependent properties. High-frequency electron paramagnetic resonance techniques were used to study the spin structure and dynamics of Mn2+ ions in core/shell CdSe/(Cd,Mn)S nanoplatelets. Two sets of resonances were observed, indicating different spin dynamics between surface and inner Mn2+ ions. The interaction between surface Mn2+ ions and 1H nuclei was measured using electron nuclear double resonance, providing information on the distances between Mn2+ ions and 1H nuclei.
Article
Chemistry, Multidisciplinary
Carolin Harkort, Dennis Kudlacik, Natalia E. E. Kopteva, Dmitri R. R. Yakovlev, Marek Karzel, Erik Kirstein, Oleh Hordiichuk, Maksym V. V. Kovalenko, Manfred Bayer
Summary: This article discusses the optical properties and spin phenomena of Ruddlesden-Popper type (PEA)(2)PbI4 perovskites. The Zeeman splitting of electrons and holes in a magnetic field was measured using spin-flip Raman scattering. The electron and hole g factors were evaluated, their anisotropies were measured, and the dynamic nuclear spin polarization induced by spin-polarized holes was detected.
Article
Multidisciplinary Sciences
E. Kirstein, N. E. Kopteva, D. R. Yakovlev, E. A. Zhukov, E. V. Kolobkova, M. S. Kuznetsova, V. V. Belykh, I. A. Yugova, M. M. Glazov, M. Bayer, A. Greilich
Summary: The spin dynamics and interaction of confined electrons or holes in perovskite nanocrystals are investigated using time resolved optical spectroscopy. Spin mode locking effect and nuclear focusing are observed in CsPb(Cl0.56Br0.44)(3) lead halide perovskite nanocrystals embedded in a glass matrix. The measured spin coherence time and spin dephasing time are 13 ns and a nanosecond respectively, and the developed theoretical model agrees well with the experimental data.
NATURE COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
T. S. Shamirzaev, A. V. Shumilin, D. S. Smirnov, D. Kudlacik, S. V. Nekrasov, Yu G. Kusrayev, D. R. Yakovlev, M. Bayer
Summary: This study investigated exciton recombination and spin dynamics in (In,Al)As/AlAs quantum dots with indirect band gap and type-I band alignment. The anisotropic exchange interaction in these quantum dots was found to be negligible, enabling the formation of spin-polarized bright excitons under quasi-resonant, circularly polarized excitation. The recombination and spin dynamics of excitons were controlled by the hyperfine interaction between the electron and nuclear spins. A kinetic model was developed to quantitatively describe the experimental data, taking into account the population dynamics of the bright and dark exciton states as well as the spin dynamics.
Article
Chemistry, Multidisciplinary
Stefan Grisard, Artur V. V. Trifonov, Ivan A. A. Solovev, Dmitri R. R. Yakovlev, Oleh Hordiichuk, Maksym V. V. Kovalenko, Manfred Bayer, Ilya A. A. Akimov
Summary: The compositional engineering of hybrid organic-inorganic lead halide perovskites is crucial for efficient solar cells and light-emitting devices. A study on the effect of bandgap fluctuations on coherent exciton dynamics in a mixed FA(0.9)Cs(0.1)PbI(2.8)Br(0.2) perovskite crystal using photon echo spectroscopy reveals a narrow homogeneous exciton line width and an exceptionally long exciton coherence time due to exciton localization at the nanoscale. The spectral and temperature dependences of the photon echo decay indicate that pure decoherence associated with elastic scattering on phonons is comparable with the exciton lifetime for low-energy excitons, while inelastic scattering to lower energy states dominates for high-energy excitons through phonon emission.
Article
Chemistry, Multidisciplinary
Olga O. Smirnova, Ina V. Kalitukha, Anna V. Rodina, Grigorii S. Dimitriev, Victor F. Sapega, Olga S. Ken, Vladimir L. Korenev, Nikolai V. Kozyrev, Sergey V. Nekrasov, Yuri G. Kusrayev, Dmitri R. Yakovlev, Benoit Dubertret, Manfred Bayer
Summary: This study investigates the optical alignment and orientation of excitons in colloidal nanoplatelets and evaluates their properties through theoretical analysis and experimental data.
