4.6 Article

NH4CoPO4 center dot H2O microbundles consisting of one-dimensional layered microrods for high performance supercapacitors

期刊

RSC ADVANCES
卷 4, 期 1, 页码 340-347

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra45977b

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资金

  1. Program for New Century Excellent Talents [NCET-13-0645]
  2. National Natural Science Foundation of China [NSFC-21201010, 21071006, U1304504, 21105002]
  3. Science & Technology Foundation of Henan Province [122102210253, 13A150019]
  4. China Post-doctoral Science Foundation [2012M521115]

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Unique layered NH4CoPO4 center dot H2O microbundles consisting of one-dimensional layered microrods are firstly synthesized by a facile hydrothermal method. As a result of novel layered structures, there are many nanolayered channels for the diffusion of ions and electrolytes. The preliminary supercapacitor investigation indicates that the specific capacitance of layered NH4CoPO4 center dot H2O microbundle electrodes reaches up to 662 F g(-1) at a current density of 1.5 A g(-1) and remains at 520 F g(-1) even at 15.0 A g(-1). The cycle test shows excellent cycling performance of layered NH4CoPO4 center dot H2O microbundle electrodes (the retention 92.7% of initial specific capacitance after 3000 cycles).

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