4.6 Article

Enhanced emission properties of Au/ SiO2/ ZnO nanorod layered structure: effect of SiO2 spacer layer and role of interfacial charge transfer

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RSC ADVANCES
卷 4, 期 30, 页码 15466-15473

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ra00950a

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  1. US-India Partnership to Advance Clean Energy-Research (PACE-R) for the Solar Energy Research Institute for India
  2. United States (SERIIUS)
  3. U.S. Department of Energy (Office of Science, Office of Basic Energy Sciences, and Energy Efficiency and Renewable Energy, Solar Energy Technology Program) [DE-AC36-08GO28308]
  4. Government of India, through the Department of Science and Technology [IUSSTF/JCERDC-SERIIUS/2012]
  5. DAE-BRNS

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SiO2 spacer layers of various thicknesses in between an Au and ZnO nanorod (NR) layer (Au/ZnO) have been introduced and the luminescence properties of the layered ensemble have been investigated. When ZnO NRs are grown directly on a granular Au layer, the ultraviolet (UV) emission of ZnO was enhanced nearly 2 times due to surface plasmon resonance (SPR) mediated charge transfer between Au and ZnO. A significant improvement is observed when the SiO2 spacer layer is introduced in between Au and ZnO. The UV/VIS emission intensity ratio of Au/SiO2/ZnO NRs' becomes-6 times higher than that of the pristine ZnO NRs. A SPR mediated electron transfer from Au/SiO2 to ZnO causes such an enhanced UV emission. The spacer diminishes the reverse electron transfer process from the conduction band of ZnO to the Fermi level of Au, a most competitive reason for PL quenching, which also accounts for the emission enhancement.

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