Article
Chemistry, Multidisciplinary
Sergey R. Meliakov, Evgeny A. Zhukov, Evgeniya V. Kulebyakina, Vasilii V. Belykh, Dmitri R. Yakovlev
Summary: Coherent spin dynamics of charge carriers in CsPbBr3 perovskite nanocrystals were investigated using time-resolved pump-probe Faraday rotation and differential transmission techniques in a temperature range of 4-300 K and magnetic fields up to 500 mT. Electron spin Larmor precession was observed throughout the temperature range, and hole spin precession was also observed at temperatures below 50 K. The temperature dependence of spin-related parameters, such as Lande g-factor and spin dephasing time, were measured and analyzed. Photocharging of the nanocrystals with either electrons or holes was found to depend on the sample cooling regime, and the type of charge carrier could be identified through carrier spin Larmor precession.
Article
Chemistry, Multidisciplinary
Patrick Doerflinger, Yong Ding, Valentin Schmid, Melina Armer, Roland C. Turnell-Ritson, Bin Ding, Paul J. Dyson, Mohammad Khaja Nazeeruddin, Vladimir Dyakonov
Summary: This study investigates the effect of a stabilizing additive on the charge carrier mobility and lifetime in triple cation perovskite thin films under thermal stress. The results reveal different conductivity behaviors in two temperature regions and identify two dominant scattering mechanisms. The stabilizing additive limits temperature-activated mobile ions and retards degradation of the perovskite film, leading to improved performance and stability.
Article
Chemistry, Physical
Rik Hooijer, Andreas Weis, Waldemar Kaiser, Alexander Biewald, Patrick Doerflinger, Clement Maheu, Oleksandr Arsatiants, David Helminger, Vladimir Dyakonov, Achim Hartschuh, Edoardo Mosconi, Filippo De Angelis, Thomas Bein
Summary: Silver pnictohalides, as novel perovskite-inspired materials, have gained attention for their high stability, low toxicity, and promising efficiencies. However, research on the silver antimony iodides is lacking due to challenges in synthesis. In this study, the authors successfully prepared Ag-Sb-I thin films using thiourea as an additive and improved their morphology through alloying with copper. The resulting solar cells demonstrated an enhanced power conversion efficiency by reducing undesired side phases. The study also revealed the detrimental role of silver point defects and the beneficial effect of minor amounts of bismuth on the efficiency and stability of the Rudorffite materials.
CHEMISTRY OF MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Natalia E. Kopteva, Dmitri R. Yakovlev, Erik Kirstein, Evgeny A. Zhukov, Dennis Kudlacik, Ina V. Kalitukha, Victor F. Sapega, Oleh Hordiichuk, Dmitry N. Dirin, Maksym V. Kovalenko, Andreas Baumann, Julian Hoecker, Vladimir Dyakonov, Scott A. Crooker, Manfred Bayer
Summary: The optical properties of lead halide perovskite semiconductors near the bandgap are controlled by excitons. The exciton Landé or g-factor g(X) is a key parameter measured by reflectivity in magnetic fields. Exciton g-factors remain nearly constant in different lead halide perovskite crystals.
Article
Chemistry, Multidisciplinary
Sergey R. Meliakov, Vasilii V. Belykh, Ina V. Kalitukha, Aleksandr A. Golovatenko, Alessio Di Giacomo, Iwan Moreels, Anna V. Rodina, Dmitri R. Yakovlev
Summary: The coherent spin dynamics of electrons in CdSe colloidal nanoplatelets were investigated at different temperatures. The measurements revealed the g-factors of the nanoplatelets and the electron spin precession in a magnetic field. The results showed weak dependence of the spin dephasing time on temperature and the longitudinal spin relaxation time exceeding 10 ns even at room temperature. The observations also confirmed the negative charge of the nanoplatelets and revealed g-factor anisotropy.
Article
Materials Science, Multidisciplinary
Dmitri R. Yakovlev, Scott A. Crooker, Marina A. Semina, Janina Rautert, Johannes Mund, Dmitry N. Dirin, Maksym V. Kovalenko, Manfred Bayer
Summary: This study investigates exciton-polaritons in solution-grown CsPbBr3 crystals by measuring circularly polarized reflection spectroscopy in high magnetic fields. Detailed quantitative information about the exciton-polariton parameters was obtained, showing that the exciton states can be described using a hydrogen-like model.
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
(2023)