Article
Chemistry, Physical
Sainan Zhang, Ying Liu, Min Feng, Bowen Zhang, Tongtong Yu, Shiwei Xu, Guoyun Sun, Daoai Wang
Summary: A new Ti3C2/TiO2 composite photoanode material was fabricated, showing enhanced photoelectrochemical water splitting performance and improved efficiency in separating electrons and holes.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Guangcan Luo, Ziling Zhang, Jing Jiang, Yang Liu, Wei Li, Jingquan Zhang, Xia Hao, Wenwu Wang
Summary: A self-powered ZnO nanorod array/CuSCN/rGO ultraviolet photodetector was fabricated using facile, convenient, and low-cost processes, demonstrating enhanced device performance through encapsulation and treatment, including improved responsivity and rectification ratio.
Article
Chemistry, Multidisciplinary
Fan Ru, Jing Xia, Xuanze Li, Yifan Wang, Ze Hua, Ruiwen Shao, Xuecong Wang, Chun-Sing Lee, Xiang-Min Meng
Summary: In this study, well-aligned single-crystalline ZnO/ZnS core/shell nanorod arrays were successfully obtained by introducing an Al2O3 buffer layer. A rational growth mechanism of the core/shell heterostructure was proposed based on detailed characterization, showing that Al2O3 can effectively improve the optical properties of the ZnO/ZnS heterostructure.
Article
Chemistry, Physical
Xiaoyu Xie, Ru Wang, Yi Ma, Jinping Chen, Zengliang Shi, Qannan Cui, Zhiyong Li, Chunxiang Xu
Summary: This study presents a strategy of in situ [SO4] modification and heterojunction construction to design photoelectrodes with multicharge-transfer channels for enhanced PEC performance. The core-shell heterojunction of sulfate-functionalized CdS decorated on ZnO nanorod arrays and Ag2S nanoparticles provides active sites for accelerated charge transfer and improved PEC reaction kinetics. The addition of AO suppresses the photocorrosion of CdS and facilitates efficient separation and transportation of photogenerated charge carriers. The optimized photoanode exhibits high PEC performance, with a maximum photocurrent density 7.75 times higher than that of pristine ZnO photoanode under simulated AM 1.5 solar light illumination.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Yongming Zhong, Siyuan Yang, Yueping Fang, Kaifeng Wang, Jianteng Sun, Wengang Wu
Summary: This study demonstrates the construction of a film-like photocatalyst ZnO-CdS(Ar)@Ni, which significantly enhances the hydrogen generation rate and can be used for efficient photoelectrochemical water splitting. The enhanced performance is attributed to the unique ZnO-CdS heterojunction structure, the combination of 1D nanorod array with 3D Ni foam substrate, and the efficient electron collection and transfer within the Ni foam.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Mengzhou Wu, Haoyang Wu, Shaohua Xie, Wenliang Wang, Guoqiang Li
Summary: This research constructed an InN nanorod/Ni(OH)2 heterojunction to enhance the interfacial charge transfer and improve the photoelectric current and efficiency of InN nanomaterials in photoelectrochemical water splitting.
Article
Chemistry, Multidisciplinary
Xu Guo, Xing Liu, Junqing Yan, Shengzhong Frank Liu
Summary: Heterostructure catalysts are promising for photocatalytic hydrogen generation, with ZnO/ZnS/CdS and ZnO/CdS heterostructures exhibiting superior performance through heterointerface engineering. These findings contribute significantly to the development of solar-driven water splitting technology.
CHEMISTRY-A EUROPEAN JOURNAL
(2022)
Article
Engineering, Chemical
Xiangbo Feng, Lvwei Sun, Wei Wang, Yuzhen Zhao, Jian-Wen Shi
Summary: A new CdS@ZnO core-shell nanorod array was successfully constructed by atomic layer deposition (ALD) for efficient H2 evolution from photoelectrochemical water splitting. The CdS@ZnO200 obtained after 200 ALD cycles showed a significantly enhanced PEC H2 evolution rate of 21.64 μmol·h-1·cm-2, which was about 9.4 times higher than pristine CdS NRAs. The improved performance could be attributed to the Z-scheme charge transfer mechanism between CdS core and ZnO shell, as well as the reduction of charge carrier transfer resistance due to the close contact between the two semiconductors.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Chemistry, Physical
Weiqi Dang, Kaijia Xu, Liqiang Zhang, Yinyin Qian
Summary: By combining CdS quantum dots with TiO2 and overlaying a ZnS passivation layer, the light absorption range was increased and the recombination of electrons/holes was reduced, leading to a significantly higher photovoltaic conversion efficiency.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Chemistry, Multidisciplinary
Ziyue He, Wenkai Zhang, Xin Xie, Jiahe Guo, Xinyu Zhang, Jingyang Wang
Summary: A new process for preparing nanorod arrays was developed in this study, and TiO2/ZnO nanorod heterojunction materials with enhanced photovoltaic properties were successfully prepared. By optimizing the structure and components, the photovoltaic performance and photocatalytic ability of the nanorod arrays were significantly improved. This work is of great significance for the research and application of nanorod arrays.
