Review
Energy & Fuels
Norhamizah Hazirah Ahmad Junaidi, Wai Yin Wong, Kee Shyuan Loh, Saidur Rahman, Wan Ramli Wan Daud
Summary: The oxygen reduction reaction (ORR) in proton exchange membrane fuel cells is a major issue due to sluggish kinetics, and exploring 2D MXene materials as catalyst supports presents great potential. MXenes exhibit excellent electronic properties, electrical conductivity, hydrophilicity, and chemical and thermal stability, making them promising catalyst supports.
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
(2021)
Article
Chemistry, Physical
Samindi Madhubha Jayawickrama, Dan Wu, Rei Nakayama, Shota Ishikawa, Xuanchen Liu, Gen Inoue, Tsuyohiko Fujigaya
Summary: The study shows that a Pt catalyst loaded on PBI-coated Vulcan with an I/C ratio of 0.2 exhibits the highest maximum power density, while maintaining stable ionomer coating and high proton conductivity. The PBI coating approach is a significant breakthrough in fabricating highly efficient CLs by improving both proton conduction and O2 diffusion simultaneously with lower ionomer content, as compared to conventional Pt catalyst on Vulcan.
JOURNAL OF POWER SOURCES
(2021)
Review
Chemistry, Physical
Eliran R. Hamo, Brian A. Rosen
Summary: As energy demands increase and environmental issues loom, fuel cells have gained significant attention as an alternative energy source, but the primary challenge remains improving fuel cell durability. Transition metal carbides (TMCs) show promise as a substitute for carbon-based catalyst supports, but concerns about their durability during start-up and shutdown operations hinder their large-scale deployment.
Article
Chemistry, Multidisciplinary
Gaoqiang Yang, Siddharth Komini Babu, Wipula P. R. Liyanage, Ulises Martinez, Dmitri Routkevitch, Rangachary Mukundan, Rodney L. Borup, David A. Cullen, Jacob S. Spendelow
Summary: This work presents a new catalyst/electrode architecture that eliminates the primary degradation mechanisms in conventional electrodes, enabling improved durability and faster mass transport. The unique coaxial nanowire electrode (CANE) design increases platinum utilization and eliminates the need for carbon support and ionomer binder. Fuel cell membrane electrode assemblies based on CANEs demonstrate extraordinary durability and high power density, enabling the rapid deployment of fuel cells in various clean energy applications.
ADVANCED MATERIALS
(2023)
Review
Thermodynamics
Yizhe Chen, Shiming Zhang, Joey Chung-Yen Jung, Jiujun Zhang
Summary: This paper systematically evaluates advanced carbons synthesized by various template methods as low-Pt catalyst supports and non-noble catalysts, and summarizes the applications of low/non-Pt carbon-based catalysts in the cathodes of PEMFCs and AEMFCs. The study also proposes effective strategies to address technical challenges and suggests future research directions for practical applications.
PROGRESS IN ENERGY AND COMBUSTION SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Takamitsu Ishiyama, Kota Igura, Takashi Suemasu, Kaoru Toko
Summary: Recent advancements in polycrystalline Ge layers formed through solid-phase crystallization have demonstrated higher carrier mobilities than single-crystal Si. This study thoroughly examines the phenomenon of metal-induced lateral crystallization in Ge, finding that 20 out of 24 tested metals promote low-temperature lateral growth on glass. The results, categorized by reaction type and growth morphology, have broad implications for various materials, with potential applications in developing next-generation thin-film devices on common and inexpensive substrates.
MATERIALS & DESIGN
(2023)
Article
Nanoscience & Nanotechnology
Yang Li, Yichang Yan, Yanping He, Shangfeng Du
Summary: The excellent performance and safety of direct formic acid fuel cells (DFAFCs) make them potential power sources for portable electronic devices. However, their real application is still challenging due to the complex fabrication of catalyst electrodes and poor power performance. In this study, a new gas diffusion electrode (GDE) with ultrathin PtCu alloy nanowire arrays grown on the carbon paper gas diffusion layer is demonstrated. The introduction of Cu in PtCu NWs enhances the direct oxidation pathway for formic acid and improves the power density of the GDE.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Materials Science, Multidisciplinary
Marcin Lapinski, Piotr Drozdz, Mariusz Golebiowski, Piotr Okoczuk, Jakub Karczewski, Marta Sobanska, Aleksiej Pietruczik, Zbigniew R. Zytkiewicz, Ryszard Zdyb, Wojciech Sadowski, Barbara Koscielska
Summary: The disintegration of continuous metallic thin film leads to the formation of isolated islands, which can be used to prepare plasmonic structures. This transformation is driven by thermally accelerated diffusion to minimize surface free energy in the system. In this study, we investigated the disintegration of gold thin film and the formation of nanoislands on silicon substrates, with and without native silicon dioxide film. Our experiments confirmed a strong correlation between the formation of nanoislands and the presence of native oxide on silicon substrates.
