Multidentate actor ligands as versatile platforms for small molecule activation and catalysis

Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex

(2012) Michael J. Sgro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Active Ligands in Catalysis

(2012) Vijayendran K. K. Praneeth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Learning from the Neighbors: Improving Homogeneous Catalysts with Functional Ligands Motivated by Heterogeneous and Biocatalysis

(2012) Bjorn Askevold et al.   ChemCatChem

Reversible formal insertion of CO2 into a remote C–H bond of a ligand in a Ru(ii) complex at room temperature

(2012) Vincent T. Annibale et al.   CHEMICAL COMMUNICATIONS

Redox-active ligands in catalysis

(2012) Oana R. Luca et al.   CHEMICAL SOCIETY REVIEWS

A New Mode of Activation of CO2 by Metal-Ligand Cooperation with Reversible CC and MO Bond Formation at Ambient Temperature

(2012) Matthias Vogt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cationic Ti(iv) and neutral Ti(iii) titanocene–phosphinoaryloxide frustrated Lewis pairs: hydrogen activation and catalytic amine-borane dehydrogenation

(2012) Andy M. Chapman et al.   DALTON TRANSACTIONS

Cooperative & Redox Non-Innocent Ligands in Directing Organometallic Reactivity (Eur. J. Inorg. Chem. 3/2012)

(2012) Karen Hindson et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Aldehyde Binding through Reversible C–C Coupling with the Pincer Ligand upon Alcohol Dehydrogenation by a PNP–Ruthenium Catalyst

(2012) Michael Montag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mechanism of Alkene Addition to a Nickel Bis(dithiolene) Complex: The Role of the Reduced Metal Complex

(2012) Li Dang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Addition of Carbon–Carbon Bonds with a Redox-Active Bis(imino)pyridine Iron Complex

(2012) Jonathan M. Darmon et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pair” hydrogenations

(2012) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Construction of Rhodium(I) and Gold(I) Macrocycles by Transferring a Phosphine-Functionalized 4,5-Diazafluorenide Ligand from Its Copper(I) N-Heterocyclic Carbene Complex

(2012) Runyu Tan et al.   ORGANOMETALLICS

Reactivity of Scandium β-Diketiminate Alkyl Complexes with Carbon Dioxide

(2012) Francis A. LeBlanc et al.   ORGANOMETALLICS

Anionic Nickel(II) Complexes with Doubly Deprotonated PNP Pincer-Type Ligands and Their Reactivity toward CO2

(2012) Matthias Vogt et al.   ORGANOMETALLICS

Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)

(2012) Chelsea A. Huff et al.   ORGANOMETALLICS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Coordination Versatility of sp3-Hybridized Pincer Ligands toward Ligand–Metal Cooperative Catalysis

(2012) Dmitri Gelman et al.   ACS Catalysis

Redox Non-Innocent Ligands: Versatile New Tools to Control Catalytic Reactions

(2012) Volodymyr Lyaskovskyy et al.   ACS Catalysis

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Unprecedented Catalytic Hydrogenation of Urea Derivatives to Amines and Methanol

(2011) Ekambaram Balaraman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Low-Pressure Hydrogenation of Carbon Dioxide Catalyzed by an Iron Pincer Complex Exhibiting Noble Metal Activity

(2011) Robert Langer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Peptides and Pyrazines from β-Amino Alcohols through Extrusion of H2 Catalyzed by Ruthenium Pincer Complexes: Ligand-Controlled Selectivity

(2011) Boopathy Gnanaprakasam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ester hydrogenation catalyzed by Ru-CNN pincer complexes

(2011) Yunshan Sun et al.   CHEMICAL COMMUNICATIONS

Organometallic frustrated Lewis pair chemistry

(2011) Gerhard Erker   DALTON TRANSACTIONS

Molecular Electrocatalysts for the Oxidation of Hydrogen and the Production of Hydrogen - The Role of Pendant Amines as Proton Relays

(2011) Daniel L. DuBois et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

(2011) Sven Schneider et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cationic Group 4 Metallocene-(o-Phosphanylaryl)oxido Complexes: Synthetic Routes to Transition-Metal Frustrated Lewis Pairs

(2011) Andy M. Chapman et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Insights into Dehydrogenative Coupling of Alcohols and Amines Catalyzed by a (PNN)–Ru(II) Hydride Complex: Unusual Metal–Ligand Cooperation

(2011) Guixiang Zeng et al.   INORGANIC CHEMISTRY

Metal-Stabilized Thiyl Radicals as Scaffolds for Reversible Alkene Addition via C–S Bond Formation/Cleavage

