期刊
RSC ADVANCES
卷 4, 期 52, 页码 27250-27258出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra03455d
关键词
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资金
- Natural Science Foundation of China [21176223]
- National Natural Science Foundation of Zhejiang [LY13B020016]
- Key Innovation Team of Science and Technology in Zhejiang Province [2010R50018]
A novel KI/TBHP-catalyzed 1,3-dipolar cycloaddition/oxidation/aromatization cascade reaction provided general, efficient and green access to biologically important pyrrolo[2,1-a]isoquinolines. The product pyrrolo[2,1-a] isoquinolines were obtained from reactions between simple, readily available dipolarophiles and tetrahydroisoquinolines in moderate to excellent yields The reaction was environmentally benign in the adoption of nontoxic KI as a catalyst and IOH was generated in situ from the oxidation reaction of KI and TBHP.
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