Mechanically Linked Block/Graft Copolymers: Effective Synthesis via Functional Macromolecular [2]Rotaxanes

An effective method to synthesize mechanically linked transformable block polymer was developed utilizing functional macromolecular [2]rotaxane with a fixed or movable wheel. The interaction between a sec-ammonium and a dibenzo-24-crown-8-ether was the key to control the mobility of the wheel component, indicating the capability of the transformation from linear block copolymer to block/graft copolymer in which the grafting polymer chain is movable along the axle polymer chain.