(2011) Kagna Ouch et al.   INORGANIC CHEMISTRY

Preface: Forum on Redox-Active Ligands

(2011) Paul J. Chirik   INORGANIC CHEMISTRY

Manifestations of Noninnocent Ligand Behavior

(2011) Wolfgang Kaim   INORGANIC CHEMISTRY

Noninnocence in Metal Complexes: A Dithiolene Dawn

(2011) Richard Eisenberg et al.   INORGANIC CHEMISTRY

Palladium β-diiminate chemistry: Reactivity towards monodentate ligands and arylboronic acids

(2011) Vincent T. Annibale et al.   INORGANICA CHIMICA ACTA

Frustrated Lewis Pairs beyond the Main Group: Cationic Zirconocene–Phosphinoaryloxide Complexes and Their Application in Catalytic Dehydrogenation of Amine Boranes

(2011) Andy M. Chapman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene–Phosphinoaryloxide Complexes

(2011) Andy M. Chapman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cascade Catalysis for the Homogeneous Hydrogenation of CO2to Methanol

(2011) Chelsea A. Huff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand

(2011) Bjorn Askevold et al.   Nature Chemistry

Combining acid–base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase

(2011) James M. Camara et al.   Nature Chemistry

Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO

(2011) Ekambaram Balaraman et al.   Nature Chemistry

Water Splitting Promoted by a Ruthenium(II) PNN Complex: An Alternate Pathway through a Dihydrogen Complex for Hydrogen Production

(2011) K. S. Sandhya et al.   ORGANOMETALLICS

New CNN-Type Ruthenium Pincer NHC Complexes. Mild, Efficient Catalytic Hydrogenation of Esters

(2011) Eran Fogler et al.   ORGANOMETALLICS

Activation of Alkyl C–F Bonds by B(C6F5)3: Stoichiometric and Catalytic Transformations

(2011) Christopher B. Caputo et al.   ORGANOMETALLICS

Computational Study on the Catalytic Role of Pincer Ruthenium(II)-PNN Complex in Directly Synthesizing Amide from Alcohol and Amine: The Origin of Selectivity of Amide over Ester and Imine

(2011) Haixia Li et al.   ORGANOMETALLICS

A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s-1 for H2 Production

(2011) M. L. Helm et al.   SCIENCE

A Biologically Inspired Organometallic Fuel Cell (OMFC) That Converts Renewable Alcohols into Energy and Chemicals

(2010) Samuel P. Annen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Imines from Alcohols and Amines with Liberation of H2

(2010) Boopathy Gnanaprakasam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen oxidation catalysis by a nickel diphosphine complex with pendant tert-butyl amines

(2010) Jenny Y. Yang et al.   CHEMICAL COMMUNICATIONS

Cooperative multimetallic catalysis using metallosalens

(2010) Robert M. Haak et al.   CHEMICAL COMMUNICATIONS

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Non-innocent ligands in bioinorganic chemistry—An overview

(2010) Wolfgang Kaim et al.   COORDINATION CHEMISTRY REVIEWS

Mechanism for the Light-Induced O2Evolution from H2O Promoted by Ru(II) PNN Complex: A DFT Study

(2010) Yue Chen et al.   JOURNAL OF PHYSICAL CHEMISTRY A

“Long-Range” Metal−Ligand Cooperation in H2Activation and Ammonia-Promoted Hydride Transfer with a Ruthenium−Acridine Pincer Complex

(2010) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling

(2010) Aubrey L. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions

(2010) Ekambaram Balaraman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New Bimetallic Reactivity in Pt2II,II/Pt2IV,IVTransformation Mediated by a Benzene Ring

(2010) Shu-Bin Zhao et al.   ORGANOMETALLICS

Perspectives on How Nature Employs the Principles of Organometallic Chemistry in Dihydrogen Activation in Hydrogenases†

(2010) John C. Gordon et al.   ORGANOMETALLICS

Metal−Ligand Cooperativity in O2Activation: Observation of a “Pt−O−O−C” Peroxo Intermediate§

(2010) Margaret L. Scheuermann et al.   ORGANOMETALLICS

Radical Ligands Confer Nobility on Base-Metal Catalysts

(2010) P. J. Chirik et al.   SCIENCE

Bifunctional Transition Metal-Based Molecular Catalysts for Asymmetric C–C and C–N Bond Formation