Article
Chemistry, Multidisciplinary
Aum Sagar Panda, Yi-Chien Lee, Chen-Jung Hung, Kang-Ping Liu, Cheng-Yen Chang, Gkreti-Maria Manesi, Apostolos Avgeropoulos, Fan-Gang Tseng, Fu-Rong Chen, Rong-Ming Ho
Summary: This study demonstrates a facile method for the controlled orientation of nanostructures in thin films using a diblock copolymer system. By manipulating the pressure and surface tension of the polymer materials, the researchers were able to achieve long-range order in the nanostructures.
Article
Nanoscience & Nanotechnology
Hamideh Eskandari, Devproshad K. Paul, Alan P. Young, Kunal Karan
Summary: This study investigates the water content and proton conductivity properties of thin-film ionomers at temperatures relevant to fuel cell operation temperatures. The acid content or equivalent weight of the ionomer is found to be the strongest determinant of both the swelling and the proton conductivity. Additionally, the study highlights the importance of water content in controlling proton conduction.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Biochemistry & Molecular Biology
Su-Jeong Bak, Mingyu Son, Jeehoon Shin, Sun- Kim, Jung Woo Lee, Duck Hyun Lee
Summary: Highly active and durable hybrid catalysts composed of small reduced graphene oxide and carbon nanotubes were prepared for oxygen reduction reaction in fuel cells. The catalysts exhibited excellent performance and stability, with the addition of carbon nanotubes further improving durability and electrical conductivity.
INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES
(2022)
Article
Multidisciplinary Sciences
Gani Yergaliuly, Baktiyar Soltabayev, Sandugash Kalybekkyzy, Zhumabay Bakenov, Almagul Mentbayeva
Summary: This study investigates the characteristics of ZnO thin films prepared using different solvents. The results show that thin films fabricated using ethanol or water solutions have high crystallinity, while films prepared with ethanol solvent have low resistivity and high electron mobility.
SCIENTIFIC REPORTS
(2022)
Article
Chemistry, Physical
Zhenxin Lin, Kai Zhao, Gang Cheng, Shuozhen Hu, Min Chen, Jun Li, Dongchu Chen, Qing Xu, Menglei Chang, Ogenko Volodymyr
Summary: A novel NiMo-Yttira-stabilized zirconia (YSZ) catalyst-layer supported tubular single cell is developed for solid oxide fuel cells running on methane. The NiMo-YSZ layer shows excellent reforming performance with high methane conversion, H2 and CO yield. The single cell demonstrates good electrochemical performance and stability, making it a promising option for direct operation in CH4/Air environments.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Jonas Hubertus, Sipontina Croce, Julian Neu, Stefan Seelecke, Gianluca Rizzello, Guenter Schultes
Summary: This report presents a new direct and maskless method for patterning compliant metallic electrodes for dielectric elastomer (DE) applications. Nickel-based electrodes with high conductivity and stretchability are sputter deposited onto pre-stretched membranes, resulting in a wrinkled surface. Using an ultra-short pulse laser system with a wavelength of 355 nm, an arbitrary electrode design can be directly patterned onto the double-sided coated DE membrane, allowing simultaneous ablation of both electrodes and selective ablation of specific electrodes. The laser structuring method enables the manufacturing of miniaturized DE transducers and the integration of optical features into DE electrodes.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Physical
M. A. Laguna-Marco, J. Herrero-Albillos, M. H. Aguirre, M. Rueda-Jimenez, I. Mikulska
Summary: Ir1-xCoxO2 thin films with rutile crystal structure were successfully prepared by reactive co-sputtering deposition. The doped films showed lower resistivity and similar magnetic response as pure IrO2.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Electrochemistry
Scott A. Mauger, K. C. Neyerlin, Shaun M. Alia, Chilan Ngo, Siddharth Komini Babu, Katherine E. Hurst, Svitlana Pylypenko, Shawn Litster, Bryan S. Pivovar
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2018)
Review
Chemistry, Multidisciplinary
Ulises Martinez, Siddharth Komini Babu, Edward F. Holby, Hoon T. Chung, Xi Yin, Piotr Zelenay
ADVANCED MATERIALS
(2019)
Article
Electrochemistry
Leiming Hu, Muxing Zhang, Siddharth Komini Babu, Anusorn Kongkanand, Shawn Litster
Article
Energy & Fuels
S. Komini Babu, D. Spernjak, J. Dillet, A. Lamibrac, G. Maranzana, S. Didierjean, O. Lottin, R. L. Borup, R. Mukundan
Article
Chemistry, Physical
Siddharth Komini Babu, Dusan Spernjak, Rangachary Mukundan, Daniel S. Hussey, David L. Jacobson, Hoon T. Chung, Gang Wu, Andrew J. Steinbach, Shawn Litster, Rod L. Borup, Piotr Zelenay
JOURNAL OF POWER SOURCES
(2020)
Article
Electrochemistry
