期刊
RSC ADVANCES
卷 4, 期 98, 页码 55115-55118出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra09922b
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资金
- Department of Science and Technology (DST), New Delhi [SB/S1/OC-53/2013]
- Council of Scientific and Industrial Research (CSIR) [02(0096)/12/EMR-II]
Different reactivities and selectivities of Cu and Pd catalysts have been demonstrated in the reactions of benzylamines with 2-phenylpyridines. Although Pd is reported to give o-arylation (ArCO-), Cu introduces an arylcarboxy group (ArCOO-) at the proximal site of the directing group. For the first time benzylamine has been utilised as a synthetic equivalent of an arylcarboxy group.
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