4.7 Article

Fabrication of highly conductive graphene/ITO transparent bi-film through CVD and organic additives- free sol-gel techniques

期刊

SCIENTIFIC REPORTS
卷 7, 期 -, 页码 -

出版社

NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-017-18063-w

关键词

-

资金

  1. Basic Science Research Program of the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2014R1A6A1030419, NRF-2015R1D1A1A01061005]

向作者/读者索取更多资源

Indium tin oxide (ITO) still remains as the main candidate for high-performance optoelectronic devices, but there is a vital requirement in the development of sol-gel based synthesizing techniques with regards to green environment and higher conductivity. Graphene/ITO transparent bi-film was synthesized by a two-step process: 10 wt. % tin-doped ITO thin films were produced by an environmentally friendly aqueous sol-gel spin coating technique with economical salts of ln(NO3)(3 center dot)H2O and SnCI4( without using organic additives, on surface free energy enhanced (from 53.826 to 97.698 mJm(-2)) glass substrate by oxygen plasma treatment, which facilitated void-free continuous ITO film due to high surface wetting. The chemical vapor deposited monolayer graphene was transferred onto the synthesized ITO to enhance its electrical properties and it was capable of reducing sheet resistance over 12% while preserving the bi-film surface smoother. The ITO films contain the ln(2)O(3) phase only and exhibit the polycrystalline nature of cubic structure with 14.35 +/- 0.5 nm crystallite size. The graphene/ITO bi-film exhibits reproducible optical transparency with 88.66% transmittance at 550 nm wavelength, and electrical conductivity with sheet resistance of 117 Omega/sq which is much lower than that of individual sol-gel derived ITO film.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

Article Nanoscience & Nanotechnology

Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode

Bastian Waduge Naveen Harindu Hemasiri, Jae-Kwan Kim, Ji-Myon Lee

NANO-MICRO LETTERS (2018)

Article Nanoscience & Nanotechnology

Synthesis and Characterization of Graphene/ITO Nanoparticle Hybrid Transparent Conducting Electrode

Bastian Waduge Naveen Harindu Hemasiri, Jae-Kwan Kim, Ji-Myon Lee

NANO-MICRO LETTERS (2018)

Article Nanoscience & Nanotechnology

Elucidating the Doping Mechanism in Fluorene-Dithiophene-Based Hole Selective Layer Employing Ultrahydrophobic Ionic Liquid Dopant

Naveen Harindu Hemasiri, Samrana Kazim, Laura Calio, Sanghyun Paek, Manuel Salado, Gianluca Pozzi, Luis Lezama, Mohammad Khaja Nazeeruddin, Shahzada Ahmad

ACS APPLIED MATERIALS & INTERFACES (2020)

Article Chemistry, Multidisciplinary

A Machine Learning Approach for Metal Oxide Based Polymer Composites as Charge Selective Layers in Perovskite Solar Cells

Murat Onur Yildirim, Elif Ceren Gok, Naveen Harindu Hemasiri, Esin Eren, Samrana Kazim, Aysegul Uygun Oksuz, Shahzada Ahmad

Summary: A library of metal oxide-conjugated polymer composites was prepared for hole selective layers in perovskite solar cells fabrication, and machine learning approaches were used to predict and compare their performances. Different composites showed different suitable models and performance scores according to the evaluation models. Machine learning can be a pioneering prediction model for the PSCs performance and its validation.

CHEMPLUSCHEM (2021)

Correction Materials Science, Multidisciplinary

The impact of fluorine atoms on a triphenylamine-based dopant-free hole-selective layer for perovskite solar cells (vol 10, pg 476, 2022)

Abolfazl Ghaderian, Meenakshi Pegu, Naveen Harindu Hemasiri, Peng Huang, Shahzada Ahmad, Samrana Kazim

Summary: This study investigates the impact of fluorine atoms on a dopant-free hole-selective layer based on triphenylamine. The results demonstrate that the introduction of an appropriate amount of fluorine atoms can enhance the photoelectric conversion efficiency and stability of the layer, suggesting its potential application in perovskite solar cells.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Materials Science, Multidisciplinary

The impact of fluorine atoms on a triphenylamine-based dopant-free hole-selective layer for perovskite solar cells

Abolfazl Ghaderian, Meenakshi Pegu, Naveen Harindu Hemasiri, Peng Huang, Shahzada Ahmad, Samrana Kazim

Summary: By rationally designing dopant-free HTL and incorporating fluorinated arms on the core through molecular engineering, the stability and cost-effectiveness of PSCs can be substantially improved. The designed fluorinated HTL, FOMePh, showed high efficiency in PSCs and performed comparably to doped Spiro-OMeTAD, but at a lower cost.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Chemistry, Multidisciplinary

An Approach to Quantify the Negative Capacitance Features in a Triple-Cation based Perovskite Solar Cells

Hassen Dhifaoui, Naveen Harindu Hemasiri, Walid Aloui, Abdelaziz Bouazizi, Samrana Kazim, Shahzada Ahmad

Summary: The study on perovskite solar cells (PSCs) reveals that planar PSCs with P3HT as hole transport layer exhibit high efficiency, while PSCs without HTL show significant hysteresis. Investigation on the electrical response of PSCs indicates the appearance of negative capacitance in low frequency regime, which is attributed to interfacial interactions between migrating ions and metal contact.

