4.6 Article

Structure and properties of hot-pressed lead-free (Ba0.85Ca0.15)(Zr0.1Ti0.9)O-3 piezoelectric ceramics

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RSC ADVANCES
卷 3, 期 43, 页码 20693-20698

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra43429j

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Randomly-oriented and textured (Ba0.85Ca0.15)(Zr0.1Ti0.9)O-3 (BCZT) ceramics are prepared by a hot-pressing (HP) method. The phase structure, microstructure, and electrical properties are systematically investigated. Structural analysis shows a decrease in tetragonality of the hot-pressed samples. The orientation of the as-processed ceramics is studied by X-ray diffraction and electron backscatter diffraction, revealing an increase in texture of the hot-pressed textured BCZT ceramics. Microstructure characterization demonstrates that the hot-pressing can greatly improve the densification of the BCZT ceramics. Dielectric constant measurement obeys a modified Curie-Weiss law. The relaxor-like behavior is decreased in hot-pressed samples. The Curie temperatures of the hot-pressed BCZT (BCZT-HP) and the hot-pressed BCZT with texture templates (BCZT-T-HP) ceramics are greatly increased to 76 degrees C and 90 degrees C, respectively. The optimum piezoelectric properties for the BCZT-HP and BCZT-T-HP ceramics are d33 = 510 pC N-1, kp = 44%, d(31) = - 182 pC N-1, k(31) = 23% and d(33) = 580 pC N-1, k(p) = 49%, d(31) = - 204 pC N-1, k(31) = 31%, respectively. Therefore, the BCZT-HP and BCZT-T-HP ceramics are promising lead-free piezoelectric ceramics which can be used in higher temperature than their counterparts prepared by conventional sintering.

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