Siddharth Komini Babu, Thomas O'Brien, Michael J. Workman, Mahlon Wilson, Rangachary Mukundan, Rod Borup
Summary: The corrosion of fuel cell components introduces contaminants that accelerate ionomer degradation, decreasing fuel cell durability. Altering gas diffusion layer wettability can affect cation contaminant transport, with the addition of a hydrophobic layer significantly suppressing contaminant transport and improving fuel cell performance.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Electrochemistry
Siddharth Komini Babu, Rangachary Mukundan, Chunmei Wang, David Langlois, David A. Cullen, Dennis Papadias, Karren L. More, Rajesh Ahluwalia, Jim Waldecker, Rodney Borup
Summary: The study shows that carbon support corrosion is similar between platinum (Pt) and platinum-cobalt (PtCo) catalysts. However, the performance degradation rate is higher for alloy catalysts due to differences in catalyst particle size and the leaching of transition metals. Lower initial carbon loading in catalysts results in lower carbon loss and better durability, but the cumulative loss of carbon remains the same for electrodes with the same catalyst support regardless of catalyst and ionomer composition in the catalyst layer.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2021)
Article
Nanoscience & Nanotechnology
ChungHyuk Lee, Xiaohua Wang, Jui-Kun Peng, Adlai Katzenberg, Rajesh K. Ahluwalia, Ahmet Kusoglu, Siddharth Komini Babu, Jacob S. Spendelow, Rangachary Mukundan, Rod L. Borup
Summary: In this study, the effects of cation contamination on fuel cell performance were comprehensively understood through controlled doping of electrodes. The research identified that around 44% of Co2+ exchange in the ionomer can be tolerated in the electrode, with performance losses mainly induced by oxygen and proton transport losses. It was also found that Co2+ preferentially resides in the electrode under wet operating conditions, providing insights for strategies to mitigate undesired effects when using alloy catalysts.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Siddharth Komini Babu, Abdurrahman Yilmaz, Md Aman Uddin, Jacob LaManna, Eli Baltic, David L. Jacobson, Ugur Pasaogullari, Jacob S. Spendelow
Summary: This research introduces a new porous transport layer (PTL), called hydrochannel PTL, that improves water management and achieves record high round trip efficiency in unitized reversible fuel cells (URFCs). URFCs require fast transport of O2 and H2O for high performance in both fuel cell and water electrolyzer modes, but the conflicting water management requirements make cell design complicated. The hydrochannel PTL addresses this issue by providing hydrophilic channels for water transport through a hydrophobic PTL, optimizing performance in both modes. Neutron radiography measurements confirm that the hydrochannel PTL enhances performance due to its improved water management capabilities.
ADVANCED ENERGY MATERIALS
(2023)
Article
Energy & Fuels
ChungHyuk Lee, Wilton J. M. Kort-Kamp, Haoran Yu, David A. Cullen, Brian M. Patterson, Tanvir Alam Arman, Siddharth Komini Babu, Rangachary Mukundan, Rod L. Borup, Jacob S. Spendelow
Summary: Researchers have developed a grooved electrode structure for PEMFCs that improves performance and durability by combining high ionomer content with grooves for efficient oxygen transport. The grooved electrodes showed up to 50% higher performance compared to conventional electrodes, and exhibited improved oxygen transport and durability.
Correction
Energy & Fuels
ChungHyuk Lee, Wilton J. M. Kort-Kamp, Haoran Yu, David A. Cullen, Brian M. Patterson, Tanvir Alam Arman, Siddharth Komini Babu, Rangachary Mukundan, Rod L. Borup, Jacob S. Spendelow
Article
Chemistry, Physical
Tanya Agarwal, Santosh Adhikari, Yu Seung Kim, Siddharth Komini Babu, Ding Tian, Chulsung Bae, Nguyet N. T. Pham, Seung Geol Lee, Ajay K. Prasad, Suresh G. Advani, Allen Sievert, Wipula Priya Rasika Liyanage, Timothy E. Hopkins, Andrew Park, Rod Borup
Summary: Phosphonic acids are a promising class of radical scavengers that can effectively remove radicals without migration issues, making them valuable for proton-exchange membrane fuel cells.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Electrochemistry
Kannan P. Ramaiyan, Sehmus Ozden, Sandip Maurya, Daniel Kelly, Siddharth K. Babu, Angelica Benavidez, Fernando G. Garzon, Yu Seung Kim, Cortney R. Kreller, Rangachary Mukundan
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2020)
Article
Electrochemistry
Ulises Martinez, Edward F. Holby, Siddharth Komini Babu, Kateryna Artyushkova, Ling Lin, Samrat Choudhury, Geraldine M. Purdy, Piotr Zelenay
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2019)
Review
Chemistry, Physical
Ulises Martinez, Siddharth Komini Babu, Edward F. Holby, Piotr Zelenay
CURRENT OPINION IN ELECTROCHEMISTRY
(2018)