JOURNAL OF NANOPARTICLE RESEARCH
(2023)
Article
Chemistry, Physical
Yuling Wei, Leshuang Wang, Changlong Chen
Summary: Yttrium doped ZnO nanorod array films grown hydrothermally on fluorine doped tin oxide substrates exhibit enhanced photoelectrochemical water splitting performance, attributed to improved light absorption, increased conductivity, and prolonged carrier lifetime caused by yttrium doping. The yttrium doped samples show higher photocurrent density under illumination compared to undoped samples, making them promising platforms for various photocatalytic applications beyond photoelectrochemical water splitting.
JOURNAL OF ALLOYS AND COMPOUNDS
(2022)
Article
Chemistry, Physical
Changlin Li, Shangrong Chen, Xiangxiang Gao, Wei Zhang, Yanfang Wang
Summary: The study presents the preparation of ZnO/CdS/CdSe heterostructures on Zn foil substrate using a facile three-step method, enhancing the light absorption ability and carrier separation efficiency of ZnO through the co-sensitization of CdS and CdSe. These heterostructures exhibit efficient photoelectrochemical properties and have potential for practical applications due to their low cost and high efficiency.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Engineering, Electrical & Electronic
Hoang Nhat Hieu, Nguyen Van Nghia, Nguyen Minh Vuong, Loan Le Thi Ngoc, Thanh Hai Phan
Summary: We reported a rational and simple approach to fabricate heterojunction CdS/CuO/ZnO branched nanowires as photoelectrodes for highly efficient water splitting. The optimized photoelectrode showed significantly enhanced photoconversion efficiency of 3.9% under solar simulation, which is much higher than other photoelectrodes.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2022)
Article
Materials Science, Ceramics
Nguyen Manh Hung, Vu Thi Bich, Nguyen Duc Quang, Nguyen Tien Hiep, Chuang Nguyen, Sutripto Majumder, Pham Tien Hung, Phung Dinh Hoat, Nguyen Van Hoang, Nguyen Minh Hieu, Tien Dai Nguyen
Summary: A three-dimensional hierarchical CuS-CdS@TiO2 multi-heterostructure with a CuS semiconductor, CdS branches and TiO2 nanorods was designed as a highly efficient photoanode for PEC water splitting. The enhanced PEC performance was attributed to the wide range of solar spectrum absorption in CdS branches, the efficient electron transfer pathway provided by TiO2 nanorods, and the improved separation of electron-hole on the surface of the photoanode facilitated by the p-n junction formed between CuS and CdS@TiO2 heterostructure.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Multidisciplinary
Ali Can Guler, Jan Antos, Milan Masar, Michal Urbanek, Michal Machovsky, Ivo Kuritka
Summary: This study investigated the effects of geometric features, light absorption spectra, and electrochemical active surface area on photoelectrochemical properties. ZnO nanorods were grown on ITO substrates with controlled morphologies and used as a model. The size of the nanorods was adjusted by varying the concentration of a cation surfactant. The results showed that the geometric characteristics and electrochemically active surface area increased together, while the light scattering effect slightly increased due to the random spatial orientation of the nanorods. The large surface area and void space between nanorods improved the photon-to-current conversion efficiency. A maximum photocurrent density was achieved with smaller diameter and length ZnO nanorods, and the charge separation efficiency was improved with a shorter photogenerated hole diffusion distance.
NANOSCALE ADVANCES
(2023)
Article
Chemistry, Multidisciplinary
Quanming Peng, Guiming Peng, Liangpeng Wu, Xiaoyang Wang, Xu Yang, Xinjun Li
RESEARCH ON CHEMICAL INTERMEDIATES
(2018)
Article
Chemistry, Multidisciplinary
Yulan Zhang, Xizhu Lin, Xinjun Li, Chenguang Wang, Qiong Long, Longlong Ma
NEW JOURNAL OF CHEMISTRY
(2018)
Article
Materials Science, Multidisciplinary
Xiaoyang Wang, Xu Yang, Lei Miao, Jie Gao, Quanming Peng, Liangpeng Wu, Siyi Chen, Xinjun Li
JOURNAL OF MATERIALS SCIENCE
(2019)
Article
Nanoscience & Nanotechnology
Nan Wang, Jianguo Liu, Long Tang, Xiuzhi Wei, Chenguang Wang, Xinjun Li, Longlong Ma
Summary: This study successfully developed two kinds of Rh nanoparticle anchored uniform spherical COF catalysts for efficient synthesis of secondary imines with good selectivity and yield. Additionally, the catalyst also showed good activity towards various substituted aromatic aldehyde compounds.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Juan Li, Liangpeng Wu, Nan Wang, Xinjun Li, Chaoping Cen
Summary: The modified confined catalyst Pt-in/Fe2O3-TNTs showed enhanced activity in catalyzing the oxidation of ethylene, with a significant decrease in complete conversion temperature. The modification of Fe2O3 on the exterior surface was found to stabilize the Pt nanoparticles at higher oxidation states and accelerate electron transfer, ultimately improving catalytic performance.
