期刊
RSC ADVANCES
卷 3, 期 45, 页码 22918-22921出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ra45205k
关键词
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资金
- National Natural Science Foundation of China [20702051]
- Natural Science Foundation of Zhejiang Province [LY13B020017]
- Key Innovation Team of Science and Technology in Zhejiang Province [2010R50018]
A simple and efficient aerobic oxidative deoximation system, using molecular oxygen as the green oxidant and FeCl3/TEMPO as the catalyst, is developed for a wide range of aldoximes. Notably, nitric oxide (NO), an active species for aerobic oxidation reactions, is assumed to be generated in situ from the cleavage of oximes and further confirmed by the existence of a large quantity of NO3 by Ionic Chromatography (IC).
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