期刊
RSC ADVANCES
卷 3, 期 2, 页码 573-578出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ra22796g
关键词
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资金
- National Natural Foundation of China [21272202, 21032005]
- Fundamental Research Funds for the Central Universities
Chiral SPINOL-phosphoric acids exhibited high activities and excellent diastereo- and enantioselectivities in the catalysis of the three-component Povarov reaction of benzyl N-vinylcarbamate, anilines and aldehydes with a catalyst loading of 5 mol%. The synthetic utility of this protocol was demonstrated by the asymmetric synthesis of enantioenriched benzo[e]indolizidine with excellent yield and excellent level of sterecontrol.
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