Article
Chemistry, Multidisciplinary
Yu-Bing Du, Nan Wang, Xiang-Nan Li, Juan Li, Liang-Peng Wu, Quan-Ming Peng, Xin-Jun Li
Summary: A heterostructure photocatalyst consisting of g-C3N4-modified TiO2 nanotubes with confined Pt nanoparticles was prepared, showing enhanced visible light-induced absorptance and improved charge carrier recombination rate. The ternary composite exhibited the highest photocatalytic performance in hydrogen evolution from water splitting under solar light, providing a promising low-cost candidate for water splitting and rational design of high-performance photocatalysts in solar-to-fuel conversion.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Nanoscience & Nanotechnology
Nan Wang, Jianguo Liu, Mingyue Zhang, Chenguang Wang, Xinjun Li, Longlong Ma
Summary: In this study, a non-noble nickel-modified covalent organic framework catalyst was successfully synthesized and showed excellent performance in the semihydrogenation of phenylacetylene under mild reaction conditions. The catalyst exhibited high selectivity and good stability, making it a promising candidate for selective hydrogenation reactions.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Chemistry, Multidisciplinary
Yaqian Chen, Xiangnan Li, Juan Li, Yubing Du, Quanming Peng, Liangpeng Wu, Xinjun, Li
Summary: The study introduces CeO2 to modify TiO2 nanotubes, forming hybrid nanotubes to confine Pt nanoparticles as efficient catalysts for high WGS activity at low temperatures. The research finds a positive correlation between the redox ability of PtOx species and WGS activity, with Pt-O-v oxygen vacancies serving as important active sites for H2O dissociation and CO oxidation in the reaction.
Article
Chemistry, Multidisciplinary
Liangpeng Wu, Wenguang Wang, Shaohong Zhang, Dan Mo, Xinjun Li
Summary: The study successfully prepared Co-doped Fe2O3 spindles with different Co contents and showed their improved photocatalytic and photo-Fenton catalytic performances. The Co(5%)-Fe2O3 spindles exhibited the highest activity and best stability, attributed to the reduction of band gap, establishment of an internal electric field, and acceleration of Fe2+/Fe3+ redox cycling.
Article
Chemistry, Multidisciplinary
Ze-Yu Wang, Feng-Ying Luo, Juan Li, Nan Wang, Xiang-Nan Li, Xin-Jun Li
Summary: This study reports a sol-gel synthesis method to prepare Cu2Y2O5 perovskite, which forms a heterostructure catalyst of Cu-Y2O3 supported on Cu2Y2O5 perovskite by light activation. The catalyst exhibits good photocatalytic performance in solar-driven WGSR.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Multidisciplinary
Jiamei Mo, Nan Wang, Shaohong Zhang, Xiaoli Chen, Juan Fu, Peili Chen, Zheng Liang, Qiucheng Su, Xinjun Li
Summary: g-C3N4/melem nanorods hybrids were synthesized via a rapid cooling process with H2SO4-assisted treatments, and exhibited enhanced photocatalytic performance compared to bulk g-C3N4. The improved efficiency is mainly attributed to the synergistic effect of g-C3N4 and melem.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Multidisciplinary
Fengying Luo, Zeyu Wang, Xiangnan Li, Lin Lang, Xinjun Li, Xiuli Yin
Summary: Highly dispersed Ni-based catalysts were prepared via the sol-gel process and self-reconstruction, and exhibited excellent catalytic performance in dry methane reforming. The presence of a transition layer of La2NiO4 between metallic Ni-0 and the La(OH)(3) support has been suggested to play a crucial role in the catalytic activity.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Physical
Peiwei Han, Hongxia Lv, Xiaogang Li, Shengzhe Wang, Zhilian Wu, Xiangnan Li, Zhao Mu, Xinjun Li, Chenglin Sun, Huangzhao Wei, Lei Ma
Summary: By regulating the amount of additive during synthesis, efficient surface oxygen vacancies were formed, improving catalytic activity while studying the reaction mechanism.
CATALYSIS SCIENCE & TECHNOLOGY
(2021)
Article
Chemistry, Inorganic & Nuclear
Quanming Peng, Guiming Peng, Liangpeng Wu, Yaqian Chen, Bin Han, Qiucheng Su, Shijun Liu, Xinjun Li
DALTON TRANSACTIONS
(2020)
Article
Chemistry, Physical
Juan Li, Liangpeng Wu, Shaohong Zhang, Jianbo Wen, Mingwei Liu, Chenguang Wang, Xinjun Li
SUSTAINABLE ENERGY & FUELS
(2019)