ADVANCED MATERIALS INTERFACES (2021)

Article Energy & Fuels

Molecular Interface Engineering via Triazatruxene-Based Moieties/NiOx as Hole-Selective Bilayers in Perovskite Solar Cells for Reliability

Naveen Harindu Hemasiri, Laura Calio, Meenakshi Pegu, Samrana Kazim, Shahzada Ahmad

Summary: Interface engineering with an organic semiconductor as an interfacial layer is proposed to improve the performance of perovskite solar cells. The organic semiconductor enhances hole mobility and electrical conductivity through π-conjugation, and effectively suppresses detrimental charge recombination. Significant performance enhancement is achieved using this approach.

SOLAR RRL (2022)

Article Energy & Fuels

Predicting Perovskite Bandgap and Solar Cell Performance with Machine Learning

Elif Ceren Gok, Murat Onur Yildirim, Muhammed P. U. Haris, Esin Eren, Meenakshi Pegu, Naveen Harindu Hemasiri, Peng Huang, Samrana Kazim, Aysegul Uygun Oksuz, Shahzada Ahmad

Summary: The study successfully predicted the performance parameters of solar cells using machine learning technology, confirming the experimental data and indicating that this technology can help advance the commercialization of perovskite solar cells.

SOLAR RRL (2022)

Article Energy & Fuels

Impact of Polymeric Hole-Selective Layers on Chemical Inductance in Inverted Perovskite Solar Cells

Hassen Dhifaoui, Naveen Harindu Hemasiri, Hanadi Mehdi, Abdelaziz Bouazizi, Samrana Kazim, Shahzada Ahmad

Summary: Charge selective layers, especially the hole transport layer (HTL), play an essential role in determining the performance of perovskite solar cells (PSCs). The influence of HTL is even more significant in inverted PSCs, as it affects both the performance and crystallization process of the perovskite deposition. Through measuring the low-frequency impedance responses of inverted PSCs, the photo-induced charge transfer dynamics and negative chemical inductor features at low frequencies were deciphered.

ENERGY TECHNOLOGY (2022)

Article Energy & Fuels

Amplifying the Performance and Stability of Perovskite Solar Cells Using Fluorinated Salt as the Surface Passivator

Abolfazi Ghaderian, Naveen Harindu Hemasiri, Shahzada Ahmad, Samrana Kazim

Summary: The 3D-halide perovskite-based solar cells have shown impressive power conversion efficiency. This study explores the use of a common salt, tetra-n-butyl ammonium hexafluorophosphate (TBAPF), as a passivating agent to improve the efficiency and stability of the perovskite solar cells.

ENERGY TECHNOLOGY (2023)

Article Chemistry, Physical

Interface engineering of a hole-transport layer/perovskite with low-band-gap 2D-carbon nitrides for solar cell fabrication

Muhammad Ashraf, Naveen Harindu Hemasiri, Samrana Kazim, Nisar Ullah, Majad Khan, Saheed Adewale Ganiyu, Khalid R. Alhooshani, Muhammad Nawaz Tahir, Shahzada Ahmad

Summary: Interfacial engineering plays an important role in enhancing the performance and stability of perovskite solar cells (PSCs) by reducing non-radiative recombination and improving the moisture resistance. This study focuses on the synthesis and characterization of 2D polymeric carbon nitride-based materials as interfacial layers in inverted PSCs. These interfacial layers effectively suppress the redox reaction between Ni3+ and organic cations in perovskites, suppress interfacial charge accumulation, and reduce non-radiative recombination, leading to improved stability and higher device performance.

SUSTAINABLE ENERGY & FUELS (2023)

Article Chemistry, Physical

Decoding the charge carrier dynamics in triple cation-based perovskite solar cells

Mohd Taukeer Khan, Naveen Harindu Hemasiri, Samrana Kazim, Shahzada Ahmad

Summary: The study revealed two different charge carrier activation processes in triple cation-based PSCs, one caused by the migration of halide anions at high temperatures, while the other resulted from the trapping/de-trapping of electronic charges from shallow traps at low temperatures. The trap density of states in triple cation-based perovskites was found to be significantly lower than that of single cation-based perovskites, while the charge carrier mobility was higher.

SUSTAINABLE ENERGY & FUELS (2021)

Article Materials Science, Multidisciplinary

1T-Rich 2D-WS2 as an interfacial agent to escalate photo-induced charge transfer dynamics in dopant-free perovskite solar cells

Naveen Harindu Hemasiri, Samrana Kazim, Shahzada Ahmad

Summary: This study introduces the use of 2D-WS2 as an interfacial layer in perovskite solar cells to enhance charge extraction and transfer dynamics, leading to improved device performance.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

暂无数据