期刊
RSC ADVANCES
卷 4, 期 28, 页码 14538-14545出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra45974h
关键词
-
资金
- National Natural Science Foundation of China [21272024]
An efficient chiral squaramide-catalysed enantioselective Michael addition of pyrazolin-5-ones to beta,gamma-unsaturated alpha-ketoesters has been developed. The chiral pyrazolone derivatives were obtained in moderate to high yields (up to 99% yield) with high enantioselectivities (up to 96% ee) for most substrates. This catalytic asymmetric reaction provides valuable and easy access to chiral pyrazolone ketoester derivatives.
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