期刊
RSC ADVANCES
卷 3, 期 44, 页码 22199-22205出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra44806a
关键词
-
资金
- European Community's 7th Framework Programme through the Marie Curie Initial Training Network NANO-HOST [215193]
- MIUR (project ItalNanoNet)
The grafting of the preformed Pc-L* (pyridine containing macrocyclic ligands) copper(I) complexes on different ordered and non-ordered silicas, and their use, under heterogeneous batch conditions, as catalysts for the olefin cyclopropanation are reported. High yields (up to 99%) and good recyclability in halogen-free solvent reactions were obtained, together with negligible copper leaching (0.1% of total copper).
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