期刊
ADVANCED MATERIALS INTERFACES
卷 3, 期 1, 页码 -出版社
WILEY
DOI: 10.1002/admi.201500340
关键词
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资金
- National Basic Research Program of China [2014CB931700]
- Natural Science Foundation of China (NSFC) [51302152, 51272128, 51302153, 61222403]
- Program for Eastern Scholar at Shanghai Institutions of Higher Learning [2012-53]
Li3VO4 is a potential anode for Li-ion batteries owing to its safe discharge plateau and high capacity, but the reported reversible capacity is still far from its theoretical value (592 mAh g(-1)). Here, for the first time, a Li3VO4 anode is reported with reversible capacity approaching the theoretical value. Li3VO4 aggregates hybridized with carbon (Li3VO4/C) are first fabricated, and then dramatically transform into well dispersed Li3VO4 nanocrystals (NCs) anchoring on carbon nanoflakes (NFs) by electrochemical reconstruction. In the Li3VO4/C NC-on-NF structures, the small-sized Li3VO4 NCs, the flexible carbon NFs, and the good dispersity provide high Li-ion storage, electronic conductivity and stability, respectively. Resultingly, outstanding electrochemical performance of the Li3VO4/C is achieved with discharge and charge capacities of 542 and 541 mAh g(-1) after 300 cycles at a specific current of 150 mA g(-1). After 1000 cycles at a specific current of 2000 mA g(-1), the discharge and charge capacities are maintained at 422 and 421 mAh g(-1). When matching with a 4 V cathode, the specific energy density of the Li3VO4/C is 4.2 times of Li4Ti5O12 and 1.2 times of graphite, and the volumetric energy density is 3.2 times of Li4Ti5O12 and 1.4 times of graphite.
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