期刊
ACS MACRO LETTERS
卷 3, 期 7, 页码 689-692出版社
AMER CHEMICAL SOC
DOI: 10.1021/mz5002959
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资金
- ND EPSCoR through NSF [EPS-0814442]
- University of North Dakota
- NIH from the INBRE program of the National Center for Research Resources [P20 RR016741]
A family of chiral zinc amido-oxazolinate complexes are shown to be highly active and isoselective initiators for the ring-opening polymerization (ROP) of rac-lactide, yielding isotactic stereoblock polylactides (PLA) with P-m up to 0.91. This represents the highest isoselectivity observed with zinc-based catalysts for ROP of rac-lactide.
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