(2010) Takao Ikariya et al.   TOPICS IN CATALYSIS

Recent Progress in Asymmetric Bifunctional Catalysis Using Multimetallic Systems

(2009) Masakatsu Shibasaki et al.   ACCOUNTS OF CHEMICAL RESEARCH

Development of Molecular Electrocatalysts for CO2Reduction and H2Production/Oxidation

(2009) M. Rakowski Dubois et al.   ACCOUNTS OF CHEMICAL RESEARCH

Neutral Tridentate PNP Ligands and Their Hybrid Analogues: Versatile Non-Innocent Scaffolds for Homogeneous Catalysis

(2009) Jarl Ivar van der Vlugt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3

(2009) Alberto Ramos et al.   CHEMICAL COMMUNICATIONS

Catalytic production of sulfur heterocycles (dihydrobenzodithiins): a new application of ligand-based alkene reactivity

(2009) Daniel J. Harrison et al.   CHEMICAL COMMUNICATIONS

Reversible H2splitting between Ru(ii) and a remote carbanion in a zwitterionic compound

(2009) Elzbieta Stepowska et al.   CHEMICAL COMMUNICATIONS

Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes

(2009) Robert H. Morris   CHEMICAL SOCIETY REVIEWS

Reductive dearomatization of a substituted benzene triggered by a strong oxidant

(2009) Runyu Tan et al.   DALTON TRANSACTIONS

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

Syntheses, Structures and Reactivities of Rhodium 4,5-Diazafluorene Derivatives

(2009) Huiling Jiang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ligand-Based Reactivity of a Platinum Bisdithiolene: Double Diene Addition Yields a NewC2-Chiral Chelate Ligand

(2009) Mitchell J. Kerr et al.   INORGANIC CHEMISTRY

Metal−Ligand Cooperation in H2Production and H2O Decomposition on a Ru(II) PNN Complex: The Role of Ligand Dearomatization−Aromatization

(2009) Jun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Hydrogen/Deuterium Effects in the Direct Hydrogenation of Ketones Catalyzed by a Well-Defined Ruthenium Diphosphine Diamine Complex

(2009) Marco Zimmer-De Iuliis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation of Sensitive Organometallic Compounds by Antagonistic N/B Lewis Pair Catalyst Systems

(2009) Kirill V. Axenov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of a Redox-Active Ligand Complex of Nickel with Dioxygen Probes Ligand-Radical Character

(2009) Tony D. Manuel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes

(2009) Charles P. Casey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Water Splitting and Oxygen−Oxygen Bond Formation by a Mononuclear Ruthenium Complex

(2009) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Consecutive Thermal H2and Light-Induced O2Evolution from Water Promoted by a Metal Complex

(2009) Stephan W. Kohl et al.   SCIENCE

Ethanol as Hydrogen Donor: Highly Efficient Transfer Hydrogenations with Rhodium(I) Amides

(2008) Theo Zweifel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel α-Keto-β-Diimine Initiators for Olefin Polymerization

(2008) Jason D. Azoulay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines

(2008) Theo Zweifel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Living healthy on a dying planet

(2008) Daniel G. Nocera   CHEMICAL SOCIETY REVIEWS

Selective CC Coupling of Ir-Ethene and Ir-Carbenoid Radicals

(2008) Wojciech I. Dzik et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aerobic oxidation of C(sp3)–H bonds of 4,5-diazafluorene promoted by coordination

(2008) Huiling Jiang et al.   DALTON TRANSACTIONS

Spectroscopic Determination of Hydrogenation Rates and Intermediates during Carbonyl Hydrogenation Catalyzed by Shvo's Hydroxycyclopentadienyl Diruthenium Hydride Agrees with Kinetic Modeling Based on Independently Measured Rates of Elementary Reactions

(2008) Charles P. Casey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Redox-Regulated Ethylene Binding to a Rhenium-Thiolate Complex

(2008) Craig A. Grapperhaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage

(2008) Matthew A. Rankin et al.   ORGANOMETALLICS

Diplatinum Complexes Supported by Novel Tetradentate Ligands with Quinoline Functionalities for Tandem C−Cl Activation and Dearomatization

(2008) Runyu Tan et al.   ORGANOMETALLICS

Syntheses, Characterizations, and Reactivities of 4,5-Diazafluorenide Complexes of Palladium(II) and Rhodium(I)

(2008) Huiling Jiang et al.   ORGANOMETALLICS

Probing the Dynamics and Reactivity of a Stereochemically Nonrigid Cp*Ru(H)(κ2-P,Carbene) Complex

(2008) Matthew A. Rankin et al.   ORGANOMETALLICS