期刊
RSC ADVANCES
卷 4, 期 12, 页码 5887-5892出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra45682j
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资金
- National Natural Science Foundation of China [21074054, 21172106, 51173078]
- National Basic Research Program of China [2010CB923303]
Four chiral fluorescence sensors (S)-L1-4 incorporating boronic ester and (S)-1,1'-bi-2-naphthol (BINOL) moieties were synthesized and developed for the enantioselective recognition of alpha-phenylethylamine and phenylglycinol enantiomers. The sensor (S)-L1 shows an obvious fluorescence quenching turn-off response towards enantiomers of both alpha-phenylethylamine and phenylglycinol. Interestingly, the sensor (S)-L2 can exhibit remarkable fluorescent enhancement turn-on response behavior towards (S)alpha-phenylethylamine, but shows no response towards phenylglycinol enantiomers. The Stern-Volmer constant (K-sv) values of (S)-L1 are 0.63 x 10(3) L mol(-1) and 4.48 x 10(3) L mol(-1) for (L)-and (D)phenylglycinol, respectively, and the value of the enantiomeric fluorescence difference ratio (ef) of (S)-L2 is 4.6 for alpha-phenylethylamine, demonstrating that (S)-L2 could be used as a fluorescence sensor for simple and direct visual discrimination of organic molecule enantiomers. On the contrary, no fluorescence enantioselective recognition response could be observed when using the (S)-BINOL-based boronic ester sensors (S)-L3 and (S)-L4 incorporating bigger naphthyl or 8-methoxyquinolinyl substituent groups.
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