期刊
RSC ADVANCES
卷 4, 期 40, 页码 20632-20635出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra02941k
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资金
- National Research Foundation - Korean government [NRF-2013R1A2A2A01068684, NRF-2012-007235]
- National Research Foundation of Korea [2013R1A2A2A01068684, 2012R1A2A1A01007235] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A new synthetic method for homopropargylic amines from alkyl azides is presented. A salient feature of this reaction is the involvement of N-unsubstituted imines as the key intermediates, which are generated from alkyl azides by Ru catalysis under photolytic conditions. Notably, this method avoids the use of a protective group strategy in the homopropargylic amine synthesis.
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