4.6 Article

Phase investigation on zinc-tin composite crystallites

期刊

RSC ADVANCES
卷 3, 期 30, 页码 12084-12087

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra41767k

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资金

  1. National Nature Science Foundation of China [61074172, 61134010, 61006055]
  2. Program for Chang Jiang Scholars and Innovative Research Team in University [IRT1017]
  3. 863 High Technology Project [2013AA030902]
  4. Graduate Innovation Fund of Jilin University [20121105]

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Zinc-tin composite crystallites (cubes and octahedra) synthesized by conventional methods in earlier literature, were proved to have ZnSn(OH)(6) structures rather than perovskite structure ZnSnO3 as reported. Furthermore, according to the tolerance factor t introduced by Goldschmidt, ZnSnO3 can not exist as a perovskite structure.

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